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A key to building functional devices on the basis of single molecule magnets in the framework of molecular electronics is the ability to deposit and study these molecules on a surface, because the structural, electronic and magnetic…

Mesoscale and Nanoscale Physics · Physics 2016-01-26 Judith Donner , Jan-Philipp Broschinski , Bastian Feldscher , Anja Stammler , Hartmut Bögge , Thorsten Glaser , Daniel Wegner

A comprehensive review is presented of single molecule junction conductance measurements across families of molecules measured while breaking a gold point contact in a solution of molecules with amine end groups. A theoretical framework…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Mark S. Hybertsen , Latha Venkataraman , Jennifer E. Klare , Adam C. Whalley , Michael L. Steigerwald , Colin Nuckolls

The state of the art ab initio calculations reveal the effect of a scanning tunnelling microscopy tip on magnetic properties and conductance of a benzene-adatom sandwich on Cu(001). We concentrate on a benzene-Co system interacting with a…

Materials Science · Physics 2009-11-13 Kun Tao , V. S. Stepanyuk , P. Bruno , D. I. Bazhanov , V. V. Maslyuk , M. Brandbyge , I. Mertig

Inelastic tunneling through magnetically anisotropic molecules is studied theoretically in the presence of a strong magnetic field. Since the molecular orientation is not well controlled in tunneling experiments, we consider arbitrary…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Carsten Timm

We present an original method to estimate the conductivity of a single molecule anchored to nanometric-sized metallic electrodes, using a Mechanically Controlled Break Junction (MCBJ) operated at room temperature in liquid. We record the…

Mesoscale and Nanoscale Physics · Physics 2018-03-16 M. Gil , T. Malinowski , M. Iazykov , H. Klein

The realization of single-molecule thermal conductance measurements has driven the need for theoretical tools to describe conduction processes that occur over atomistic length scales. In macroscale systems, the principle that is typically…

Mesoscale and Nanoscale Physics · Physics 2023-05-17 Galen T. Craven , Abraham Nitzan

Ionic gating is a very popular tool to investigate and control the electric charge transport and electronic ground state in a wide variety of different materials. This is due to its capability to induce large modulations of the surface…

Superconductivity · Physics 2021-05-27 Erik Piatti

The influence of vibrational motion on electron conduction through single molecules bound to metal electrodes is investigated employing first-principles electronic-structure calculations and projection-operator Green's function methods.…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 C. Benesch , M. Thoss , W. Domcke , M. Cizek

The possibility of using single molecule junctions as electron pumps for energy conversion and storage is considered. It is argued that the small dimensions of these systems enable to make use of unique intra-molecular quantum coherences in…

Quantum Physics · Physics 2015-05-20 Roie Volkovich , Uri Peskin

Temperature ($T$) dependent conductance $G = G(T)$ data measured in molecular junctions are routinely taken as evidence for a two-step hopping mechanism. The present paper emphasizes that this is not necessarily the case. A curve of $\ln G$…

Mesoscale and Nanoscale Physics · Physics 2022-12-01 Ioan Baldea

Understanding of charge transport mechanisms in nanoscale structures is essential for the development of molecular electronic devices. Charge transport through 1D molecular systems connected between two contacts is influenced by several…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Daijiro Nozaki , Horacio M. Pastawski , Gianaurelio Cuniberti

A detailed computational analysis has been performed, considering copper atomic contacts that are exposed directly to water molecules, hydroxyl groups, and monatomic as well as molecular hydrogen and oxygen species. The optimized physical…

Chemical Physics · Physics 2020-02-28 Firuz Demir , Kevin Dean , George Kirczenow

The electronic conduction of a novel, three-terminal molecular architecture, analogous to a heterojunction bipolar transistor is studied. In this architecture, two diode arms consisting of donor-acceptor molecular wires fuse through a ring,…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Haiying He , Ravindra Pandey , Shashi P. Karna

Electronic conductance through a single molecule is sensitive towards its structural orientation between two electrodes, owing to the distribution of molecular orbitals and their coupling to the electrode levels, that are governed by…

Mesoscale and Nanoscale Physics · Physics 2023-08-11 Koushik R. Das , Sudipta Dutta

We present measurements of magnetic tunnel junctions made using a self-assembled-monolayer molecular barrier. Ni/octanethiol/Ni samples were fabricated in a nanopore geometry. The devices exhibit significant changes in resistance as the…

Mesoscale and Nanoscale Physics · Physics 2010-10-05 J. R. Petta , S. K. Slater , D. C. Ralph

We studied the noise spectra of molecule-free and molecule-containing mechanically controllable break junctions. Both types of junctions revealed typical 1/ f noise characteristics at different distances between the contacts with square…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 V. A. Sydoruk , D. Xiang , S. A. Vitusevich , M. V. Petrychuk , A. Vladyka , Y. Zhang , A. Offenhäusser , V. A. Kochelap , A. E. Belyaev , D. Mayer

Tunneling of electrons through rotor-stator anthracene aldehyde molecular interfaces is studied with a combined ab initio and model approach. Molecular electronic structure calculated from first principles is utilized to model different…

Chemical Physics · Physics 2016-05-27 Irina Petreska , Vladimir Ohanesjan , Ljupco Pejov , Ljupco Kocarev

We study spin transport in normal/ferromagnetic/normal graphene junctions where a gate electrode is attached to the ferromagnetic graphene. We find that due to the exchange field of the ferromagnetic graphene, spin current through the…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Takehito Yokoyama

We show that the direction of coherent electron transport across a cyclic system of quantum dots or a cyclic molecule can be modulated by an external magnetic field if the cycle has an odd number of hopping sites, but the transport becomes…

Mesoscale and Nanoscale Physics · Physics 2015-06-19 Josep Planelles , Juan I. Climente

Combined diverse two-dimensional (2D) materials for semiconductor interfaces are attractive for electrically controllable carrier confinement to enable excellent electrostatic control. We investigated the transport characteristic in…

Mesoscale and Nanoscale Physics · Physics 2021-03-22 Rahul Tripathi , Pritam Bhattacharyya , Sukanta Nandi , Alok Shukla , Abha Misra
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