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We examine the robustness of single-molecule tunneling diodes to thermal-environmental effects. The diode comprises three fragments: two different conjugated chemical groups at the boundaries, and a saturated moiety in between, breaking…

Mesoscale and Nanoscale Physics · Physics 2015-12-29 Michael Kilgour , Dvira Segal

The electrostatic screening properties of ionic fluids are of paramount importance in countless physical processes. Yet, the behavior of ionic conductors out of thermal equilibrium has to date mainly been studied in the context of…

Statistical Mechanics · Physics 2023-04-19 Andrea Grisafi , Federico Grasselli

We have developed a theory of the anomalous Hall effect in two-dimensional electron gas in the case where the time of electron-electron collisions is much smaller than the transport relaxation time. The transition between the diffusion…

Mesoscale and Nanoscale Physics · Physics 2023-10-30 D. S. Zohrabyan , M. M. Glazov

The particle diffusion in a fluid is a classical topic that dates back to more than one century ago. However, a full solution to this issue still lacks. In this work the velocity autocorrelation function and the diffusion constant are…

Fluid Dynamics · Physics 2016-08-03 Hanqing Zhao , Hong Zhao

Thermodiffusion in aqueous electrolyte solutions exhibits complex dependencies on temperature, concentration, and salt composition, yet its microscopic origins remain incompletely understood. Here, we employ non-equilibrium molecular…

Soft Condensed Matter · Physics 2026-04-21 Guansen Zhao , Fernando Bresme

Continuum simulation is employed to study ion transport and fluid flow through a nanopore in a solid-state membrane under an applied potential drop. Results show the existence of concentration polarization layers on the surfaces of the…

Fluid Dynamics · Physics 2015-06-16 Mao Mao , Sandip Ghosal , Guohui Hu

We investigate the minimal requirements that induce a nonreciprocal response to temperature differences in a mesoscopic electronic conductor. We identify two distinct mechanisms involved in electron-electron interactions, namely inelastic…

Mesoscale and Nanoscale Physics · Physics 2025-05-12 José Balduque , Rafael Sánchez

A simple theory of ion permeation through a channel is presented, in which diffusion occurs according to Fick's law and drift according to Ohm's law, in the electric field determined by all the charges present. This theory accounts for…

Biomolecules · Quantitative Biology 2016-10-17 Bob Eisenberg

The effect of an axial temperature gradient on the flow profile and the induced streaming potential of a pressure-driven symmetric electrolyte in a slit channel is investigated. Based on the non-isothermal Nernst-Planck equations as well as…

Fluid Dynamics · Physics 2020-06-26 Mathias Dietzel , Steffen Hardt

Dipole-conserving fluids serve as examples of kinematically constrained systems that can be understood on the basis of symmetry. They are known to display various exotic features including glassylike dynamics, subdiffusive transport, and…

Strongly Correlated Electrons · Physics 2023-04-18 Aleksander Głódkowski , Francisco Peña-Benítez , Piotr Surówka

The ability to induce regions of high and low ionic concentration adjacent to a permeselective membrane or nanochannel subject to an externally applied electric field (a phenomenon termed concentration-polarization) has been used for a…

Fluid Dynamics · Physics 2018-03-12 Sinwook Park , Gilad Yossifon

Molten salts are important in a number of energy applications, but the fundamental mechanisms operating in ionic liquids are poorly understood, particularly at higher temperatures. This is despite their candidacy for deployment in solar…

The static dielectric properties of dense ionic fluids, e.g., room temperature ionic liquids (RTILs) and inorganic fused salts, are investigated on different length scales by means of grandcanonical Monte Carlo simulations. A generally…

Soft Condensed Matter · Physics 2015-05-14 Grigory Zarubin , Markus Bier

Molecular dynamics simulations for aqueous sodium chloride solutions were carried out at various concentrations. Supplementary to the Debye-H\"uckel theory, reversible transient nucleation of ions was observed even in dilute solutions. The…

Soft Condensed Matter · Physics 2014-11-26 Gan Ren , Yanting Wang

Solid-state electrolytes, by enabling lithium metal anodes, may significantly increase the energy density of current lithium-ion batteries. However, similar to their liquid counterparts, these hard and stiff electrolytes can still be…

Chemical Physics · Physics 2024-10-04 Rajeev Gopal , Longan Wu , Youngju Lee , Jinzhao Guo , Peng Bai

We use fluctuating hydrodynamics to analyze the dynamical properties in the non-equilibrium steady state of a diffusive system coupled with reservoirs. We derive the two-time correlations of the density and of the current in the…

Statistical Mechanics · Physics 2016-11-23 Tridib Sadhu , Bernard Derrida

Solute-surface interactions have garnered considerable interest in recent years as a novel control mechanism for driving unique fluid dynamics and particle transport with potential applications in fields such as biomedicine, the development…

Fluid Dynamics · Physics 2023-05-05 Jian Teng , Bhargav Rallabandi , Jesse T. Ault

The drift and diffusion of a cloud of ions in a fluid are distorted by an inhomogeneous electric field. If the electric field carries the center of the distribution in a straight line and the field configuration is suitably symmetric, the…

Instrumentation and Detectors · Physics 2009-11-13 R. N. Cahn , J. D. Jackson

The description of molecular motion by macroscopic hydrodynamics has a long and continuing history. The Stokes-Einstein relation between the diffusion coefficient of a solute and the solvent viscosity predicted using macroscopic continuum…

Disordered Systems and Neural Networks · Physics 2007-05-23 Xiaoyu Xia , Peter G. Wolynes

We discuss the interplay between transport and intrinsic dissipation in quantum Hall bilayers, within the framework of a simple thought experiment. We compute, for the first time, quantum corrections to the semiclassical dynamics of this…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Robert L. Jack , Derek K. K. Lee , Nigel R. Cooper
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