Related papers: From valence fluctuations to long-range magnetic o…
We present results of magnetic susceptibility and thermal expansion measurements performed on high-quality single crystals of EuPd$_2$(Si$_{1-x}$Ge$_x$)$_2$ for 0 $\leq$ x $\leq$ 0.2 and temperatures 2 K $\leq T \leq$ 300 K. Data were taken…
We report on the successful single crystal growth of pure EuRh${_2}$Si${_2}$ and of Eu(Rh$_{1-x}$Co$_{x}$)$_2$Si$_2$ with $x\leq0.23$ by the flux method. Through Co substitution, EuRh$_2$Si$_2$ can be tuned from stable antiferromagnetism…
Single crystals of intermediate valent EuPd$_2$Si$_2$ were grown from an Eu-rich melt by the Bridgman as well as the Czochralski technique. The chemical and structural characterization of an extracted single crystalline Czochralski-grown…
Unusual phases and phase transitions are seen at the magnetic-nonmagnetic boundary in Ce, Eu and Yb-based compounds. EuNi$_2$P$_{2}$ is a very unusual valence fluctuating Eu system, because at low temperatures the Eu valence stays close to…
We report on the single crystal growth of Eu(Pd$_{1-x}$Au$_x$)$_2$Si$_2$, $0< x\leq 0.2$, from a levitating Eu-rich melt using the Czochralski method. Our structural analysis of the samples confirms the ThCr$_2$Si$_2$-type structure as well…
We present results of the magnetic susceptibility on high-quality single crystals of EuPd$_2$(Si$_{1-x}$Ge$_x$)$_2$ for Ge concentrations 0 $\leq x \leq$ 0.105 performed under varying hydrostatic (He-gas) pressure 0 $\leq p \leq$ 0.5 GPa.…
Hard X-ray angle-resolved photoemission spectroscopy reveals significant alterations in the valence band states of EuPd$_2$Si$_2$ at a temperature $T_V$, where the Eu ions undergo a temperature-induced valence crossover from a magnetic…
We present a detailed study of the temperature evolution of the crystal structure, specific heat, magnetic susceptibility and resistivity of single crystals of the paradigmatic valence-fluctuating compound EuIr$_2$Si$_2$. A comparison to…
Single crystals of ${\rm Ce_2Re_3Si_5}$ and ${\rm Pr_2Re_3Si_5}$ have been grown by Czochralski method in a tetra-arc furnace. Powder x-ray diffraction confirmed that these compounds crystallize in the ${\rm U_2Mn_3Si_5}$-type tetragonal…
Single crystals of EuPd$_3$Si$_2$ were grown using a high-temperature EuPd-flux method. The material was structurally and chemically characterized by single-crystal x-ray diffraction, powder x-ray diffraction, Laue method and…
Single crystals of EuPd2Sb2 have been grown from PdSb self-flux. The properties of the single crystals have been investigated by x-ray diffraction, magnetic susceptibility chi, magnetization M, electrical resistivity rho, Hall coefficient…
Structural, magnetic, electrical transport, and heat capacity data are reported for single crystals of TlFe1.6Se2. This compound crystallizes in a tetragonal structure similar to the ThCr2Si2 structure, but with vacancies in the Fe layer.…
We present results of hard X-ray angle-resolved photoemission spectroscopy and photoemission diffraction measurements performed on high-quality single crystals of the valence transition compound EuPd$_2$Si$_2$ for temperatures 25~K $\leq$ T…
An antiferromagnetic transition is observed in single crystal EuRh2As2 at a high temperature T_N = 47 K compared to the ferromagnetic Weiss temperature theta = 12 K. We show that this is, surprisingly, consistent with mean field theory. A…
The pressure-temperature phase diagram of an intermediate-valence compound YbPd was revealed via simultaneous ac-calorimetry and electrical resistivity measurements. Two successive structural phase transition temperatures, $T_1$ = 125 K and…
Structural, magnetization and heat capacity studies were performed on Ce$_2$(Pd$_{1-x}$Ni$_x$)$_2$Sn ($0 \leq x \leq 1$) alloys. The substitution of Pd atoms by isoelectronic Ni leads to a change in the crystallographic structure from…
The equiatomic PrGe single crystal was grown by Czochralski pulling method. The grown single crystal was found to have CrB-type orthorhombic crystal structure with the space group \textit{Cmcm} (#63). Transport and magnetization data reveal…
The compound EuPd2Si2 is a well-known valence-fluctuating compound with a largest variation of Eu valence in a narrow temperature interval (around 150 K). The ball-milled form of this compound was investigated to understand the Eu valence…
Considering certain interesting features in the previously reported 166Er Moessbauer effect and neutron diffraction data on the polycrystalline form of ErPd2Si2 crystallizing in ThCr2Si2-type tetragonal structure, we have carried out…
(Mn,Fe)2(P,Si) single crystals have been successfully grown by flux method. Single crystal diffraction demonstrates that Mn0.83Fe1.17P0.72Si0.28 crystallizes in a hexagonal crystal structure (space group P-62m) at both 100 and 280 K, in the…