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We present a first-principles scheme for computing the magnetoelectric response of multiferroics. We apply our method to BiFeO3 (BFO) and related compounds in which Fe is substituted by other magnetic species. We show that under certain…

Materials Science · Physics 2012-04-17 Jacek C. Wojdel , Jorge Iniguez

We present a first-principles study of ferroelectric domain walls (FE-DWs) in multiferroic BiFeO$_3$ (BFO), a material in which the FE order parameter coexists with anti-ferrodistortive (AFD) modes involving rotations of the O$_6$…

Materials Science · Physics 2015-06-12 Oswaldo Diéguez , Pablo Aguado-Puente , Javier Junquera , Jorge Íñiguez

We present results of an {\it ab initio} density functional theory study of three bismuth-based multiferroics, BiFeO$_{3}$, Bi$_{2}$FeCrO$_{6}$, and BiCrO$_{3}$. We disuss differences in the crystal and electronic structure of the three…

Materials Science · Physics 2007-05-23 Pio Baettig , Claude Ederer , Nicola A. Spaldin

Epitaxial strain has emerged as a powerful tool to tune magnetic and ferroelectric properties in functional materials such as in multiferroic perovskite oxides. Here, we use first-principles calculations to explore the evolution of magnetic…

Materials Science · Physics 2023-11-23 Sebastian Meyer , Bin Xu , Laurent Bellaiche , Bertrand Dupé

Given the paucity of single phase multiferroic materials (with large ferromagnetic moment), composite systems seem an attractive solution in the quest to realize magnetoelectric cou-pling between ferromagnetic and ferroelectric order…

Mesoscale and Nanoscale Physics · Physics 2014-09-15 P. Jain , Q. Wang , M. Roldan , A. Glavic , V. Lauter , C. Urban , Z. Bi , T. Ahmed , J. Zhu , M. Varela , Q. Jia , M. R. Fitzsimmons

We analyze the coupling between the ferroelectric and magnetic order parameters in the magnetoelectric multiferroic BiFeO_3 using density functional theory within the local spin density approximation and the LSDA+U method. We show that weak…

Materials Science · Physics 2007-05-23 Claude Ederer , Nicola A. Spaldin

Recently, oxide multiferroics have attracted much attention due to their large magnetoelectric effect which allows the tuning of magnetic properties with electric field and vice versa and open new venues for future spintronic applications…

Strongly Correlated Electrons · Physics 2010-10-12 M. Cazayous , Y. Gallais , A. Sacuto , R. De Sousa , D. Lebeugle , D. Colson

We calculate the exact analytical solution to the domain wall properties in a multiferroic system with two order parameters that are coupled bi-quadratically. This is then adapted to the case of a magnetoelectric multiferroic material such…

Materials Science · Physics 2013-05-29 Maren Daraktchiev , Gustau Catalan , James F. Scott

First-principles calculations, in combination with the four-state energy mapping method, are performed to extract the magnetic interaction parameters of multiferroic BiFeO$_3$. Such parameters include the symmetric exchange (SE) couplings…

Materials Science · Physics 2019-03-20 Changsong Xu , Bin Xu , Bertrand Dupé , L. Bellaiche

We study the electrical behavior of multiferroic BiFeO$_3$ by means of first-principles calculations. We do so by constraining a specific component of the electric displacement field along a variety of structural paths, and by monitoring…

Materials Science · Physics 2016-01-20 Massimiliano Stengel , Jorge Íñiguez

BiFeO3 is a model multiferroic in which the ferroelectric polarization is coupled to ferroelastic lattice distortions, yet deterministic control of its domain structure remains limited by high switching fields and competing polarization…

We present a detailed study of the structural, electronic, magnetic and ferroelectric properties of prototypical \textit{proper} and \textit{improper} multiferroic (MF) systems such as BiFeO$_{3}$ and orthorhombic HoMnO$_{3}$, respectively,…

Materials Science · Physics 2017-03-15 A. Stroppa , S. Picozzi

We have studied the magnetic field dependence of far-infrared active magnetic modes in a single ferroelectric domain \BFO/ crystal at low temperature. The modes soften close to the critical field of 18.8\,T along the [001] (pseudocubic)…

Strongly Correlated Electrons · Physics 2013-06-26 U. Nagel , Randy S. Fishman , T. Katuwal , H. Engelkamp , D. Talbayev , Hee Taek Yi , S. -W. Cheong , T. Rõõm

Bismuth ferrite is one of the most widely studied multiferroic materials because of its large ferroelectric polarisation coexisting with magnetic order at room temperature. Using density functional theory (DFT), we identify several…

Materials Science · Physics 2021-05-12 Bastien F. Grosso , Nicola A. Spaldin

Multiferroics have received intense attention due to their great application potential in multi-state information storage devices and new types of sensors. Coupling among ferroic orders such as ferroelectricity, (anti-)ferromagnetism,…

In this work, we report a massively parallel and time domain implementation of the 3D phase field model that can reach beyond micron scale and consider for arbitrary electrical and mechanical boundary conditions. The first part of the paper…

Materials Science · Physics 2012-03-27 Khalid Ashraf , Sayeef Salahuddin

The presence of domains in ferroic materials can negatively affect their macroscopic properties and hence their usefulness in device applications. From an experimental perspective, measuring materials comprising multiple domains can…

Strongly Correlated Electrons · Physics 2019-02-20 N. Waterfield Price , A. M. Vibhakar , R. D. Johnson , J. Schad , W. Saenrang , A. Bombardi , F. P. Chmiel , C. B. Eom , P. G. Radaelli

Materials with coexisting and coupled ferroelectric and magnetic orders are rare. Here we show, using density functional theory calculations, that inducing Fe$_\mathrm{La}$ antisites into non-ferroelectric and antiferromagnetic LaFeO$_3$…

Materials Science · Physics 2025-08-13 Souren Majani , Harish K. Singh , Ulrich Aschauer

Magnetoelectric multiferroics, materials with intrinsically coupled electric polarization and magnetic order, promise ultralow-power switching, nonvolatile memory, and energy-efficient signal transduction. Yet practical deployment demands…

Understanding the magnetic and ferroelectric ordering of magnetoelectric multiferroic materials at the nanoscale necessitates a versatile imaging method with high spatial resolution. Here, soft X-ray ptychography is employed to…

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