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Detecting the internal state of polar molecules is a substantial challenge when standard techniques such as resonance-enhanced multi photon ionization (REMPI) or laser-induced fluorescense (LIF) do not work. As this is the case for most…
This perspective provides a brief introduction into the theoretical complexity of polaritonic chemistry, which emerges from the hybrid nature of strongly coupled light-matter states. To tackle this complexity, the importance of ab initio…
The rovibrational kinetic energy for an arbitrary number of rigid molecules is computed. The result has the same general form as the kinetic energy in the molecular rovibrational Hamiltonian, although certain quantities are augmented to…
We show that by manipulating quantum interference in a multi-atom cavity QED system, the nonlinear excitation of the cavity-atom polariton can be resonantly enhanced while the linear excitation is suppressed. Under appropriate conditions,…
A quantum system composed of a molecule and an atomic ensemble, confined in a microscopic cavity, is investigated theoretically. The indirect coupling between atoms and the molecule, realized by their interaction with the cavity radiation…
Fabry-Perot microcavities can strongly enhance interactions between light and molecules, leading to the formation of hybrid light-matter states known as polaritons. Polaritons possess much smaller effective masses and much larger group…
Quantum dynamics of the photoisomerization of a single 3,3'-diethyl-2,2'-thiacynine iodide molecule embedded in an optical microcavity was theoretically studied. The molecule was coupled to a single cavity mode via the quantum Rabi…
We investigate the multi-photon resonance and multi-ion excitation in a single-mode cavity with identical vibrating ion-qubits, which enables the tripartite interaction among the internal states of ions, the cavity mode and the ions'…
A calculation of dynamic polarizabilities of rovibrational states with vibrational quantum number $v=0-7$ and rotational quantum number $J=0,1$ in the 1s$\sigma_g$ ground-state potential of HD$^+$ is presented. Polarizability contributions…
Intermolecular van der Waals interactions are central to chemical and physical phenomena ranging from biomolecule binding to soft-matter phase transitions. However, there are currently very limited approaches to manipulate van der Waals…
We study a system of interacting matter quasiparticles strongly coupled to photons inside an optomechanical cavity. The resulting normal modes of the system are represented by hybrid polaritonic quasiparticles, which acquire effective…
In this work, we develop an optomechanical formalism for macroscopic quantum states in exciton-polariton systems with strong exciton-phonon interactions. We show that polariton optomechanical interactions induce dynamical backaction,…
We explore the electroluminescence efficiency for a quantum mechanical model of a large number of molecular emitters embedded in an optical microcavity. We characterize the circumstances under which a microcavity enhances harvesting of…
Strong coupling between light and matter is possible with a variety of organic materials. In contrast to the simpler inorganic case, organic materials often have a complicated spectrum, with vibrationally dressed electronic transitions.…
We consider the use of pulse-shaped broadband femtosecond lasers to optically cool rotational and vibrational degrees of freedom of molecules. Since this approach relies on cooling rotational and vibrational quanta by exciting an electronic…
The nonlinear optical response of organic polaritonic matter has received increasing attention due to their enhanced and controllable nonlinear response and their potential for novel optical devices such as compact photon sources and…
The Dicke-Ising model describes cavity quantum electrodynamics setups in which dipoles couple not only with the photonic cavity field but also to each other through dipole-dipole interaction. In this work we diagonalise such a model in…
We study a hybrid semiconductor-optomechanical system, which consists of a cavity with an oscillating mirror made by semiconducting materials or with a semiconducting membrane inside. The cavity photons and the excitons in the oscillating…
We propose an optomechanical scheme for reaching quantum entanglement in vibration polaritons. The system involves $N$ molecules, whose vibrations can be fairly entangled with plasmonic cavities. We find that the vibration-photon…
An effective Hamiltonian without symmetry restriction has been developed to model the rotational and fine structure of two nearly degenerate electronic states of an open-shell molecule. In addition to the rotational Hamiltonian for an…