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Ionic-liquid based acidic aqueous biphasic solutions (AcABS) recently offered a breakthrough in the field of metal recycling. Indeed, the mixture of tributyltetradecylphosphonium chloride (P$_{44414}$Cl) and acid with water content larger…

The shift in chemical equilibria due to isotope substitution is often exploited to gain insight into a wide variety of chemical and physical processes. It is a purely quantum mechanical effect, which can be computed exactly using…

Statistical Mechanics · Physics 2014-07-04 Michele Ceriotti , Thomas E. Markland

The stable isotopologues of water have been used in atmospheric and climatic studies for over fifty years, because the temperature-dependent preferential condensation of heavy isotopologues during phase changes makes them useful diagnostics…

Atmospheric and Oceanic Physics · Physics 2021-07-20 Kara Lamb , Ben Clouser , Maximilien Bolot , Laszlo Sarkozy , Volker Ebert , Harald Saathoff , Ottmar Möhler , Elisabeth Moyer

This work investigates the migration of spherical particles of different sizes in a centrifuge-driven deterministic lateral displacement (c-DLD) device. Specifically, we use a scaled-up model to study the motion of suspended particles…

Soft Condensed Matter · Physics 2016-04-27 Mingliang Jiang , Aaron D. Mazzeo , German Drazer

Microcapsules allow for the controlled containment, transport, and release of cargoes ranging from pharmaceuticals to fragrances. Given the interest from a variety of industries in microcapsules and other core-shell structures, a multitude…

Soft Condensed Matter · Physics 2021-08-04 Steven Dang , John Brady , Ryle Rel , Sreenidhi Surineni , Conor O'Shaughnessy , Ryan McGorty

In this letter, we use knowledge gained from our recent study to present a technique for separation of nanoparticles such as exosomes, anticancer drugs, and vaccines. The technique involves adding non-adsorptive polymers to a system in…

Soft Condensed Matter · Physics 2024-04-29 Ikuma Ogasawara , Ken-ichi Amano

Isotachophoresis (ITP) is a versatile electrophoretic technique which can be used for sample preconcentration, separation, purification, mixing, and control and acceleration of chemical reactions. Although the basic technique is nearly a…

Chemical Physics · Physics 2022-03-30 Ashwin Ramachandran , Juan G. Santiago

The {\AA}ngstr\"om-sized probe of the scanning transmission electron microscope can visualize and collect spectra from single atoms. This can unambiguously resolve the chemical structure of materials, but not their isotopic composition.…

It is shown that structuring at the microlevel, a previously not described in detail phenomenon, is the intrinsic property of water and aqueous solutions. At room conditions water (including "ultrapure" one) and aqueous solutions are…

Soft Condensed Matter · Physics 2018-09-05 Tatiana Yakhno , Vladimir Yakhno

Recently it was shown that the WAC model for liquid silica [L. V. Woodcock, C. A. Angell, and P. Cheeseman, J. Chem. Phys. 65, 1565 (1976)] is remarkably close to having a liquid-liquid critical point (LLCP). We demonstrate that increasing…

Soft Condensed Matter · Physics 2016-03-30 Erik Lascaris

A broad variety of liquids conform to density scaling: relaxation times expressed as a function of the ratio of temperature to density, the latter raised to a material constant {\gamma}. For atomic liquids interacting only through simple…

Soft Condensed Matter · Physics 2019-06-26 D. Fragiadakis , C. M. Roland

The recent availability of step-edge, frit-disc crucible sets (generally sold as Canfield Crucible Sets or CCS) has led to multiple innovations associated with our group's use of solution growth. Use of CCS allows for the clean separation…

Materials Science · Physics 2025-03-14 Paul C. Canfield , Tyler J. Slade

Self-similar solutions of the coherent diffusion equation are derived and measured. The set of real similarity solutions is generalized by the introduction of a nonuniform phase surface, based on the elegant Gaussian modes of optical…

Quantum Physics · Physics 2015-05-19 O. Firstenberg , P. London , D. Yankelev , R. Pugatch , M. Shuker , N. Davidson

We present an experimental study of segregation of granular matter in a quasi-two dimensional silo emptying out of an orifice. Size separation is observed when multi-sized particles are used with the larger particles found in the center of…

Statistical Mechanics · Physics 2009-10-31 Azadeh Samadani , A. Pradhan , A. Kudrolli

We have demonstrated a new, accessible and economical technique, dubbed photostop, for producing high densities of trappable molecules. Direct measurements are presented of NO molecules produced with a narrow velocity distribution centered…

Chemical Physics · Physics 2013-08-12 Alexandre Trottier , David Carty , Eckart Wrede

We study the electrophoretic flow of suspensions of charged colloids with a mesoscopic method that allows to model generic experimental conditions. We show that for highly charged colloids their electrophoretic mobility increases…

Soft Condensed Matter · Physics 2015-05-28 Giovanni Giupponi , Ignacio Pagonabarraga

Displacing liquid in a confined space is important for technological processes, ranging from porous membrane separation to CO$_{2}$ sequestration. The liquid to be displaced usually consists of multiple components with different…

Soft Condensed Matter · Physics 2021-02-26 Gilmar F. Arends , Jae Bem You , John M. Shaw , Xuehua Zhang

We consider the numerical solution of partial differential equations with coefficients that are strongly heterogeneous in space. We provide an overview of higher-order localized orthogonal decomposition (LOD) methods for the elliptic…

Numerical Analysis · Mathematics 2026-05-29 Balaje Kalyanaraman , Felix Krumbiegel , Roland Maier , Siyang Wang

We present an approach to construct position-sensitive silicon detectors with an integrated cooling circuit. Tests on samples demonstrate that a very modest liquid flow very effectively cool the devices up to a power dissipation of over…

Instrumentation and Detectors · Physics 2016-08-03 L. Andricek , M. Boronat , J. Fuster , I. Garcia , P. Gomis , C. Marinas , J. Ninkovic , M. Perello Rosello , M. A. Villarejo , M. Vos

This manuscript describes measurements of water-based liquid scintillators (WbLS), demonstrating separation of the Cherenkov and scintillation components using the fast timing response of a Large Area Picosecond Photodector (LAPPD).…

Instrumentation and Detectors · Physics 2022-03-03 T. Kaptanoglu , E. J. Callaghan , M. Yeh , G. D. Orebi Gann