Related papers: Diffusioosmotic dispersion
In this work, we perform a comparative study of the size dependence of diffusion of charged and neutral solutes in water. The neutral solute in water shows a nonmonotonicity in the size dependence of diffusion. This is usually connected to…
Mathematically modeling complex transport phenomena at the molecular level can be a powerful tool for identifying transport mechanisms and predicting macroscopic properties. We use two different stochastic time series models, parameterized…
In charged nanopores, ionic diffusion current reflects the ionic selectivity and ionic permeability of nanopores which determines the performance of osmotic energy conversion, i.e. the output power and efficiency. Here, theoretical…
We study the trapping of charged particles and macromolecules (such as DNA) in salt gradients in aqueous solutions. The source for the salt gradient can be as simple as a dissolving ionic crystal, as shown by McDermott et al. [Langmuir 28,…
We study the combined effects of natural convection and rotation on the dissolution of a solute in a solvent-filled circular cylinder. The density of the fluid increases with the increasing concentration of the dissolved solute, and we…
In the presence of a chemically active particle, a nearby chemically inert particle can respond to a concentration gradient and move by diffusiophoresis. The nature of the motion is studied for two cases: first, a fixed reactive sphere and…
Recent laboratory experiments on solute migration in composite porous columns have shown an asymmetry in the solute arrival time upon reversal of the flow direction, which is not explained by current paradigms of transport. In this work, we…
The driven, cylindrical, free interface between two miscible, Stokes fluids with high viscosity contrast have been shown to exhibit dispersive hydrodynamics. A hallmark feature of dispersive hydrodynamic media is the dispersive resolution…
In this study, we develop a saturation-dependent treatment of dispersion in porous media using concepts from critical path analysis, cluster statistics of percolation, and fractal scaling of percolation clusters. We calculate spatial solute…
Taylor dispersion in periodic but highly corrugated channels is studied. Exact analytical expressions for the long-time diffusion constant and drift along the channel are derived to next-to-leading order in the limit of small channel…
The evolution of the interface separating a conduit of light, viscous fluid rising buoyantly through a heavy, more viscous, exterior fluid at small Reynolds numbers is governed by the interplay between nonlinearity and dispersion. Previous…
The dispersion of a passive colloid immersed in a bath of non-interacting and non-Brownian run-and-tumble microswimmers in two dimensions is analyzed using stochastic simulations and an asymptotic theory, both based on a minimal model of…
This fluid dynamics video shows how an oil-in-water emulsion stabilized by an ionic surfactant spreads on the free surface of a layer of pure water. The spreading shows two intriguing features: a transparent area surrounding the source of…
We present a theory for the kinetics of surfactant adsorption at the interface between an aqueous solution and another fluid (air, oil) phase. The model relies on a free-energy formulation. It describes both the diffusive transport of…
The present study revisits the vertical distribution of suspended sediment concentration in an open channel flow with a special attention to sediment diffusion coefficient. If turbulent diffusivity is considered to follow a parabolic-type…
In this article, we study numerically the dispersion of colloids in a two-dimensional cellular flow in the presence of an imposed mean salt gradient. Owing to the additional scalar, the colloids do not follow exactly the Eulerian flow…
The motion of active colloids is generally achieved through their anisotropy, as exemplified by Janus colloids. Recently, there was a growing interest in the propulsion of isotropic colloids, which requires some local symmetry breaking.…
Discrete element method simulations of confined bidisperse granular shear flows elucidate the balance between diffusion and segregation that can lead to either mixed or segregated states, depending on confining pressure. Results indicate…
The viscously dominated, low Reynolds' number dynamics of multi-phase, compacting media can lead to nonlinear, dissipationless/dispersive behavior when viewed appropriately. In these systems, nonlinear self-steepening competes with wave…
The cellular environment, characterized by its intricate composition and spatial organization, hosts a variety of organelles, ranging from membrane-bound ones to membraneless structures that are formed through liquid-liquid phase…