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Gross--Oliveira--Kohn (GOK) ensemble density-functional theory (GOK-DFT) is a time-\textit{independent} extension of density-functional theory (DFT) which allows to compute excited-state energies via the derivatives of the ensemble energy…

Chemical Physics · Physics 2020-06-18 Clotilde Marut , Bruno Senjean , Emmanuel Fromager , Pierre-François Loos

In recent years, a number of dynamical density functional theories (DDFTs) have been developed for describing the dynamics of the one-body density of both colloidal and atomic fluids. In the colloidal case, the particles are assumed to have…

Soft Condensed Matter · Physics 2009-08-10 A. J. Archer

A collective coordinate theory is develop for soliton ratchets in the damped discrete sine-Gordon model driven by a biharmonic force. An ansatz with two collective coordinates, namely the center and the width of the soliton, is assumed as…

Pattern Formation and Solitons · Physics 2015-01-21 B. Sánchez-Rey , N. R. Quintero , J. Cuevas-Maraver , M. A. Alejo

Real-time time-dependent density functional theory (rt-TDDFT) with hybrid exchange-correlation functional has wide-ranging applications in chemistry and material science simulations. However, it can be thousands of times more expensive than…

Computational Physics · Physics 2019-05-07 Weile Jia , Lin-Wang Wang , Lin Lin

The Generalized Method of Moments (GMM) is a partition of unity based technique for solving electromagnetic and acoustic boundary integral equations. Past work on the GMM for electromagnetics was confined to geometries modeled by piecewise…

Computational Physics · Physics 2015-06-18 Daniel Dault , Naveen V. Nair , Jie Li , Balasubramaniam Shanker

The predictions of the geometric collective model (GCM) for different sets of Hamiltonian parameter values are related by analytic scaling relations. For the quartic truncated form of the GCM -- which describes harmonic oscillator, rotor,…

Nuclear Theory · Physics 2007-05-23 M. A. Caprio

Stimuli-responsive macromolecules display large conformational changes during their dynamics, sometimes switching states, and are an integral property for the development of soft functional materials. Here, we introduce a mean-field…

Soft Condensed Matter · Physics 2024-07-02 José López-Molina , Sebastien Groh , Joachim Dzubiella , Arturo Moncho-Jordá

A generalization of the density-functional based tight-binding method (DFTB) for the use with range-separated exchange-correlation functionals is presented. It is based on the Generalized Kohn-Sham (GKS) formalism and employs the density…

Materials Science · Physics 2015-06-03 Thomas A. Niehaus , Fabio Della Sala

We introduce a general framework for defining context-dependent time distributions in quantum systems using projective measurements. The time-of-flow (TF) distribution, derived from population transfer rates into a measurement subspace,…

Quantum Physics · Physics 2025-11-17 Mathieu Beau

This paper develops a quantitatively accurate first-principles description for the frequency and the linewidth of collective electronic excitations in inhomogeneous weakly disordered systems. A finite linewidth in general has intrinsic and…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 C. A. Ullrich , G. Vignale

Stochastic and mixed stochastic-deterministic density functional theory (DFT) are promising new approaches for the calculation of the equation-of-state and transport properties in materials under extreme conditions. In the intermediate warm…

Computational Physics · Physics 2023-09-27 Vidushi Sharma , Lee A. Collins , Alexander J. White

Simulations of laser-induced electron dynamics in a molecular system are performed using time-dependent (TD) equation-of-motion (EOM) coupled-cluster (CC) theory. The target system has been chosen to highlight potential shortcomings of…

Chemical Physics · Physics 2023-08-09 Stephen H. Yuwono , Brandon C. Cooper , Tianyuan Zhang , Xiaosong Li , A. Eugene DePrince

We present a numerical method for grand canonical density functional theory (DFT) tailored to solid-state systems, employing Gaussian-type orbitals as the primary basis. Our approach directly minimizes the grand canonical free energy using…

Chemical Physics · Physics 2025-10-09 Anton Z. Ni , Adam Rettig , Joonho Lee

By using stochastic ensembles of walkers in physical and in one-body Hilbert spaces the recently proposed time-dependent quantum Monte Carlo (TDQMC) method offers the unique capability to calculate one-body density matrices at fully…

Quantum Physics · Physics 2025-02-07 Ivan P. Christov

This chapter concerns with the recent development of a new DFT methodology for accurate, reliable prediction of many-electron systems. Background, need for such a scheme, major difficulties encountered, as well as their potential remedies…

Chemical Physics · Physics 2019-04-19 Amlan K. Roy

We discuss issues related to pairing dynamics in nuclear large amplitude collective motion. The examples of effects which are not properly described within BCS theory are presented. In the second part we review properties of TDDFT and in…

Nuclear Theory · Physics 2018-07-03 P. Magierski , J. Grineviciute , K. Sekizawa

We study the structure of generalized parton distributions in spin 0 nuclei within a microscopic approach for nuclear dynamics. GPDs can be used on one side as tools to unravel the deep inelastic transverse structure of nuclei in terms of…

High Energy Physics - Phenomenology · Physics 2009-11-11 S. Liuti , S. K. Taneja

We prove that the theorems of TDDFT can be applied to a class of qubit Hamiltonians that are universal for quantum computation. The theorems of TDDFT applied to universal Hamiltonians imply that single-qubit expectation values can be used…

Quantum Physics · Physics 2011-08-20 David G. Tempel , Alan Aspuru-Guzik

The breathing-mode giant monopole resonance (GMR) is studied within the framework of the relativistic mean-field theory using the Generator Coordinate Method (GCM). The constrained incompressibility and the excitation energy of isoscalar…

Nuclear Theory · Physics 2009-09-25 M. V. STOITSOV , P. RING , M. M. SHARMA

A summary of recent researches on nuclear dynamics with realistic microscopic quantum approaches is presented. The Balian-V\'en\'eroni variational principle is used to derive the time-dependent Hartree-Fock (TDHF) equation describing the…

Nuclear Theory · Physics 2014-06-03 Cédric Simenel