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Thermoelectric materials convert a temperature gradient into a voltage. This phenomenon is relatively well understood for inorganic materials, but much less so for organic semiconductors (OSs). These materials present a challenge because…

Charge transport in organic semiconductors is notoriously extremely sensitive to the presence of disorder, both internal and external (i.e. related to the interactions with the dielectric layer), especially for n-type materials. Internal…

The present study examines the electronic transport characteristics of amorphous semiconductors through TOF measurements and numerical simulations. The primary objective is to determine the DOS in amorphous selenium (a-Se) and to assess the…

Materials Science · Physics 2025-12-29 F. Serdouk , A. Boumali , M. L. Benkhedir , Y. Goutal

Organic semiconductors (OSCs) are widely explored for flexible optoelectronic technologies, with performance governed not only by molecular design, but also by solid-state packing, which can give rise to polymorphism.…

Charge transport in crystalline organic semiconductors is intrinsically limited by the presence of large thermal molecular motions, which are a direct consequence of the weak van der Waals inter-molecular interactions. These lead to an…

Materials Science · Physics 2018-06-18 S. Fratini , D. Mayou , S. Ciuchi

Charge transport in organic semiconductors is notoriously extremely sensitive to the presence of disorder, both intrinsic and extrinsic, especially for n-type materials. Intrinsic dynamic disorder stems from large thermal fluctuations both…

We explore the charge transport mechanism in organic semiconductors based on a model that accounts for the thermal intermolecular disorder at work in pure crystalline compounds, as well as extrinsic sources of disorder that are present in…

Materials Science · Physics 2012-12-10 S. Ciuchi , S. Fratini

Optical conductivity in molecular semiconductors is suppressed in the terahertz region, featuring the displaced Drude peak that reflects carriers' transient localization (TL) by slow intermolecular vibrations. Meanwhile, recent computations…

Chemical Physics · Physics 2025-11-24 Veljko Janković

Predicting charge transport in organic molecular crystals is notoriously challenging. Carrier mobility calculations in organic semiconductors are dominated by quantum chemistry methods based on charge hopping, which are laborious and only…

Materials Science · Physics 2018-03-21 Nien-En Lee , Jin-Jian Zhou , Luis A. Agapito , Marco Bernardi

We explore polaronic quantum transport in three-dimensional models of disordered organic crystals with strong coupling between electronic and vibrational degrees of freedom. By studying the polaron dynamics in a static disorder environment,…

Materials Science · Physics 2015-06-03 Frank Ortmann , Stephan Roche

We analyze a model that accounts for the inherently large thermal lattice fluctuations associated to the weak van der Waals inter-molecular bonding in crystalline organic semiconductors. In these materials the charge mobility generally…

Materials Science · Physics 2010-01-08 S. Fratini , S. Ciuchi

Physics based numerical simulation has been carried out to probe the sub-gap density of states (DOS) and underlying electron transport properties of amorphous oxide based thin film transistors (TFTs). The DOS model of TFTs consists of…

Applied Physics · Physics 2024-02-15 D. Saha , Sachin Kulkarni

We find that the hole mobility of the crystal smectic phases of the liquid crystal 1,4-di-(5-n-tridecylthien-2-yl)-benzene increases exponentially with decreasing temperature. While qualitatively consistent with transport via polaron bands,…

We present a model of charge transport in organic molecular semiconductors based on the effects of lattice fluctuations on the quantum coherence of the electronic state of the charge carrier. Thermal intermolecular phonons and librations…

Other Condensed Matter · Physics 2009-11-11 J. -D. Picon , M. N. Bussac , L. Zuppiroli

We provide a phenomenological formula which describes the low-frequency optical absorption of charge carriers in disordered systems with localization. This allows to extract, from experimental data on the optical conductivity, the relevant…

Materials Science · Physics 2015-06-19 Simone Fratini , Sergio Ciuchi , Didier Mayou

In organic field effect transistors (FETs), charges move near the surface of an organic semiconductor, at the interface with a dielectric. In the past, the nature of the microscopic motion of charge carriers -that determines the device…

Materials Science · Physics 2015-06-25 I. N. Hulea , S. Fratini , H. Xie , C. L. Mulder , N. N. Iossad , G. Rastelli , S. Ciuchi , A. F. Morpurgo

We develop an analytical theory of the localization-delocalization transition for a disordered Bose system, focusing on a Cooper-pair insulator. We consider a chain of small superconducting granules coupled via Josephson links and show that…

Mesoscale and Nanoscale Physics · Physics 2011-10-28 N. M. Chtchelkatchev , A. Petkovic , A. Glatz , T. I. Baturina , V. M. Vinokur

Deviations of molecular shapes from spherical symmetry may give rise to a variety of novel phenomena, including their dynamic behavior. It has recently been predicted [Mazza \textit{et al}. Phys. Rev. Lett. \textbf{105}, 227802 (2010)] that…

We study the temperature dependence of the conductivity of the 2D electronic solid. In realistic samples, a domain structure forms in the solid and each domain randomly orients in the absence of the in-plane field. At higher temperature,…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Shi-Jie Yang , Yue Yu

We suggest universal expressions for the rates of charge transition between molecules in organic disordered semiconductors, which differ between electrons and holes. The donor and acceptor molecules (monomers) are represented in terms of…

Disordered Systems and Neural Networks · Physics 2015-08-17 E. D. Gutliansky , Nir Tesler , Uri Peskin
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