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The chiral-induced spin selectivity (CISS) effect, a phenomenon where the chirality of molecules imparts significant spin selectivity to electron transfer processes, has garnered increasing interest among the chemistry, biology, and physics…

Chemical Physics · Physics 2025-09-05 Tian-Yi Zhang , Yue Mao , Ai-Min Guo , Qing-Feng Sun

Here we propose a mechanism by which spin polarization can be generated dynamically in chiral molecular systems undergoing photo-induced electron transfer. The proposed mechanism explains how spin polarization emerges in systems where…

Mesoscale and Nanoscale Physics · Physics 2021-08-19 Thomas P. Fay , David T. Limmer

Chirality-induced spin selectivity is a spin-splitting phenomenon from a helical structure with a considerably effective spin-orbit coupling. This unexpectedly large spin-splitting phenomenon has been experimentally observed in chiral…

Strongly Correlated Electrons · Physics 2024-05-08 Meng Xu , Yan Chen

We present the first microscopic model for chirality-induced spin selectivity effect in electron-transfer, in which the internal degrees of freedom of the chiral bridge are explicitly included. By exactly solving this model on short chiral…

Mesoscale and Nanoscale Physics · Physics 2024-10-08 A. Chiesa , E. Garlatti , M. Mezzadri , L. Celada , R. Sessoli , M. R. Wasielewski , R. Bittl , P. Santini , S. Carretta

We show how a spin polarization can be generated through the photo-induced electron transfer of an achiral donor-acceptor complex following chiral light excitation. In particular, we illustrate the basic energetic and symmetry requirements…

Chemical Physics · Physics 2026-03-10 Sindhana Pannir-Sivajothi , David T. Limmer

Chiral induced spin selectivity is a phenomenon that has been attributed to chirality, spin-orbit interactions, and non-equilibrium conditions, while the role of electron exchange and correlations have been investigated only marginally…

Mesoscale and Nanoscale Physics · Physics 2021-04-28 J. Fransson

The role of chirality in determining the spin dynamics of photoinduced electron transfer in donor-acceptor molecules remains an open question. Although chirality-induced spin selectivity (CISS) has been demonstrated in molecules bound to…

Charge and spin dynamics is addressed in chiral molecules immediately after the instantaneous coupling to an external metallic reservoir. It is shown how a spin-polarization is induced in the chiral structure as a response to the charge…

Mesoscale and Nanoscale Physics · Physics 2022-02-08 J. Fransson

Photoexcitable donor-bridge-acceptor (D-B-A) molecules that support intramolecular charge transfer are ideal platforms to probe the influence of chiral-induced spin selectivity (CISS) in electron transfer and resulting radical pairs. In…

Quantum Physics · Physics 2023-04-27 Laura A. Völker , Konstantin Herb , Erika Janitz , Christian L. Degen , John M. Abendroth

It is well assessed that the charge transport through a chiral potential barrier can result in spin-polarized charges. The possibility of driving this process through visible photons holds tremendous potential for several aspects of quantum…

Chiral molecules can selectively transport electrons of a particular spin orientation, yet the underlying mechanism remain poorly understood. Here, we present theoretical evidence that electrons propagating through chiral materials with…

Materials Science · Physics 2024-03-01 Xiaoming Wang , Yeming Xian , Yanfa Yan

Highly spin selective transport of electrons through a helically shaped electrostatic potential is demonstrated in the frame of a minimal model approach. The effect is significant even in the case of weak spin-orbit coupling. Two main…

Mesoscale and Nanoscale Physics · Physics 2015-05-30 R. Gutierrez , E. Diaz , R. Naaman , G. Cuniberti

We describe theoretically the process of multi-beam reflection in a two-dimensional electron system with a lateral potential barrier. Due to spin-orbital interaction, the reflection process leads to the formation of three beams with…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 A. O. Govorov , A. V. Kalameitsev , J. P. Dulka

Chiral-induced spin selectivity (CISS) is a phenomenon in which electron spins are polarized as they are transported through chiral molecules, and the spin polarization depends on the handedness of the chiral molecule. In this study, we…

Mesoscale and Nanoscale Physics · Physics 2023-02-09 Nguyen Thanh Phuc

A spin-charge recombination route to superconductivity, proposed earlier (1992)], is examined using the Schwinger boson representation of the t-J model. The representation is known to work well at half-filling. It was shown in the earlier…

Condensed Matter · Physics 2007-05-23 Sanjoy K. Sarker

The helical distribution of the electronic density in chiral molecules, such as DNA and bacteriorhodopsin, has been suggested to induce a spin-orbit coupling interaction that may lead to the so-called chirality-induced spin selectivity…

Mesoscale and Nanoscale Physics · Physics 2020-01-01 Miguel A. Sierra , David Sanchez , Rafael Gutierrez , Gianaurelio Cuniberti , Francisco Dominguez-Adame , Elena Diaz

In connection to the chiral-induced spin-selectivity (CISS) effect, we theoretically analyze the electronic and spin states of edges of a finite $p$-orbital helical atomic chain with the intra-atomic spin-orbit interaction (SOI). This model…

Mesoscale and Nanoscale Physics · Physics 2023-12-25 Takemitsu Kato , Yasuhiro Utsumi , Ora Entin-Wohlman , Amnon Aharony

Recent observations of considerable spin polarization in photoemission from metal surfaces through monolayers of chiral molecules were followed by several efforts to rationalize the results as the effect of spin-orbit interaction that…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Joel Gersten , Kristen Kaasbjerg , Abraham Nitzan

Interacting one-dimensional conductors with Rashba spin-orbit coupling are shown to exhibit a spin-selective Peierls-type transition into a mixed spin-charge-density-wave state. The transition leads to a gap for one-half of the conducting…

Mesoscale and Nanoscale Physics · Physics 2010-08-03 Bernd Braunecker , George I. Japaridze , Jelena Klinovaja , Daniel Loss

Chirality-induced spin selectivity (CISS) was recently observed in photo-excited donor-chiral bridge-acceptor molecules, but a predictive theory able to explain available experiments is still lacking. Here we show that low-energy torsional…

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