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The transport and dispersion of multiple species of charged ions are central to many biological and physical processes, including electrokinetic ion separation. However, most theoretical studies of dispersion in channels have focused on…

Soft Condensed Matter · Physics 2026-05-04 Thakurdas Mahata , Anirban Chatterjee , Ameeya Kumar Nayak

The problem of the one dimensional electro-diffusion of ions in a strong binary electrolyte is considered. In such a system the solute dissociates completely into two species of ions with unlike charges. The mathematical description…

Chemical Physics · Physics 2012-03-28 Sandip Ghosal , Zhen Chen

The Taylor-Aris theory of shear diffusion predicts that the effective diffusivity of a tracer molecule in a sheared liquid is enhanced by a term quadratic in the shear rate. In sheared supercooled liquids, instead, the observed enhancement…

Soft Condensed Matter · Physics 2025-11-06 Mangesh Bhendale , Jayant K. Singh , Alessio Zaccone

In this letter we analyze the effects of an externally applied electric field on thermal fluctuations for a fluid containing charged species. We show in particular that the fluctuating Poisson-Nernst-Planck equations for charged…

The differential migration of ions in an applied electric field is the basis for separation of chemical species by capillary electrophoresis. Axial diffusion of the concentration peak limits the separation efficiency. Electromigration…

Quantitative Methods · Quantitative Biology 2015-06-04 S. Ghosal , Z. Chen

We consider the evolution of a passive scalar advected by a parallel shear flow in an infinite cylinder with bounded cross section, in arbitrary space dimension. The essential parameters of the problem are the molecular diffusivity $\nu$,…

Analysis of PDEs · Mathematics 2023-05-23 Michele Coti Zelati , Thierry Gallay

This paper explores the phenomena of enhanced dissipation and Taylor dispersion in solutions to the passive scalar equations subject to time-dependent shear flows. The hypocoercivity functionals with carefully tuned time weights are applied…

Analysis of PDEs · Mathematics 2023-09-29 Daniel Coble , Siming He

Taylor dispersion in periodic but highly corrugated channels is studied. Exact analytical expressions for the long-time diffusion constant and drift along the channel are derived to next-to-leading order in the limit of small channel…

Statistical Mechanics · Physics 2025-05-28 Arthur Alexandre , Thomas Guérin , David S. Dean

We consider ionic electrodiffusion in fluids, described by the Nernst-Planck-Navier-Stokes system. We prove that the system has global smooth solutions for arbitrary smooth data: arbitrary positive Dirichlet boundary conditions for the…

Analysis of PDEs · Mathematics 2021-05-05 Peter Constantin , Mihaela Ignatova , Fizay-Noah Lee

On the basis of a hydrodynamical model analogous to that in critical fluids, we investigate the influences of shear flow upon the electrostatic contribution to the viscosity of binary electrolyte solutions in the Debye-H\"{u}ckel…

Statistical Mechanics · Physics 2007-05-23 Hirofumi Wada

We consider a coupled system of Navier Stokes, Maxwell Stefan and Poisson Boltzmann equations by incorporating the variation of dielectric constant, which governs the electro osmotic flow in nano channel, describing the evolution of the…

Fluid Dynamics · Physics 2016-02-24 Rajendra Padidhapu , Shahnaz Bathul , V. Brahmajirao

A modified Poisson-Nernst-Planck system in a bounded domain with mixed Dirichlet-Neumann boundary conditions is analyzed. It describes the concentrations of ions immersed in a polar solvent and the correlated electric potential due to the…

Analysis of PDEs · Mathematics 2023-05-25 Ansgar Jüngel , Annamaria Massimini

We show that the Nernst-Planck-Euler system, which models ionic electrodiffusion in fluids, has global strong solutions for arbitrarily large data in the two dimensional bounded domains. The assumption on species is either there are two…

Analysis of PDEs · Mathematics 2022-12-27 Dapeng Du , Jingyu Li , Yansheng Ma , Ruyi Pang

The response of a model micro-electrochemical system to a time-dependent applied voltage is analyzed. The article begins with a fresh historical review including electrochemistry, colloidal science, and microfluidics. The model problem…

Soft Condensed Matter · Physics 2009-11-10 Martin Z. Bazant , Katsuyo Thornton , Armand Ajdari

We consider Taylor dispersion for tracer particles in micro-fluidic planar channels with strong confinement. In this context, the channel walls modify the local diffusivity tensor and also interactions between the tracer particles and the…

Fluid Dynamics · Physics 2021-08-12 Arthur Alexandre , Thomas Guérin , David S. Dean

Channels are fundamental building blocks from biophysics to soft robotics, often used to transport or separate solutes. As solute particles inevitably transverse between streamlines along the channel by molecular diffusion, the effective…

Soft Condensed Matter · Physics 2020-02-10 Sophie Marbach , Karen Alim

The dispersion of a passive scalar in a fluid through the combined action of advection and molecular diffusion is often described as a diffusive process, with an effective diffusivity that is enhanced compared to the molecular value.…

Fluid Dynamics · Physics 2015-06-18 P. H. Haynes , J. Vanneste

The flow of ions through permeable channels causes voltage drop in physiological nanodomains such as synapses, dendrites and dendritic spines, and other protrusions. How the voltage changes around channels in these nanodomains has remained…

Soft Condensed Matter · Physics 2025-01-10 Frédéric Paquin-Lefebvre , David Holcman

We study the long time behavior of an advection-diffusion equation with a random shear flow which depends on a stationary Ornstein-Uhlenbeck (OU) process in parallel-plate channels enforcing the no-flux boundary conditions. We derive a…

Analysis of PDEs · Mathematics 2020-12-15 Lingyun Ding , Richard M. McLaughlin

The phenomenon of Taylor or shear-induced dispersion of a non-passive scalar field in a pulsatile pipe flow is investigated, accounting for the scalar field's influence on fluid density and transport coefficients. By employing multiple…

Fluid Dynamics · Physics 2026-03-13 Prabakaran Rajamanickam , Adam D. Weiss
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