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Interactions of quantum systems with their environment play a crucial role in resource-theoretic approaches to thermodynamics in the microscopic regime. Here, we analyze the possible state transitions in the presence of "small" heat baths…

Quantum Physics · Physics 2018-02-27 Jakob Scharlau , Markus P. Mueller

This paper explores a novel connection between a thermodynamic and a dynamical systems perspective on emergent dynamical order. We provide evidence for a conjecture that Hamiltonian systems with mixed chaos spontaneously find regular…

Adaptation and Self-Organizing Systems · Physics 2025-09-16 Pavel Chvykov , Jeremy England

Ability of dynamical systems to relax to equilibrium has been investigated since the invention of statistical mechanics, which establishes the connection between dynamics of many-body Hamiltonian systems and phenomenological thermodynamics.…

Statistical Mechanics · Physics 2019-07-01 K. S. Glavatskiy , V. L. Kulinskii

Quantum thermodynamics explores novel thermodynamic phenomena that emerge when interactions between macroscopic systems and microscopic quantum ones go into action. Among various issues, quantum heat engines, in particular, have attracted…

Quantum Physics · Physics 2023-05-09 Miku Ishizaki , Naomichi Hatano , Hiroyasu Tajima

Thermodynamics entails a set of mathematical conditions on quantum Markovian dynamics. In particular, strict energy conservation between the system and environment implies that the dissipative dynamical map commutes with the unitary system…

Quantum Physics · Physics 2021-04-07 Roie Dann , Ronnie Kosloff

The study of quantum thermal machines, and more generally of open quantum systems, often relies on master equations. Two approaches are mainly followed. On the one hand, there is the widely used, but often criticized, local approach, where…

Using the quasi-equilibrium Helmholtz energy (qHE), defined as the thermodynamic work in a quasi-static process, we investigate the thermal properties of both an isothermal process and a transition process between the adiabatic and…

Statistical Mechanics · Physics 2022-07-06 Shoki Koyanagi , Yoshitaka Tanimura

In this brief note, we compare two frameworks for characterizing possible operations in quantum thermodynamics. One framework considers Thermal Operations---unitaries which conserve energy. The other framework considers all maps which…

Quantum Physics · Physics 2015-04-13 Philippe Faist , Jonathan Oppenheim , Renato Renner

We formulate a thermodynamic theory applicable to both classical and quantum systems. These systems are depicted as thermodynamic system-bath models capable of handling isothermal, isentropic, thermostatic, and entropic processes. Our…

Statistical Mechanics · Physics 2024-06-25 Shoki Koyanagi , Yoshitaka Tanimura

In standard thermodynamics, internal energy is a state function, independent of process rates. We show that this structure breaks down in open quantum systems undergoing thermalization. Within Gorini-Kossakowski-Lindblad-Sudarshan (GKLS)…

Statistical Mechanics · Physics 2026-05-12 Hyeong-Chan Kim , Youngone Lee

Deriving conditions under which a macroscopic system thermalizes directly from the underlying quantum many-body dynamics of its microscopic constituents is a long-standing challenge in theoretical physics. The well-known eigenstate…

Statistical Mechanics · Physics 2022-02-02 Lennart Dabelow , Patrick Vorndamme , Peter Reimann

Catalysis, the acceleration of product formation by a substance that is left unchanged, typically results from multiple elementary processes, including diffusion of the reactants toward the catalyst, chemical steps, and release of the…

Chemical Physics · Physics 2023-12-27 Yann Sakref , Maitane Muñoz-Basagoiti , Zorana Zeravcic , Olivier Rivoire

We describe a symplectic approach towards thermodynamics in which thermodynamic transformations are described by (symplectic) Hamiltonian dynamics. Upon identifying the spaces of equilibrium states with Lagrangian submanifolds of a…

Mathematical Physics · Physics 2026-05-01 Aritra Ghosh , E. Harikumar

Under the Eigenstate Thermalization Hypothesis (ETH), quantum-quenched systems equilibrate towards canonical, thermal ensembles. While at first glance the ETH might seem a very strong hypothesis, we show that it is indeed not only…

Quantum Physics · Physics 2016-02-03 Giacomo De Palma , Alessio Serafini , Vittorio Giovannetti , Marcus Cramer

It is argued that a typical many body energy eigenstate has a well defined thermodynamic entropy and that individual eigenstates possess thermodynamic characteristics analogous to those of generic isolated systems. We examine large systems…

Statistical Mechanics · Physics 2015-05-14 J. M. Deutsch

Passive states, i.e., those states from which no work can be extracted via unitary operations, play an important role in the foundations and applications of quantum thermodynamics. They generalize the familiar Gibbs thermal states, which…

Quantum Physics · Physics 2021-08-13 Uttam Singh , Siddhartha Das , Nicolas J. Cerf

We define thermodynamic configurations and identify two primitives of discrete quantum processes between configurations for which heat and work can be defined in a natural way. This allows us to uncover a general second law for any discrete…

Quantum Physics · Physics 2015-06-12 Janet Anders , Vittorio Giovannetti

We study properties of steady states (states with time-independent density operators) of systems of coupled harmonic oscillators. Formulas are derived showing how adiabatic change of the Hamiltonian transforms one steady state into another.…

General Relativity and Quantum Cosmology · Physics 2009-10-22 Max Tegmark , Leehwa Yeh

There is much interest in how quantum systems thermalize after a sudden change, because unitary evolution should preclude thermalization. The eigenstate thermalization hypothesis resolves this because all observables for quantum states in a…

Quantum Gases · Physics 2014-08-22 H. Fotso , K. Mikelsons , J. K. freericks

The second law of thermodynamics tells us which state transformations are so statistically unlikely that they are effectively forbidden. Its original formulation, due to Clausius, states that "Heat can never pass from a colder to a warmer…