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Electronic properties of graphene quantum dots (GQDs) constitute a subject of intense scientific interest. Being smaller than 20 nm, GQDs contain confined excitons in all dimensions simultaneously. GQDs feature a non-zero band gap and…

Materials Science · Physics 2015-04-21 Guilherme Colherinhas , Eudes Eterno Fileti , Vitaly V. Chaban

Density functional theory (DFT) can be quite advantageous in advancing the field of catalysis because of the microscopic insights it provides, and thus can guide experimental searches of novel catalysts. Several recent works have…

Materials Science · Physics 2022-03-24 Vaishali Sharma , Basant Roondhe , Sumit Saxena , Alok Shukla

Density functional theory calculations are performed on phosphorene quantum dots having different shapes and edge terminations to investigate their structure stability, electronic properties, and gas sensing ability. All the selected…

Mesoscale and Nanoscale Physics · Physics 2018-12-05 Hazem Abdelsalam , Vasil A. Saroka , Waleed O. Younis

Graphene quantum dots (GQDs) are nanoscale structures of graphene with quantum properties and edge effects that give photoluminescence properties. The effect of quantum confinement and differences in the nature of GQD structure makes its…

Computational Physics · Physics 2022-12-21 Setianto , I Made Joni

Density functional theory (DFT) and thermal DFT (thDFT) calculations were used to evaluate the energy band structure, bandgap, and the total energy of various graphene quantum dots (GQDs). The DFT calculations were performed using local…

Materials Science · Physics 2021-12-20 Majid Ghandchi , Ghafar Darvish , Mohammad Kazem Moravvej-Farshi

The adsorption behavior of toxic gas molecules (NO, CO, NO2, and NH3) on graphene-like BC3 are investigated using first-principle density functional theory (DFT). The most stable adsorption configurations, adsorption energies,binding…

Mesoscale and Nanoscale Physics · Physics 2017-08-22 S. M. Aghaei , M. M. Monshi , I. Torres , I. Calizo

The electronic energy gap and total dipole moment of chemically functionalized hexagonal and triangular graphene quantum dots are investigated by the density functional theory. It has been found that the energy gap can be efficiently tuned…

Mesoscale and Nanoscale Physics · Physics 2018-03-14 Hazem Abdelsalam , Hanan Elhaes , Medhat A. Ibrahim

We have studied the electronic and optical properties of three low-symmetry graphene quantum dots (GQDs), with the point-group symmetries $C_{2v}$, and $C_{2h}$. For the calculations of linear optical absorption spectra, we employed both…

Chemical Physics · Physics 2024-12-06 Samayita Das , Alok Shukla

Using density functional theory calculations, we have examined the structural stability, electronic, magnetic and optical properties of rectangular shaped quantum dots (QDs) of graphene (G), Boron Nitride (BN) and their hybrids. Different…

Materials Science · Physics 2013-11-14 Sharma SRKC Yamijala , Arkamita Bandyopadhyay , Swapan K Pati

Spin-polarized first-principles calculations have been performed to tune the electronic and optical properties of graphene (G) and boron-nitride (BN) quantum dots (QDs) through molecular charge-transfer using Tetracyanoquinodimethane (TCNQ)…

Materials Science · Physics 2017-09-13 Arkamita Bandyopadhyay , Sharma SRKC Yamijala , Swapan K Pati

The band modulation of the silicene and graphene quantum dots is investigated by a first-principles method. This study includes the ordinary silicene and graphene quantum dots and the embedded quantum dots in the hydrogenated silicene and…

Mesoscale and Nanoscale Physics · Physics 2018-12-24 Bi-Ru Wu

We present exemplary results of extensive studies of mechanical, electronic and transport properties of covalent functionalization of graphene monolayers (GML) with -NH2. We report new results of ab initio studies of covalent…

Materials Science · Physics 2014-01-24 Karolina Z. Milowska , Jacek A. Majewski

A 200 mm processing platform for the large-scale production of graphene field-effect transistor-quantum dot (GFET-QD) hybrid photodetectors is demonstrated. Comprehensive statistical analysis of electric data shows a high yield (96%) and…

Graphene is a nonmagnetic semimetal and cannot be directly used as electronic or spintronic devices. We demonstrate that graphene quantum dots (GQDs) can exhibit strong edge magnetism and tunable energy gaps due to the presence of localized…

Materials Science · Physics 2017-11-01 Wei Hu , Yi Huang , Lin Lin , Erjun Kan , Xingxing Li , Chao Yang , Jinlong Yang

We analyse the electronic and optical properties of graphene quantum dots (GQD) using accurate \textit{ab initio} many-body $GW$ and Bethe-Salpeter calculations. We show that most pristine GQD, including structures with irregular shapes,…

Mesoscale and Nanoscale Physics · Physics 2020-03-26 Denis M. Basko , Ivan Duchemin , Xavier Blase

Due to the advantage of tunability via size, shape, doping and relatively low level of loss and high extent of spatial confinement, graphene quantum dots (GQDs) are emerging as an effective way to control light by molecular engineering. The…

Materials Science · Physics 2015-02-13 Sharma S. R. K. C Yamijala , Madhuri Mukhopadhyay , Swapan K. Pati

We report on time-dependent density functional theory (TDDFT) calculations of the excited states of 63 different graphene quantum dots (GQDs) in square shape with side lengths 1 nm, 1.5 nm and 2 nm. We investigate the systematics and trends…

Chemical Physics · Physics 2022-06-07 Şener Özönder , Caner Ünlü , Cihat Güleryüz , Levent Trabzon

Strongly correlated electron liquids which occur in quantizing magnetic fields reveal a cornucopia of fascinating quantum phenomena such as fractionally charged quasiparticles, anyonic statistics, topological order, and many others. Probing…

Mesoscale and Nanoscale Physics · Physics 2010-03-09 D. A. Abanin , I. Skachko , X. Du , E. Y. Andrei , L. S. Levitov

The adsorption effects of small molecules (H$_{2}$O, CO, NH$_{3}$, NO$_{2}$) and large molecules (Tetracyanoquinodimethane (TCNQ) and Tetrafluoro-tetracyanoquinodimethane (F4TCNQ)) on electronic and magnetic properties of two triangular…

Mesoscale and Nanoscale Physics · Physics 2020-07-23 Zahra Talebi Esfahani , Alireza Saffarzadeh , Ahmad Akhound , Amir Abbas Sabouri Dodaran

The structure stability and electronic properties of edge carboxylated hexagonal and triangular graphene quantum dots are investigated by using density functional theory. The calculated binding energies show that the hexagonal clusters with…

Mesoscale and Nanoscale Physics · Physics 2018-03-14 Hazem Abdelsalam , Hanan Elhaes , Medhat A. Ibrahim
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