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Machine learning interatomic potentials (ML-IAPs) enable quantum-accurate, classical molecular dynamics simulations of large systems, beyond reach of density functional theory (DFT). Yet, their efficiency and ability to predict systems…

Materials Science · Physics 2023-11-07 Lei Zhang , Gábor Csányi , Erik van der Giessen , Francesco Maresca

Fast coherent state transport is essential to quantum computation and quantum information processing. While an adiabatic transport of atomic qubits guarantees a high fidelity of the state preparation, it requires a long timescale that…

Quantum Physics · Physics 2026-04-27 Ya-Tang Yu , Hsin-Lien Lee , Ting Hsu , Guin-Dar Lin , Ying-Cheng Chen , H. H. Jen

A reduced-order model based on Proper Orthogonal Decomposition (POD) is proposed for the bidomain equations of cardiac electrophysiology. Its accuracy is assessed through electrocardiograms in various configurations, including myocardium…

Numerical Analysis · Mathematics 2012-07-23 Muriel Boulakia , Elisa Schenone , Jean-Frédéric Gerbeau

We introduce machine-learned potentials for Ag-Pd to describe the energy of alloy configurations over a wide range of compositions. We compare two different approaches. Moment tensor potentials (MTP) are polynomial-like functions of…

A new empirical potential for efficient, large scale molecular dynamics simulation of water is presented. The HIPPO (Hydrogen-like Intermolecular Polarizable POtential) force field is based upon the model electron density of a hydrogen-like…

Chemical Physics · Physics 2021-09-30 Joshua A. Rackers , Roseane R. Silva , Zhi Wang , Jay W. Ponder

We define a method to modularize crosscutting concerns in Component-Based Systems (CBSs) expressed using the Behavior Interaction Priority (BIP) framework. Our method is inspired from the Aspect Oriented Programming (AOP) paradigm which was…

Software Engineering · Computer Science 2018-05-23 Antoine El-Hokayem , Yliès Falcone , Mohamad Jaber

In this paper the authors study a non-linear elliptic-parabolic system, which is motivated by mathematical models for lithium-ion batteries. One state satisfies a parabolic reaction diffusion equation and the other one an elliptic equation.…

Numerical Analysis · Mathematics 2023-08-02 Behzad Azmi , Andrea Petrocchi , Stefan Volkwein

Direct Preference Optimization is an offline post-SFT method for aligning language models from preference pairs, with strong results in instruction following and summarization. However, DPO's sequence-level implicit reward can be brittle…

Computation and Language · Computer Science 2026-03-03 Samah Fodeh , Linhai Ma , Ganesh Puthiaraju , Srivani Talakokkul , Afshan Khan , Ashley Hagaman , Sarah R. Lowe , Aimee Kendall Roundtree

In the quantum optimization paradigm, variational quantum algorithms face challenges with hardware-specific and instance-dependent parameter tuning, which can lead to computational inefficiencies. The promising potential of parameter…

We introduce and explore an approach for constructing force fields for small molecules, which combines intuitive low body order empirical force field terms with the concepts of data driven statistical fits of recent machine learned…

Chemical Physics · Physics 2020-10-26 Alice Allen , Gábor Csányi , Geneviève Dusson , Christoph Ortner

We propose a novel method to describe realistically ionization processes with absorbing boundary conditions in basis expansion within the formalism of the so-called Non-Adiabatic Quantum Molecular Dynamics. This theory couples…

Quantum Physics · Physics 2015-06-26 Mathias Uhlmann , Thomas Kunert , Ruediger Schmidt

This paper presents a pseudo-spectral method for Dynamic Optimization Problems (DOPs) that allows for tight polynomial bounds to be achieved via flexible sub-intervals. The proposed method not only rigorously enforces inequality…

Optimization and Control · Mathematics 2026-04-08 Eduardo M. G. Vila , Eric C. Kerrigan , Paul Bruce

Unless special conditions apply, the attempt to solve ill-conditioned systems of linear equations with standard numerical methods leads to uncontrollably high numerical error. Often, such systems arise from the discretization of operator…

Numerical Analysis · Mathematics 2021-05-18 Stephan Mohr , Yuji Nakatsukasa , Carolina Urzúa-Torres

The efficient condition assessment of engineered systems requires the coupling of high fidelity models with data extracted from the state of the system `as-is'. In enabling this task, this paper implements a parametric Model Order Reduction…

Numerical Analysis · Mathematics 2024-07-25 Konstantinos Vlachas , Konstantinos Tatsis , Konstantinos Agathos , Adam R. Brink , Eleni Chatzi

Optimal path parameterization (OPP) is a fundamental problem for planning trajectories along a prescribed geometric path under kinodynamic constraints and task-dependent objectives. While TOPP minimizes traversal time, its saturating states…

Optimization and Control · Mathematics 2026-05-20 Yunan Wang , Jizhou Yan , Chuxiong Hu , Zeyang Li

The Spectral Neighbor Analysis Potential (SNAP) is a classical interatomic potential that expresses the energy of each atom as a linear function of selected bispectrum components of the neighbor atoms. An extension of the SNAP form is…

Materials Science · Physics 2018-04-18 Mitchell A. Wood , Aidan P. Thompson

In recent years, efficient inter-atomic potentials approaching the accuracy of density functional theory (DFT) calculations have been developed using rigorous atomic descriptors satisfying strict invariances, for example, to translation,…

Materials Science · Physics 2018-09-18 Xiang-Guo Li , Chongze Hu , Chi Chen , Zhi Deng , Jian Luo , Shyue Ping Ong

We present a spectral finite-element formulation of the optimized effective potential (OEP) method for atomic structure calculations in the random phase approximation (RPA). In particular, we develop a finite-element framework that employs…

Computational Physics · Physics 2026-01-28 Shubhang Krishnakant Trivedi , Phanish Suryanarayana

We present a modified bond-valence model of PbTiO$_3$ based on the principles of bond-valence and bond-valence vector conservation. The relationship between the bond-valence model and the bond-order potential is derived analytically in the…

Materials Science · Physics 2013-09-09 Shi Liu , Ilya Grinberg , Hiroyuki Takenaka , Andrew M. Rappe

Despite of its huge successes in vast amount of applications, the Kohn-Sham scheme of density functional theory (DFT-Kohn-Sham) has not been able to get reliable ionization potentials (IP) for semiconductors, due to self-interaction error…

Materials Science · Physics 2016-04-07 Lin-Hui Ye