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In 1939, von Neumann argued for the equivalence of the thermodynamic entropy and $-\text{Tr}\rho\ln\rho$, since known as the von Neumann entropy. Hemmo and Shenker (2006) recently challenged this argument by pointing out an alleged…

Quantum Physics · Physics 2023-06-22 Carina E. A. Prunkl

Recently, attention has returned to the now-famous 1932 thought experiment in which John von Neumann establishes the form of the quantum mechanical von Neumann entropy -Tr $ \rho \ln \rho $ ($S_{VN}$), supposedly by arguing for its…

History and Philosophy of Physics · Physics 2020-07-15 Erin Sheridan

Statistical formulations of thermodynamic entropy, such as those by Boltzmann and Gibbs, were originally developed for classical systems and are well understood in that context. However, the foundational aspects of quantum statistical…

Quantum Physics · Physics 2025-10-08 Smitarani Mishra , Shaon Sahoo

This paper is an introduction to the von Neumann entropy in a historic approach. Von Neumann's gedanken experiment is repeated, which led him to the formula of thermodynamic entropy of a statistical operator. In the analysis of his ideas we…

Mathematical Physics · Physics 2007-05-23 D. Petz

Given the algebra of observables of a quantum system subject to selection rules, a state can be represented by different density matrices. As a result, different von Neumann entropies can be associated with the same state. Motivated by a…

Quantum Physics · Physics 2021-05-25 Paolo Facchi , Giovanni Gramegna , Arturo Konderak

We develop the argument that the Gibbs-von Neumann entropy is the appropriate statistical mechanical generalisation of the thermodynamic entropy, for macroscopic and microscopic systems, whether in thermal equilibrium or not, as a…

Quantum Physics · Physics 2008-01-23 O. J. E. Maroney

Thermodynamic entropy, as defined by Clausius, characterizes macroscopic observations of a system based on phenomenological quantities such as temperature and heat. In contrast, information-theoretic entropy, introduced by Shannon, is a…

Quantum Physics · Physics 2017-01-04 Mirjam Weilenmann , Lea Krämer , Philippe Faist , Renato Renner

Entropy concept was introduced by Clausius 160 years ago, and has been continually enriched, developed and interpreted by the researchers in many different scientific disciplines ever since. Thermodynamics and other scientific disciplines…

Chemical Physics · Physics 2017-11-21 Marko Popovic

This thesis investigates the connection between quantum theory, thermodynamics and information theory. Theories with structure similar to that of quantum theory are considered, mathematically described by the framework of "Generalized…

Quantum Physics · Physics 2015-08-14 Marius Krumm

Quantum information-theoretic approach has been identified as a way to understand the foundations of quantum mechanics as early as 1950 due to Shannon. However there hasn't been enough advancement or rigorous development of the subject. In…

Quantum Physics · Physics 2018-07-04 Shubhayan Sarkar

We compare the thermodynamic entropy of a quantum Brownian oscillator derived from the partition function of the subsystem with the von Neumann entropy of its reduced density matrix. At low temperatures we find deviations between these two…

Quantum Physics · Physics 2009-11-13 Christian Hoerhammer , Helmut Buettner

We take the view that the standard von Neumann definition, in which the entropy $S^{vN}$ of a pure state is zero, is in evident conflict with the statement of the second law that the entropy of the universe $S_{univ}$ increases in…

Quantum Physics · Physics 2018-10-25 George L. Barnes , Phillip C. Lotshaw , Michael E. Kellman

Entropy and free energy are central concepts in both statistical physics and information theory, with quantum and classical facets. In mathematics these concepts appear quite often in different contexts (dynamical systems, probability…

Mathematical Physics · Physics 2025-10-20 Zied Ammari , Michele Correggi , Marco Falconi , Raphaël Gautier

The science of thermodynamics was put together in the Nineteenth Century to describe large systems in equilibrium. One part of thermodynamics defines entropy for equilibrium systems and demands an ever-increasing entropy for non-equilibrium…

Statistical Mechanics · Physics 2014-03-26 Leo P. Kadanoff

K. He, J. Hou, and M. Li have recently given a sufficient and necessary condition for unitary equivalence of quantum states. This condition is based on the von Neumann entropy. In this note we first give a short proof of their result, and…

Quantum Algebra · Mathematics 2013-12-10 Roman Drnovšek

We study the entropy of small subsystems in thermalizing quantum many-body systems governed by local Hamiltonians. Assuming the eigenstate thermalization hypothesis, we derive an analytical formula for the von Neumann entropy of…

Statistical Mechanics · Physics 2025-02-03 Yichen Huang

A microscopic understanding of the thermodynamic entropy in quantum systems has been a mystery ever since the invention of quantum mechanics. In classical physics, this entropy is believed to be the logarithm of the volume of phase space…

Quantum Physics · Physics 2013-05-08 J. M. Deutsch , Haibin Li , Auditya Sharma

The thermodynamic entropy of an isolated system is given by its von Neumann entropy. Over the last few years, there is an intense activity to understand thermodynamic entropy from the principles of quantum mechanics. More specifically, is…

Quantum Physics · Physics 2016-07-19 S. Santhosh Kumar , S. Shankaranarayanan

We consider three von Neumann entropy inequalities: subadditivity; Pinsker's inequality for relative entropy; and the monotonicity of relative entropy. For these we state conditions for equality, and we prove some new error bounds away from…

Quantum Physics · Physics 2014-10-21 Eric A. Carlen , Elliott H. Lieb

We consider the von Neumann entropy of a thermal mixed state in quantum systems derived from mirror curves, where the kinetic terms are exponential functions of the momentum operators. Using the mathematical results on the asymptotics of…

High Energy Physics - Theory · Physics 2023-10-10 Min-xin Huang
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