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Band structure of inorganic lead halide perovskites is substantially different from the band structure of group IV, III-V and II-VI semiconductors. However, the standard empirical tight-binding model with sp3d5s* basis gives nearly perfect…

Mesoscale and Nanoscale Physics · Physics 2023-09-12 M. O. Nestoklon

In this work we present a comparison of multiband k.p-models, the effective bond-orbital approach, and an empirical tight-binding model to calculate the electronic structure for the example of a truncated pyramidal GaN/AlN self-assembled…

Materials Science · Physics 2009-11-13 Oliver Marquardt , Daniel Mourad , Stefan Schulz , Tilmann Hickel , Gerd Czycholl , Jörg Neugebauer

This paper summarises the theory and functionality behind Questaal, an open-source suite of codes for calculating the electronic structure and related properties of materials from first principles. The formalism of the linearised muffin-tin…

First-principles calculations using the plane-wave pseudopotential method within the generalized gradient approximation method were performed to study the pressure dependence of the structural, elastic, electronic and optical properties for…

Materials Science · Physics 2021-12-21 M. Radjai , A. Bouhemadou , D. Maouche

Tight-binding models provide great insight and are a low-cost alternative to \emph{ab initio} methods for calculation of a material's electronic structure. These models are used to calculate optical responses, including nonlinear optical…

Materials Science · Physics 2025-09-29 Andreas Ghosh , Aaron M. Schankler , Andrew M. Rappe

As a second part of a previous paper, here the calculated electronic band structure of ideal Pt(100) and Pt(110) surfaces, studied using density functional theory and the empirical tight-binding method, is presented. A detailed discussion…

Materials Science · Physics 2015-03-17 H. J. Herrera-Suarez , A. Rubio-Ponce , D. Olguin

A key objective of computational solid state physics is to predict electronic properties of periodic materials. However, electronic structure simulations based on density functional theory fail to predict experimental results if…

Titanium dioxide is one of the most widely investigated oxides. This is due to its broad range of applications, from catalysis to photocatalysis to photovoltaics. Despite this large interest, many of its bulk properties have been sparsely…

Materials Science · Physics 2010-03-12 L. Chiodo , J. M. García-Lastra , D. J. Mowbray , A. Iacomino , A. Rubio

Finite-temperature calculations are relevant for rationalizing material properties yet they are computationally expensive because large system sizes or long simulation times are typically required. Circumventing the need for performing many…

We have examined a method of direct extraction of accurate tight-binding parameters from an ab-initio band-structure calculation. The linear muffin-tin potential method, in its full-potential implementation, has been used to provide the…

Materials Science · Physics 2015-06-24 David Djajaputra , Bernard R. Cooper

Harrison's tight-binding theory provides an excellent qualitative description of the electronic structure of the elements across the periodic table. However, the resulting band structures are in significant disagreement with those found by…

Materials Science · Physics 2009-11-10 L. Shi , D. A. Papaconstantopoulos

In this paper we analyze the band-structure of two-dimensional (2D) halide perovskites by considering structures related to the simpler case of the series, (BA)$_2$PbI$_4$, in which PbI$_4$ layers are intercalated with butylammonium…

Materials Science · Physics 2023-07-24 Efstratios Manousakis

We present optimized tight-binding models with atomic orbitals to improve \textit{ab initio} tight-binding models constructed by truncating full density functional theory (DFT) Hamiltonian based on localized orbitals. Retaining qualitative…

Mesoscale and Nanoscale Physics · Physics 2024-02-20 Sejoong Kim

We present the AMBiT software package for general atomic structure calculations. This software implements particle-hole configuration interaction with many-body perturbation theory (CI+MBPT) for fully relativistic calculations of atomic…

Atomic Physics · Physics 2019-01-15 E. V. Kahl , J. C. Berengut

An empirical $s_cp^3_a$ tight-binding (TB) model is applied to the investigation of electronic states in semiconductor quantum dots. A basis set of three $p$-orbitals at the anions and one $s$-orbital at the cations is chosen. Matrix…

Other Condensed Matter · Physics 2009-11-11 Stefan Schulz , Gerd Czycholl

A computationally efficient workflow for obtaining the low-energy symmetric tight-binding Hamiltonians for twisted multilayer systems is presented in this work. We apply this scheme to twisted bilayer graphene at the first magic angle. As…

Strongly Correlated Electrons · Physics 2022-11-24 Arkadiy Davydov , Kenny Choo , Mark H. Fischer , Titus Neupert

We introduce a minimum tight-binding model with only three parameters extracted from graphene and untwisted bilayer graphene. This model reproduces quantitatively the electronic structure of not only these two systems and bulk graphite near…

Mesoscale and Nanoscale Physics · Physics 2018-09-12 Xianqing Lin , David Tománek

Li2Pd3B is known to be superconducting, while the isotypical Li2Pt3B compound is not. Electronic structures of Li2Pd3B and Li2Pt3B have been calculated in order to obtain an insight into this surprising difference, through an analysis of…

Superconductivity · Physics 2009-11-11 Sharat Chandra , S. Mathi Jaya , M. C. Valsakumar

The title material has a quasi-one-dimensional electronic structure and is of considerable interest because it has a metallic phase with properties different from a simple Fermi liquid, a poorly understood "insulating" phase, and a…

Strongly Correlated Electrons · Physics 2015-06-04 Jaime Merino , Ross H. McKenzie

Moving beyond traditional 2D materials is now desirable to have switching capabilities (e.g., transistors). Here we propose using borophene because, as we will show in this letter, obtaining regions of the electronic bandstructure which act…

Materials Science · Physics 2020-12-15 Clifford M. Krowne , Xianwei Sha