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We present a novel method to measure transient photovoltage at nanointerfaces using ultrafast electron diffraction. In particular, we report our results on the photoinduced electronic excitations and their ensuing relaxations in a…

Materials Science · Physics 2009-11-13 Ryan A. Murdick , Ramani K. Raman , Yoshie Murooka , Chong-Yu Ruan

Binary mixtures of water with lower alcohols display non-linear phase behaviour upon mixing which are attributed to potential cluster formation at molecular level. Unravelling such elusive structures requires the investigation of…

Soft Condensed Matter · Physics 2023-10-09 Riccardo Morbidini , Robert M. Edkins , Mark Devonport , Gøran Nilsen , Tilo Seydel , Katharina Edkins

When a chemical bond is broken, the molecular structure undergoes a transformation. An ideal experiment should probe the change in the electronic and nuclear structure simultaneously. Here, we present a method for the simultaneous…

Atomic Physics · Physics 2024-10-11 Saurabh Mhatre , Zack Dube , André Staudte , Stefanie Gräfe , Matthias Kübel

(short version) Accurate determination of the coherent static structure factor of disordered materials containing proton nuclei is prohibitively difficult by neutron diffraction, due to the large incoherent cross section of $^1$H. This…

Soft Condensed Matter · Physics 2021-01-28 László Temleitner , Anne Stunault , Gabriel Cuello , László Pusztai

Ultrafast spectroscopies can access the dynamics of electrons and nuclei at short timescales, shedding light on nonequilibrium phenomena in materials. However, development of accurate calculations to interpret these experiments has lagged…

Materials Science · Physics 2021-05-05 Xiao Tong , Marco Bernardi

We present results predicting experimentally measurable structural quantities from molecular dynamics studies of hydrogen. In doing this, we propose a paradigm shift for experimentalists -- that the predictions from such calculations should…

Materials Science · Physics 2020-03-25 Graeme J. Ackland , John S. Loveday

Visualizing the electron dynamics in four dimensions of space and time is crucial to the understanding of several ubiquitous processes in nature. Hence, ultrafast X-ray and electron imaging tools have been developed to probe the dynamics of…

Mesoscale and Nanoscale Physics · Physics 2024-11-26 Mingrui Yuan , Nikolay V. Golubev

Melting is an everyday phase transition that is determined by thermodynamic parameters like temperature and pressure. In contrast, ultrafast melting is governed by the microscopic response to a rapid energy input and, thus, can reveal the…

X-ray as well as electron diffraction are powerful tools for structure determination of molecules. Studies on randomly oriented molecules in the gas-phase address cases in which molecular crystals cannot be generated or the interaction-free…

We have observed the signatures of valence electron rearrangement in photoexcited ammonia using ultrafast hard X-ray scattering. Time-resolved X-ray scattering is a powerful tool for imaging structural dynamics in molecules because of the…

Attosecond streaking of photoelectrons emitted by extreme ultraviolet light has begun to reveal how electrons behave during their transport within simple crystalline solids. Many sample types within nanoplasmonics, thin-film physics, and…

It has been argued that in atomic-resolution transmission electron microscopy (TEM) of sparse weakly scattering structures, such as small biological molecules, multiple electron scattering usually has only a small effect, while the…

Optics · Physics 2021-11-16 T. E. Gureyev , H. M. Quiney , A. Kozlov , D. M. Paganin , G. Schmalz , L. J. Allen

Gas phase ultrafast electron diffraction (GUED) has become a powerful technique to directly observe the structural dynamics of photoexcited molecules. GUED reveals information about the nuclear motions that is complementary to the…

Ultrafast electron microscopy (UEM) has found widespread applications in physics, chemistry, and materials science, enabling real-space imaging of dynamics on ultrafast timescales. Recent advances have pushed the temporal resolution of UEM…

An ultrafast photoemission-based low-energy electron diffraction experiment with monolayer surface sensitivity is presented. In a first experiment on tin-phthalocyanine adsorbed on graphite, we demonstrate a time resolution of approx. 100…

Mesoscale and Nanoscale Physics · Physics 2024-04-23 Hermann Erk , Carl Eric Jensen , Stephan Jauernik , Michael Bauer

Electrical pulse stimulation drives many important physical phenomena in condensed matter as well as in electronic systems and devices. Often, nanoscopic and mesoscopic mechanisms are hypothesized, but methods to image electrically driven…

Mesoscale and Nanoscale Physics · Physics 2023-06-05 Thomas E Gage , Daniel B Durham , Haihua Liu , Supratik Guha , Ilke Arslan , Charudatta Phatak

The ultrafast response of metals to light is governed by intriguing non-equilibrium dynamics involving the interplay of excited electrons and phonons. The coupling between them gives rise to nonlinear diffusion behavior on ultrashort…

The charge and proton dynamics in hydrogen-bonded networks are investigated using ammonia as a model system. The fragmentation dynamics of medium-sized clusters (1-2 nm) upon single photon multi-ionization is studied, by analyzing the…

Although liquid water has been studied for many decades by (X-ray and neutron) diffraction measurements, new experimental results keep appearing, virtually every year. The reason for this is that neither X-ray, nor neutron diffraction data…

Soft Condensed Matter · Physics 2016-02-25 Ildikó Pethes , László Pusztai

We present two methods for computing the dynamic structure factor for warm dense hydrogen without invoking either the Born-Oppenheimer approximation or the Chihara decomposition, by employing a wave-packet description that resolves the…