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We propose a novel means to isolate and quantify the effects of Berry force on molecular dynamics using two reasonably strong continuous wave (CW) laser fields with frequencies $\omega$ and $2\omega$. For molecules or materials with three…

Chemical Physics · Physics 2020-08-25 Zeyu Zhou , Joseph E. Subotnik , Hsing-Ta Chen

In quantum mechanics it is often required to describe in a semiclassical approximation the motion of particles moving within a given energy band. Such a representation leads to the appearance of an analogues of fictitious forces in the…

Statistical Mechanics · Physics 2017-10-11 Eldad Bettelheim

Under the Born-Oppenheimer approximation, the electronic ground state evolves adiabatically and can accumulate geometrical phases characterized by the molecular Berry curvature. In this work, we study the effect of the molecular Berry…

Mesoscale and Nanoscale Physics · Physics 2022-02-23 Daniyar Saparov , Bangguo Xiong , Yafei Ren , Qian Niu

It is shown that due to Thomas precession, angular momentum is not generally a constant of the motion in a quasiclassical model of the Positronium atom consisting of circular-orbiting point charges with intrinsic spin and associated…

Classical Physics · Physics 2010-12-13 David C. Lush

There are confusions about angular momentum propagation in scattering or decay processes involving the transition between particle systems that appear to transform differently under Lorentz transformations. This paper provides an analysis…

High Energy Physics - Phenomenology · Physics 2024-01-09 Bowen Wang

We consider area-preserving deformations of the plane, acting on electronic wavefunctions through "quantomorphisms" that change both the underlying metric and the confining potential. We show that adiabatic sequences of such transformations…

Mesoscale and Nanoscale Physics · Physics 2023-10-11 Blagoje Oblak , Benoit Estienne

The Born-Oppenheimer electronic wavefunction $\Phi_R^{BO}(r)$ picks up a topological phase factor $\pm 1$, a special case of Berry phase, when it is transported around a conical intersection of two adiabatic potential energy surfaces in…

Chemical Physics · Physics 2016-04-14 Ryan Requist , Falk Tandetzky , E. K. U. Gross

We demonstrate that the molecular Berry phase and the corresponding non-analyticity in the electronic Born-Oppenheimer wavefunction is, in general, not a true topological feature of the exact solution of the full electron-nuclear…

Quantum Physics · Physics 2015-06-18 S. K. Min , A. Abedi , K. S. Kim , E. K. U. Gross

Describing the dynamics of nuclei in molecules requires a potential energy surface, which is traditionally provided by the Born-Oppenheimer or adiabatic approximation. However, we also need to assign masses to the nuclei. There, the…

Understanding the transport behavior of an electronic system under the influence of a magnetic field remains a key subject in condensed matter physics. Particularly in topological materials, their nonvanishing Berry curvature can lead to…

Mesoscale and Nanoscale Physics · Physics 2023-03-24 Jeonghyeon Suh , Sanghyun Park , Hongki Min

The band geometric properties of quantum materials play an elemental role in the linear and nonlinear transport of electrons. In this paper, we propose that the interplay of the Berry curvature, the orbital magnetic moment and the Lorentz…

Mesoscale and Nanoscale Physics · Physics 2022-03-22 Shibalik Lahiri , Tanmay Bhore , Kamal Das , Amit Agarwal

We show that in non-collinear magnetic molecules, non-adiabatic (dynamical) effects due to the electron-vibron coupling are time-reversal symmetry breaking interactions for the vibrational field. As in these systems the electronic…

Chemical Physics · Physics 2021-06-16 Oliviero Bistoni , Francesco Mauri , Matteo Calandra

The expression for the total angular momentum carried by a laser optical vortex beam, splits, in the paraxial approximation, into two terms which seem to represent orbital and spin angular momentum respectively. There are, however, two very…

Optics · Physics 2018-02-28 Elliot Leader

In recent work [Coretti et al., The Journal of Chemical Physics, 2018, 149, 191102], a new algorithm to solve numerically the dynamics of the shell model for polarization was presented. The approach, broadly applicable to systems involving…

Statistical Mechanics · Physics 2020-06-24 Sara Bonella , Alessandro Coretti , Rodolphe Vuilleumier , Giovanni Ciccotti

The spin-dependent Berry force is a genuine effect of Berry curvature in molecular dynamics, which can dramatically result in spatial spin separation and change of reaction pathways. However, the way to probe the effect of Berry force…

Atomic Physics · Physics 2023-07-14 Ming Zhang , Xiaoyu Mi , Linfeng Zhang , Chengyin Wu , Zheng Li

We consider the adiabatic evolution of the Dirac equation in order to compute its Berry curvature in momentum space. It is found that the position operator acquires an anomalous contribution due to the non Abelian Berry gauge connection…

High Energy Physics - Theory · Physics 2016-08-16 Alain Bérard , Herve Mohrbach

Hybrid quantum systems exhibiting coupled optical, spin, and mechanical degrees of freedom can serve as a platform for sensing, or as a bus to mediate interactions between qubits with disparate energy scales. These systems are also creating…

Quantum Physics · Physics 2020-01-08 Pablo R. Zangara , Alexander Wood , Marcus W. Doherty , Carlos. A. Meriles

We explore the effects of spin-orbit coupling on nuclear wave packet motion near an out-of-equilibrium molecular junction, where nonzero Berry curvature emerges as the antisymmetric part of the electronic friction tensor. The existence of…

Materials Science · Physics 2022-11-30 Hung-Hsuan Teh , Wenjie Dou , Joseph E. Subotnik

Extended Lagrangian Born-Oppenheimer molecular dynamics based on Kohn-Sham density functional theory is generalized in the limit of vanishing self-consistent field optimization prior to the force evaluations. The equations of motion are…

Chemical Physics · Physics 2015-06-23 Anders M. N. Niklasson , Marc J. Cawkwell

In this paper we study the properties of cold bosons in a two-dimensional optical lattice system where Bose-condensation occurs at a momentum point k with non-zero k-space Berry curvature. By combining results from both analytic and…

Mesoscale and Nanoscale Physics · Physics 2017-04-05 Xiao-Hui Li , Ting-Pong Choy , Tai-Kai Ng