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We consider the radiation of angular momentum (AM) from current-carrying molecular junctions. Using the nonequilibrium Green's function method, we derive a convenient formula for the AM radiation and apply it to a prototypical benzene…

Mesoscale and Nanoscale Physics · Physics 2021-01-12 Zu-Quan Zhang , Jing-Tao Lü , Jian-Sheng Wang

In the present work we theoretically analyze electroluminescence occurring in a biased single-molecule junction with a chiral bridge imitated by a helical chain. We show that optical transitions between electron states of the chiral linker…

Mesoscale and Nanoscale Physics · Physics 2025-07-22 Natalya A Zimbovskaya

Photoelectron circular dichroism results from one-photon ionization of chiral molecules by circularly polarized light and manifests itself in forward-backward asymmetry of electron emission in the direction orthogonal to the light…

Atomic Physics · Physics 2019-04-24 Andres F. Ordonez , Olga Smirnova

Chiral matter exhibits unique electromagnetic responses due to the macroscopic manifestation of the chiral anomaly as anomalous transport currents. Here, we study the modification of electromagnetic radiation in isotropic chiral matter…

High Energy Physics - Phenomenology · Physics 2025-01-29 Eduardo Barredo-Alamilla , Luis F. Urrutia , Maxim A. Gorlach

We consider several fundamental optical phenomena involving single molecules in biased metal-molecule-metal junctions. The molecule is represented by its highest occupied and lowest unoccupied molecular orbitals, and the analysis involves…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michael Galperin , Abraham Nitzan

Quantum transport through single molecules is essentially affected by molecular vibrations. We investigate the behavior of the prototype single-level model with intermediate electron-vibron coupling and arbitrary coupling to the leads. We…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Dmitry A. Ryndyk , Gianaurelio Cuniberti

Starting from the modified Maxwell equations in Carroll-Field-Jackiw electrodynamics we study the electromagnetic radiation in a chiral medium characterized by an axion coupling $\theta(x)=b_\mu x^\mu$, with $b_\mu= (0,\mathbf{b})$, which…

High Energy Physics - Phenomenology · Physics 2023-06-14 Eduardo Barredo-Alamilla , Luis F. Urrutia , Manoel M. Ferreira

A triaxial particle-rotor Hamiltonian for three mutually perpendicular angular momentum vectors corresponding to two high-$j$ quasiparticles and the rotation of a triaxial collective core, is treated within a time-dependent variational…

Nuclear Theory · Physics 2018-08-01 R. Budaca

We analyze two simple model planar molecules: an ionic molecule with D3 symmetry and a covalent molecule with D6 symmetry. Both symmetries allow the existence of chiral molecular orbitals and normal modes that are coupled to each other in a…

Mesoscale and Nanoscale Physics · Physics 2025-11-05 Ivan Pasqua , Gregorio Staffieri , Michele Fabrizio

The Smith-Purcell effect arises when charged particles move near a periodic structure, emitting radiation. Conventional approaches for generating chiral Smith-Purcell radiation rely on metasurface phase engineering or resonant mode…

We show that individual vibrational modes in single-molecule junctions with asymmetric molecule-lead coupling can be selectively excited by applying an external bias voltage. Thereby, a non-statistical distribution of vibrational energy can…

Mesoscale and Nanoscale Physics · Physics 2017-09-13 R. Volkovich , R. Härtle , M. Thoss , U. Peskin

Molecular chirality is a key design property for many technologies including bioresponsive imaging, circularly polarized light detection and emission, molecular motors and switches. Imaging and manipulating the primary steps of transient…

Non-equilibrium Green's functions (NEGF) formalism combined with extended Huckel (EHT) and charging model are used to study electrical conduction through single-molecule junctions. Analyzed molecular complex is composed of asymmetric…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Kamil Walczak , Sergey Edward Lyshevski

Chirality is a fundamental concept in physics that underpins various phenomena in nonlinear optics, quantum physics, and topological photonics. Although the spin of a photon naturally brings chirality, orbital angular momentum can also…

Characterization of the structural and electron transport properties of single chiral molecules provides critical insights into the interplay between their electronic structure and electrochemical environments, providing broader…

Chemical Physics · Physics 2024-09-26 Yueqing Shi , Liya Bi , Zihao Wang , Kangkai Liang , Ji-Kun Li , Xiao-Ye Wang , Wan-Lu Li , Shaowei Li

We show that the combination of two achiral components - atomic or molecular target plus a circularly polarized photon - can yield chirally structured photoelectron angular distributions. For photoionization of CO, the angular distribution…

We investigate the interplay of quantum interference effects and electronic-vibrational coupling in electron transport through single-molecule junctions, employing a nonequilibrium Green's function approach. Our findings show that inelastic…

Mesoscale and Nanoscale Physics · Physics 2013-02-18 R. Härtle , M. Butzin , M. Thoss

We study a two-dimensional chiral active crystal composed of underdamped chiral active particles. These particles, characterized by intrinsic handedness and persistence, interact via linear forces derived from harmonic potentials. Chirality…

Soft Condensed Matter · Physics 2024-12-25 Umberto Marini Bettolo Marconi , Lorenzo Caprini

The interplay of electrons with a chiral medium has a diverse impact across science and technology, influencing drug separation, chemical reactions, and electronic transport. In particular, such electronchirality interactions can…

Mesoscale and Nanoscale Physics · Physics 2024-08-23 Anil Kumar Singh , Kevin Martin , Maurizio Mastropasqua Talamo , Axel Houssin , Nicolas Vanthuyne , Narcis Avarvari , Oren Tal

In a nanoscale molecular junction at finite bias voltage,the intra-molecular distribution of vibrational energy can strongly deviate from the thermal equilibrium distribution and specific vibrational modes can be selectively excited in a…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Rainer Härtle , Roie Volkovich , Michael Thoss , Uri Peskin
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