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We demonstrate (both analytically and numerically) total angular momentum conservation for a molecular system subject to circularly polarized light (CPL) field moving along a single Born-Oppenheimer surface, where all of the angular…

Chemical Physics · Physics 2024-03-05 Xuezhi Bian , Joseph Subotnik

We show that standard Ehrenfest dynamics does not conserve linear and angular momentum when using a basis of truncated adiabatic states. However, we also show that previously proposed effective Ehrenfest equations of…

Chemical Physics · Physics 2023-12-15 Zhen Tao , Xuezhi Bian , Yanze Wu , Jonathan Rawlinson , Robert G. Littlejohn , Joseph E. Subotnik

We study the role of rotational symmetry in the systems where nonabelian Berry potentials emerge as a result of integrating out fast degrees of freedom. The conserved angular momentum is constructed in the presence of a non-abelian Berry…

High Energy Physics - Theory · Physics 2007-05-23 Hyun Kyu Lee , Mannque Rho

This paper concerns the representation of angular momentum operators in the Born-Oppenheimer theory of polyatomic molecules and the various forms of the associated conservation laws. Topics addressed include the question of whether these…

Chemical Physics · Physics 2023-03-22 Robert Littlejohn , Jonathan Rawlinson , Joseph Subotnik

The total angular momentum of a close system is a conserved quantity, which should remain constant in time for any excitation experiment once the pumping signal has extinguished. Such conservation, however, is never satisfied in practice in…

Mesoscale and Nanoscale Physics · Physics 2022-04-13 Jacopo Simoni , Stefano Sanvito

Mechanical angular momentum is not conserved in systems involving electromagnetic fields with non-zero electromagnetic field angular momentum. Conservation is restored only if the total (mechanical and field) angular momentum is considered.…

Classical Physics · Physics 2016-11-08 George Pantazis , Leandros Perivolaropoulos

We ask the question of how angular momentum is conserved in electroweak interaction processes. To introduce the problem with a minimum of mathematics, we first raise the same issue in elastic scattering of a circularly polarized photon by…

High Energy Physics - Phenomenology · Physics 2024-09-05 Gordon Baym , Jen-Chieh Peng , C. J. Pethick

The Berry phase for a variety of systems comprising of two angular momenta is discussed. These include the electron and proton in the ground state of the hydrogen atom (taking into account the hyperfine interaction), the positronium atom,…

Quantum Physics · Physics 2011-04-29 K. J. B. Ghosh , D. De Munshi , B. Dutta-Roy

We develop a complete relativistic theory to describe the dynamics of electronic angular momentum including both spin (S) and orbital (L) contributions in magnetic systems. We start with the relativistic Dirac-Kohn-Sham Hamiltonian under…

Other Condensed Matter · Physics 2026-05-19 Subhadip Santra , Ritwik Mondal , Marco Berritta , Peter M. Oppeneer

We show that Berry's geometrical (topological) phase for circular quantum dots with an odd number of electrons is equal to \pi and that eigenvalues of the orbital angular momentum run over half-integer values. The non-zero value of the…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 V. D. Mur , N. B. Narozhny , A. N. Petrosyan , Yu. E. Lozovik

In nonrelativistic quantum mechanics, the total (i.e. orbital plus spin) angular momentum of a charged particle with spin that moves in a Coulomb plus spin-orbit-coupling potential is conserved. In a classical nonrelativistic treatment of…

Classical Physics · Physics 2015-05-27 V. Hnizdo

Whether the total angular momentum of the photon can be separated into spin and orbital parts has been a long-standing problem due to the constraint of transversality condition on its vector wavefunction. A careful analysis shows that the…

Quantum Physics · Physics 2016-01-29 Chun-Fang Li

We report on an experiment demonstrating the conservation of orbital angular momentum in stimulated down-conversion. The orbital angular momentum is not transferred to the individual beams of the spontaneous down-conversion, but it is…

We describe the effective Lorentz forces on the ions of a generic insulating system in an magnetic field, in the context of Born-Oppenheimer ab-initio molecular dynamics. The force on each ion includes an important contribution of…

Materials Science · Physics 2007-05-23 D. Ceresoli , R. Marchetti , E. Tosatti

The diagonal nonadiabatic term arising from the Born--Oppenheimer wave-function ansatz contains contributions from a vector and scalar potential. The former is provably zero when the wave function can be taken to be real valued, and the…

Chemical Physics · Physics 2022-02-08 Tanner Culpitt , Laurens D. M. Peters , Erik I. Tellgren , Trygve Helgaker

We show that the orbital angular momentum (OAM) of electrons is dynamically induced by circularly polarized phonons. The induced OAM originates from the adiabatic evolution in which electrons acquire Berry phase formulated in terms of the…

Mesoscale and Nanoscale Physics · Physics 2026-03-17 Dapeng Yao , Dongwook Go , Yuriy Mokrousov , Shuichi Murakami

We prove that for a combined system of classical and quantum particles, it is possible to write a dynamics for the classical particles that incorporates in a natural way the Boltzmann equilibrium population for the quantum subsystem. In…

Other Condensed Matter · Physics 2010-09-01 J. L. Alonso , A. Castro , P. Echenique , V. Polo , A. Rubio , D. Zueco

The dynamics of a molecule in a magnetic field is significantly different form its zero-field counterpart. One important difference in the presence of a field is the Lorentz force acting on the nuclei, which can be decomposed as the sum of…

Chemical Physics · Physics 2021-07-28 Tanner Culpitt , Laurens D. M. Peters , Erik I. Tellgren , Trygve Helgaker

Different from the usual conclusion that the separation of the photon angular momentum into orbital and spin parts is physically meaningless, the orbital and spin angular momenta are demonstrated in the first-quantization framework not to…

Quantum Physics · Physics 2015-01-28 Chun-Fang Li

We develop a phase-space electronic structure theory of molecules in magnetic fields. For a system of electrons in a magnetic field with vector potential $\bf{A}(\hat{\bf{r}})$, the usual Born-Oppenheimer Hamiltonian is the sum of the…

Chemical Physics · Physics 2024-11-25 Mansi Bhati , Zhen Tao , Xuezhi Bian , Jonathan Rawlinson , Robert Littlejohn , Joseph E. Subotnik
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