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Recent experiments have shown that trivalent ion, spermidine$^{3+}$, can provoke lateral microphase segregation in DNA brushes. Using molecular simulations and simple theoretical arguments, we explore the effects of trivalent counterions on…

Soft Condensed Matter · Physics 2017-03-03 Lei Liu , Philip A. Pincus , Changbong Hyeon

Planar brushes of flexible, semiflexible and rodlike diblock polyampholytes are studied using molecular dynamics simulations and scaling analysis in a wide range of the grafting density. Simulations show linear dependence of the average…

Soft Condensed Matter · Physics 2015-05-14 M. Baratlo , H. Fazli

We demonstrate that the plasmon frequency and Drude weight of the electron liquid in a doped graphene sheet are strongly renormalized by electron-electron interactions even in the long-wavelength limit. This effect is not captured by the…

Mesoscale and Nanoscale Physics · Physics 2011-07-19 Saeed H. Abedinpour , G. Vignale , A. Principi , Marco Polini , Wang-Kong Tse , A. H. MacDonald

We have investigated coupling constants in elementary electron-phonon scattering processes on a graphite surface by the combined use of high-resolution electron-energy-loss spectroscopy (HREELS) and very low-energy electron diffraction…

It is shown using a method based on a modified version of the mean field theory of Miklavic Marcelja that it should be possible for osmotic pressure due to the counterions associated with the two polyelectrolyte polymer brush coated…

Materials Science · Physics 2009-11-13 J. B. Sokoloff

A seemingly anomalous enhancement of electron mobility in strained silicon inversion layers at high sheet densities has exposed a conspicuous gap between device physics theory and experiment in recent years. We show that the root of this…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 Chris Bowen , Ryan Hatcher

In this paper, we study electrostatic and structural properties between pH-responsive polyelectrolyte brushes by using a strong stretching theory accounting for excluded volume interactions, the density of polyelectrolyte chargeable sites…

Soft Condensed Matter · Physics 2022-08-31 Jun-Sik Sin

The transport of polyelectrolytes confined by oppositely charged surfaces and driven by a constant electric field is of interest in studies of DNA separation according to size. Using molecular dynamics simulations that include surface…

Soft Condensed Matter · Physics 2020-09-15 Debarshee Bagchi , Monica Olvera de la Cruz

Superconductivity in single-layer graphene has attracted considerable interest. Here, using the determinant quantum Monte Carlo method, we study transitions of superconductivity and magnetism in a monolayer graphene with a special periodic…

Strongly Correlated Electrons · Physics 2024-12-31 Jingyao Meng , Runyu Ma , Tianxing Ma , Hai-Qing Lin

The aim of this work is to describe the electronic properties of graphene in a constant magnetic field in the long wavelength approximation with random binary disorder, by solving the Soven equation self-consistently. Density of state…

Mesoscale and Nanoscale Physics · Physics 2015-03-03 Juan Sebastian Ardenghi , Pablo Bechthold , Estela Gonzalez , Paula Jasen , Alfredo Juan

Materials subjected to a magnetic field exhibit the Hall effect, a phenomenon studied and understood in fine detail. Here we report a qualitative breach of this classical behavior in electron systems with high viscosity. The viscous fluid…

We present mesoscopic DPD-simulations of polyelectrolyte electrophoresis in confined nanogeometries, for varying salt concentration and surface slip conditions. Special attention is given to the influence of electroosmotic flow (EOF) on the…

Soft Condensed Matter · Physics 2011-03-03 Jens Smiatek , Friederike Schmid

Poisson-Boltzmann theory is the cornerstone for soft matter electrostatics. We provide novel exact analytical solutions to this non-linear mean-field approach, for the diffuse layer of ions in the vicinity of a planar or a cylindrical…

Soft Condensed Matter · Physics 2020-01-29 L. Samaj , E. Trizac

We calculate the effect of the electron-phonon interaction on the electronic density of states (DOS), the quasiparticle properties and on the optical conductivity of graphene. In metals with DOS constant on the scale of phonon energies, the…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 J. P. Carbotte , E. J. Nicol , S. G. Sharapov

The classical Poisson-Boltzmann (PB) theory of electrolytes assumes a dilute solution of point charges with mean-field electrostatic forces. Even for very dilute solutions, however, it predicts absurdly large ion concentrations (exceeding…

Chemical Physics · Physics 2007-05-23 Mustafa Sabri Kilic , Martin Z. Bazant , Armand Ajdari

Optical tweezers are employed to measure the forces of interaction within a single pair of DNA-grafted colloids in dependence of the molecular weight of the DNA-chains, and the concentration and valence of the surrounding ionic medium. The…

The effective elasticity of highly charged stiff polyelectrolytes is studied in the presence of counterions, with and without added salt. The rigid polymer conformations may become unstable due to an effective attraction induced by…

Soft Condensed Matter · Physics 2009-11-07 Ramin Golestanian , Tanniemola B. Liverpool

Using self-assembly techniques, x-ray reflectivity measurements, and computer simulations, we study the effective interaction between charged polymer rods and surfaces. Long-time Brownian dynamics simulations are used to measure the…

Soft Condensed Matter · Physics 2009-10-31 R. Jay Mashl , Niels Grønbech-Jensen , M. R. Fitzsimmons , M. Lütt , DeQuan Li

Although the volume transition of the polyelectrolyte gel has been studied for decades, little research on the effects of size of the mobile ions has been conducted. In the present paper, Tanaka classical theory of polyelectrolyte gel is…

Soft Condensed Matter · Physics 2015-06-17 Li-Jian Qu , Xinghua Zhang , Jiuzhou Tang , Dadong Yan

Polymer brushes have found extensive applications as responsive surfaces, particularly in achieving tunable friction in solvent environments. Despite recent interest in extending this technology to air environments, little is known about…

Soft Condensed Matter · Physics 2023-10-24 Stephen Merriman , Saranshu Singla , Ali Dhinojwala