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The abundance spectrum of Na^-_{n~7-140} anions formed by low energy electron attachment to free nanoclusters is measured to be strongly and nontrivially restructured with respect to the neutral precursor beam. This restructuring is…

Atomic and Molecular Clusters · Physics 2008-06-11 Roman Rabinovitch , Chunlei Xia , Vitaly V. Kresin

Neutral alkali clusters efficiently capture low-energy electrons with the aid of long-range polarization attraction. Upon attachment, the electron affinity and kinetic energy are dissipated into vibrations, heating the cluster and…

Atomic and Molecular Clusters · Physics 2011-12-14 Roman Rabinovitch , Klavs Hansen , Vitaly V. Kresin

Dissociative electron attachment (DEA) to gas-phase carbonyl sulfide (OCS) has been studied diligently using the time-of-flight (TOF) based state-of-the-art velocity map imaging (VMI) technique. Three well-resolved DEA resonances are…

Atomic Physics · Physics 2022-02-24 Narayan Kundu , Vikrant Kumar , Tejas Jani , Minaxi Vinodkumar , Dhananjay Nandi

Nitrogen-vacancy (NV) centers in diamond are widely used in the development of a number of sensors. The sensitivity of these devices is limited by both the number of centers used and their coherent properties. While the effects on the…

On a dense energy grid reaching up to 75 meV electron collision energy the fragmentation angle and the kinetic energy release of neutral dissociative recombination fragments have been studied in a twin merged beam experiment. The anisotropy…

Rate coefficients for dissociative recombination and state-to-state rotational transitions of the D$_{2}^{+}$ ion induced by collisions with very low-energy electrons have been reported following our previous studies on HD$^{+}$ and…

Atomic Physics · Physics 2022-03-30 M. D. Epée Epée , O. Motapon , N. Pop , F. Iacob , E. Roueff , I. F. Schneider , J. Zs Mezei

Inelastic collision dynamics between isolated gas-phase carbon monoxide molecules and low energetic electrons (< 50 eV) has been studied using state-of-the-art velocity map imaging apparatus and reported previously. These were based on data…

Atomic Physics · Physics 2021-11-16 Narayan Kundu , Dipayan Biswas , Vikrant Kumar , Anirban Paul , Dhananjay Nandi

We demonstrate fully three-dimensional and patterned localization of nitrogen-vacancy (NV) centers in diamond with coherence times in excess of 1 ms. Nitrogen {\delta}-doping during CVD diamond growth vertically confines nitrogen to 4 nm…

Mesoscale and Nanoscale Physics · Physics 2016-05-04 Claire A. McLellan , Bryan A. Myers , Stephan Kraemer , Kenichi Ohno , David D. Awschalom , Ania C. Bleszynski Jayich

The electrical conductivity of a material can feature subtle, nontrivial, and spatially-varying signatures with critical insight into the material's underlying physics. Here we demonstrate a conductivity imaging technique based on the…

Mesoscale and Nanoscale Physics · Physics 2018-06-26 Amila Ariyaratne , Dolev Bluvstein , Bryan A. Myers , Ania C. Bleszynski Jayich

Low energy electron attachment to mixed (H$_2$)$_x$/(O$_2$)$_y$ clusters and their deuterated analogues has been investigated for the first time. These experiments were carried out using liquid helium nanodroplets to form the clusters, and…

Atomic and Molecular Clusters · Physics 2018-05-03 Michael Renzler , Lorenz Kranabetter , Erik Barwa , Lukas Grubwieser , Paul Scheier , Andrew M. Ellis

We use transient absorption spectroscopy to monitor the ionization and dissociation products following two-photon excitation of pure liquid water. The two decay mechanisms occur with similar yield for an excitation energy of 9.3 eV, whereas…

Chemical Physics · Physics 2009-11-13 Christopher G. Elles , Ilya A. Shkrob , Robert A. Crowell , Stephen E. Bradforth

Resonant vibrational excitation cross sections and the corresponding rate coefficients for electron-N$_2$ collisions occurring through the N$_2^-(\textrm{X}\ ^2\Pi_g)$ resonant state are reviewed. New calculations are performed using…

Plasma Physics · Physics 2015-06-18 V. Laporta , D. A. Little , R. Celiberto , J. Tennyson

Cross sections and thermal rate coefficients are computed for electron-impact dissociative recombination and vibrational excitation/de-excitation of the N$^+_2$ molecular ion in its lowest six vibrational levels, for collision…

The dissociation of relativistic $^{12}$N nuclei having a momentum of 2 GeV/c per nucleon and undergoing the most peripheral interactions in a track emulsion is studied. The picture of charged topology of product ensembles of relativistic…

Photoinduced quantum dynamics in molecules have hierarchical temporal structures with different energy scales that are associated with electron and nuclear motions. Femtosecond-to-attosecond transient absorption spectroscopy (TAS) using…

Electrochemical ammonia synthesis via lithium-mediated nitrogen dissociation has demonstrated exceptional Faradaic efficiency at ambient conditions, but its viability is limited by a high energy cost of ~9.12 eV per NH3 via lithium…

Chemical Physics · Physics 2025-07-30 Victor Azumah , Venkatasubramanian Viswanathan

We performed calculations of the optimized structure, harmonic vibrational frequencies and dissociation energies of RbOH and its anion, and investigate the interactions between Rb and OH$^-$ leading to possible associative detachment…

Chemical Physics · Physics 2015-06-16 Jason N. Byrd , H. Harvey Michels , John A. Montgomery , Robin Côté

Directly imaging structural dynamics involving hydrogen atoms by ultrafast diffraction methods is complicated by their low scattering cross-sections. Here we demonstrate that megaelectronvolt ultrafast electron diffraction is sufficiently…

We present an experimental study of the dissociative excitation in the collision of helium ions with nitrogen and oxygen molecules for collision energy of $0.7-10$ keV. Absolute emission cross sections are measured and reported for most…

Atomic Physics · Physics 2024-01-30 M. Gochitashvili , R. Lomsadze , R. Ya. Kezerashvili , I. Noselidze , M. Schulz

The low-frequency vibrational spectrum of an isolated nanometer-scale solid differs dramatically from that of a bulk crystal, causing the decay of a localized electronic state by phonon emission to be inhibited. We show, however, that an…

Materials Science · Physics 2009-10-31 Ho-Soon Yang , Michael R. Geller , W. M. Dennis