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The development of high-performance multifunctional polymer-based electronic circuits is a major step towards future flexible electronics. Here, we demonstrate a tunable approach to fabricate such devices based on rationally designed…

We investigate a nanoscale dielectric capacitor model consisting of two-dimensional, hexagonal h-BN layers placed between two commensurate and metallic graphene layers using self-consistent field density functional theory. The separation of…

Mesoscale and Nanoscale Physics · Physics 2013-07-30 V. Ongun Özçelik , S. Ciraci

Supercapacitors are energy storage devices able to deliver electricity with a high power. They consist of porous carbon electrodes in a concentrated electrolyte. Charged is stored by the adsorption of ions at the electrode surface.…

Chemical Physics · Physics 2018-11-26 Benjamin Rotenberg , Mathieu Salanne , Patrice Simon

Electric capacitors are commonly used in electronic circuits for short-term storage of small amounts of energy. It is desirable however to use capacitors to store much larger energy amounts to replace rechargeable batteries. Unfortunately,…

Mesoscale and Nanoscale Physics · Physics 2020-11-25 A. Bezryadin , A. Belkin , E. Ilin , M. Pak , Eugene V. Colla , A. Hubler

Supercapacitors are electric devices able to deliver a large power, enabling their use e.g. for the recovery of breaking energy in cars. This is achieved by using two carbon electrodes and an electrolyte solution or a pure ionic liquid…

Chemical Physics · Physics 2018-11-26 Céline Merlet , Clarisse Péan , Mathieu Salanne , Benjamin Rotenberg

Due to the shorter channel length allowing faster ion/charge movement, nanoscale molecular thin films can be attractive electronic components for next-generation high-performing energy storage devices. However, controlling chemical…

Applied Physics · Physics 2023-03-28 Ritu Gupta , Ankur Malik , Vincent Vivier , Prakash Chandra Mondal

The formation of well-defined three-dimensional (3D) redox-active molecular nanostructures at the electrode surfaces may open additional routes to achieve higher conductance in molecular junctions (MJs). We report here experimental and…

Materials Science · Physics 2023-11-30 Ritu Gupta , Shapath Bhandari , Savas Kaya , Konstantin P. Katin , Prakash Chandra Mondal

Nanoporous carbon-based supercapacitors store electricity through adsorption of ions from the electrolyte at the surface of the electrodes. Room temperature ionic liquids, which show the largest ion concentrations among organic liquid…

Modeling nanoscale capacitance presents particular challenge because of dynamic contribution from electrodes, which can usually be neglected in modeling macroscopic capacitance and nanoscale conductance. We present a model to calculate…

Materials Science · Physics 2013-10-03 Jun-Qiang Lu , Jonathan Gonzalez , Carlos Sierra , Yang Li

Supercapacitors have been attracting significant attention as promising energy storage devices. However, the voltage window limitation associated with electrolyte solutions has hindered the improvement of their capacitance. To address this…

Chemical Physics · Physics 2023-06-27 Weihang Gao , Teng Zhao , Shian Dong , Xingyi Huang , Zhenli Xu

The ability to control the conductance of single molecules will have a major impact in nanoscale electronics. Azobenzene, a molecule that changes conformation as a result of a trans/cis transition when exposed to radiation, could form the…

Mesoscale and Nanoscale Physics · Physics 2008-11-26 Miriam del Valle , Rafael Gutierrez , Carlos Tejedor , Gianaurelio Cuniberti

Ability to encapsulate molecules is one of the outstanding features of nanotubes. The encapsulation alters physical and chemical properties of both nanotubes and guest species. The latter normally form a separate phase, exhibiting…

Materials Science · Physics 2014-07-23 Vitaly Chaban , Oleg Prezhdo

We have fabricated air-stable n-type, ambipolar carbon nanotube field effect transistors (CNFETs), and used them in nanoscale memory cells. N-type transistors are achieved by annealing of nanotubes in hydrogen gas and contacting them by…

Mesoscale and Nanoscale Physics · Physics 2015-06-24 M. Radosavljevic , M. Freitag , K. V. Thadani , A. T. Johnson

Heterostructures constructed from two-dimensional building blocks have shown promise for field-effect transistors, memory devices, photosensors and other electronic applications1,2. 2D nanosheet crystals can be constructed into multilayer…

We propose a model for planar nanoscale dielectric capacitor consisting of a single layer, insulating hexagonal boron nitride (BN) stripe placed between two metallic graphene stripes, all forming commensurately a single atomic plane.…

Mesoscale and Nanoscale Physics · Physics 2015-06-02 V. Ongun Özçelik , S. Ciraci

In recent years, constant applied potential molecular dynamics has allowed to study the structure and dynamics of the electrochemical double-layer of a large variety of nanoscale capacitors. Nevertheless it remained impossible to simulate…

Materials Science · Physics 2021-09-03 Thomas Dufils , Michiel Sprik , Mathieu Salanne

Nanosized energy storage, energy-harvesting, and functional devices are the three key components for integrated self-power systems. Here, we report on nanoscale electrochemical devices with a nearly three-fold enhanced stored charge under…

Solid state ionic conductors are good candidates for the next generation of nonvolatile computer memory elements. Such devices have to show reproducible resistance switching at reasonable voltage and current values even if scaled down to…

Mesoscale and Nanoscale Physics · Physics 2011-04-25 A. Geresdi , A. Halbritter , A. Gyenis , P. Makk , G. Mihály

Achieving operating conditions comparable to ``bulk'' electronic devices, such as thin film capacitors, during \textit{operando} electron microscopy remains challenging, particularly when devices are grown on non-conductive substrates.…

Devices made of few molecules constitute the miniaturization limit that both inorganic and organic-based electronics aspire to reach. However, integration of millions of molecular junctions with less than 100 molecules each has been a long…

Mesoscale and Nanoscale Physics · Physics 2013-02-11 Kacem Smaali , Nicolas Clement , Gilles Patriarche , Dominique Vuillaume
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