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The search for energy-efficient and environmentally friendly cooling technologies is a key driver for the development of magnetic refrigeration based on the magnetocaloric effect (MCE). This phenomenon arises from the interplay between…

In this article, our recent progresses about the effects of atomic substitution, magnetic field and temperature on the magnetic and magnetocaloric properties of the LaFe13-xAlx compounds are reviewed. With the increase of aluminum content,…

Materials Science · Physics 2012-12-04 Shen Bao-Gen , Hu Feng-Xia , Dong Qiao-Yan , Sun Ji-Rong

Magnetic refrigeration based on the magnetocaloric effect (MCE) of materials is a potential technique that has prominet advantages over the currently used gas compression-expansion technique in the sense of its high efficiency and…

Materials Science · Physics 2023-10-18 B. G. Shen , J. R. Sun , F. X. Hu , H. W. Zhang , Z. H. Cheng

The efficient coupling between lattice degrees of freedom and spin degrees of freedom in magnetic materials can be used for refrigeration and energy conversion. This coupling is enhanced in materials exhibiting the giant magnetocaloric…

We report on structural, magnetic and magnetocaloric properties of MnxFe1.95-xP0.50Si0.50 (x > 1.10) compounds. With increasing the Mn:Fe ratio, a first-order magneto-elastic transition gradually changes into a first-order…

Materials Science · Physics 2012-06-01 N. H. Dung , L. Zhang , Z. Q. Ou , E. Brück

The mechanisms underlying the enhancement of magnetic anisotropies (MAs) of Sm ions, owing to valence electrons at the Sm site and the screened nuclear charges of ligands, are clarified using a detailed analysis of crystal fields (CF). In…

Materials Science · Physics 2022-01-12 Takuya Yoshioka , Hiroki Tsuchiura , Pavel Novák

The structural transitions, magnetic properties, and electronic structures of Co(Fe)-doped MnNiSi compounds are investigated by x-ray powder diffraction (XRD), differential scanning calorimetry (DSC), magnetic measurements, and…

Materials Science · Physics 2015-04-17 Y. Li , Z. Y. Wei , E. K. Liu , G. D. Liu , S. G. Wang , W. H. Wang , G. H. Wu

Magnetic entropy and adiabatic temperature changes in and above the room-temperature region has been measured for La0.7Sr0.3Mn1-xM'xO3 (M' = Al, Ti) by means of magnetization and heat capacity measurements in magnetic fields up to 6 T. The…

Materials Science · Physics 2007-08-17 D. N. H. Nam , N. V. Dai , L. V. Hong , N. X. Phuc , S. C. Yu , M. Tachibana , E. Takayama-Muromachi

Magnetocaloric cooling offers the potential to improve the efficiency of refrigeration devices and hence cut the significant CO2 emissions associated with cooling processes. A critical issue in deployment of this technology is the…

This work investigates the magnetocaloric effect (MCE) in LaFe_{11.6}Si_{1.4} and LaFe_{11.78}Mn_{0.41}Si_{1.32}H_{1.6} alloys under adiabatic {\Delta}T and isothermal {\Delta}Q conditions in a magnetic field of {\mu}_{0}H = 1.8 T. The…

La(Fe,Si)$_{13}$-based compounds are considered to be very promising magnetocaloric materials for magnetic refrigeration applications. Many studies have focused on this material family but only in bulk form. In this paper, we report the…

Materials Science · Physics 2020-06-03 N. H. Dung , N. B. Doan , P. De Rango , L. Ranno , K. G. Sandeman , N. M. Dempsey

We report the evolution of structural and magnetic properties in La2O3(Fe1-xMnx)2Se2. Heat capacity and bulk magnetization indicate an increased ferromagnetic component of the long-range magnetic order and possible increased degree of…

Strongly Correlated Electrons · Physics 2012-10-10 Hechang Lei , Emil S. Bozin , A. Llobet , V. Ivanovski , V. Koteski , J. Belosevic Cavor , B. Cekic , C. Petrovic

By combination of two independent approaches, nuclear resonant inelastic X-ray scattering and first-principles calculations in the framework of density functional theory, we determine the element-resolved vibrational density of states in…

We present extensive X-ray Absorption Fine Structure (XAFS) measurements on La_{1-x}Ca_xMnO_3 as a function of B-field (to 11T) and Ca concentration, x (21-45%). These results reveal local structure changes (associated with polaron…

Materials Science · Physics 2009-11-10 L. Downward , F. Bridges , S. Bushart , J. J. Neumeier , N. Dilley , L. Zhou

In this paper we attempt to understand the different nature of first order magnetic transformation in Mn$_3$SnC as compared to that in Mn$_3$GaC. The transformation in Mn$_3$SnC is close to room temperature (T$_t \approx$ 280K) and is…

Materials Science · Physics 2015-06-30 E. T. Dias , K. R. Priolkar , A. Das , G. Aquilanti , Ö. Çakir , M. Acet , A. K. Nigam

The crystal structure and magnetic properties of MnCoxFe1-xSi (x=0-0.5) compounds were investigated. With increasing Fe content, the unit cell changes anisotropically and the magnetic property evolves gradually: Curie temperature decreases…

We have studied the effect of Fe substitution on magnetic and magnetocaloric properties in La0.7Sr0.3Mn1-xFexO3 (x = 0.05, 0.07, 0.10, 0.15, and 0.20) over a wide temperature range (T = 10-400 K). It is shown that substitution by Fe…

Materials Science · Physics 2009-09-28 C. Krishnamoorthi , S. K. Barik , R. Mahendiran

We have studied selected rare earth doped and transition metal doped CeFe2 compounds by examining their structural, magnetic and magneto-thermal properties. With substitution of Ce by 5 and 10% Gd and 10% Ho, the Curie temperature can be…

Strongly Correlated Electrons · Physics 2015-05-19 Arabinda Haldar , K. G. Suresh , A. K. Nigam

We have studied the crystal and magnetic structures of Fe-doped hexagonal manganites LuMn1-xFexO3 (x = 0, 0.1, 0.2, and 0.3) by using bulk magnetization and neutron powder diffraction methods. The samples crystalize consistently in a…

A study investigating the effect of Sn substitution on the magnetocaloric properties of Mn$ _{3} $Ga$ _{(1-x)} $Sn$ _{x} $C compounds reveals that nature of the MCE has a strong dependence on the nature of the magnetic ordering. For small…

Materials Science · Physics 2015-06-30 E. T. Dias , K. R. Priolkar , O. Cakir , M. Acet , A. K. Nigam
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