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We present detailed results of Unrestricted Hartree-Fock (UHF) calculations for up to eight electrons in a parabolic quantum dot. The UHF energies are shown to provide rather accurate estimates of the ground-state energy in the entire range…

Strongly Correlated Electrons · Physics 2009-11-10 Boris Reusch , Hermann Grabert

We propose a mean field framework in which the charge and the parity symmetries of a single-particle state are broken. We break these symmetries to incorporate the correlation induced by the tensor force into a nuclear mean field model. We…

Nuclear Theory · Physics 2009-11-10 Satoru Sugimoto , Kiyomi Ikeda , Hiroshi Toki

Coupled cluster theory is the method of choice for weakly correlated systems. But in the strongly correlated regime, it faces a symmetry dilemma, where it either completely fails to describe the system, or has to artificially break certain…

Chemical Physics · Physics 2020-05-14 Yiheng Qiu , Thomas M. Henderson , Jinmo Zhao , Gustavo E. Scuseria

The nuclear symmetry energy is defined by the second derivative of the energy per nucleon with respect to the proton-neutron asymmetry, and is sometimes approximated by the energy difference between the neutron matter and the symmetric…

Nuclear Theory · Physics 2017-04-24 Y. Tsukioka , H. Nakada

The Hartree-Fock based diagonalization is a computational method for the investigation of the low-energy properties of correlated electrons in disordered solids. The method is related to the quantum-chemical configuration interaction…

Disordered Systems and Neural Networks · Physics 2007-05-23 Michael Schreiber , Thomas Vojta

We study the quantum dynamics of a large number of interacting fermionic particles in a constant magnetic field. In a coupled mean-field and semiclassical scaling limit, we show that solutions of the many-body Schr\"odinger equation…

Mathematical Physics · Physics 2025-03-24 Niels Benedikter , Chiara Boccato , Domenico Monaco , Ngoc Nhi Nguyen

A self-consistent, non-perturbative scheme of approximation is proposed for arbitrary interacting quantum systems by generalization of the Hartree method.The scheme consists in approximating the original interaction term $\lambda H_I$ by a…

Quantum Physics · Physics 2007-05-23 B. P. Mahapatra , N. Santi , N. B. Pradhan

We present a density matrix approach for computing global solutions of Hartree-Fock theory, based on semidefinite programming (SDP), that gives upper and lower bounds on the Hartree-Fock energy of quantum systems. Equality of the upper- and…

Chemical Physics · Physics 2014-02-11 Srikant Veeraraghavan , David A. Mazziotti

The reconstruction of the neutrino energy is crucial in oscillation experiments that use interactions with nuclei to detect the neutrino. The common reconstruction procedure is based on the kinematics of the final-state lepton. The…

When using Hartree-Fock (HF) trial wave functions in quantum Monte Carlo calculations, one faces, in case of HF instabilities, the HF symmetry dilemma in choosing between the symmetry-adapted solution of higher HF energy and symmetry-broken…

Chemical Physics · Physics 2011-07-19 Peter Reinhardt , Julien Toulouse , Roland Assaraf , C. J. Umrigar , Philip E. Hoggan

Complex conjugation symmetry breaking and restoration generate two non-orthogonal configurations at the Hartree-Fock level that can capture static correlation naturally. In conjunction with broken spin-symmetry coupled cluster theory, the…

Strongly Correlated Electrons · Physics 2024-07-18 Ruiheng Song , Thomas M. Henderson , Gustavo E. Scuseria

The density of an atom in a state of well-defined angular momentum has a specific finite spherical harmonic content, without and with interactions. Approximate single-particle schemes, such as the Hartree, Hartree-Fock, and Local Density…

Materials Science · Physics 2009-02-05 H. A. Fertig , W. Kohn

An ab initio Wannier-function-based approach to electronic ground-state calculations for crystalline solids is outlined. In the framework of the linear combination of atomic orbitals method the infinite character of the solid is rigorously…

Condensed Matter · Physics 2009-10-31 Martin Albrecht , Alok Shukla , Michael Dolg , Peter Fulde , Hermann Stoll

$\mathcal{PT}$-symmetry --- invariance with respect to combined space reflection $\mathcal{P}$ and time reversal $\mathcal{T}$ --- provides a weaker condition than (Dirac) Hermiticity for ensuring a real energy spectrum of a general…

Chemical Physics · Physics 2020-06-05 Hugh G. A. Burton , Alex J. W. Thom , Pierre-François Loos

This article is concerned with the derivation and the mathematical study of a new mean-field model for the description of interacting electrons in crystals with local defects. We work with a reduced Hartree-Fock model, obtained from the…

Mathematical Physics · Physics 2009-02-06 Eric Cancès , Amélie Deleurence , Mathieu Lewin

We develop a new method of implementing the Hartree-Fock calculations. A class of Gaussian bases is assumed, which includes the Kamimura-Gauss basis-set as well as the set equivalent to the harmonic-oscillator basis-set. By using the…

Nuclear Theory · Physics 2011-07-19 H. Nakada , M. Sato

We use a method based on metadynamics to locate multiple low-energy Unrestricted Hartree--Fock (UHF) self-consistent-field (SCF) solutions of two model octahedral $d^1$ and $d^2$ transition-metal complexes, $[\mathrm{MF}_6]^{3-} (\mathrm{M}…

Chemical Physics · Physics 2019-12-12 Bang C. Huynh , Alex J. W. Thom

A method for constructing semianalytical strongly correlated wave functions for single and molecular quantum dots is presented. It employs a two-step approach of symmetry breaking at the Hartree-Fock level and of subsequent restoration of…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Constantine Yannouleas , Uzi Landman

I review results concerning the derivation of effective equations for the dynamics of interacting Fermi gases in a high-density regime of mean-field type. Three levels of effective theories, increasing in precision, can be distinguished:…

Mathematical Physics · Physics 2022-08-17 Niels Benedikter

The $\lambda \phi^4$ model in a finite volume is studied within a non-gaussian Hartree-Fock approximation (tdHF) both at equilibrium and out of equilibrium, with particular attention to the structure of the ground state and of certain…

High Energy Physics - Phenomenology · Physics 2009-10-31 C. Destri , E. Manfredini