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Molecular clusters of 1,3-butadiene were theoretically investigated using a variety of approaches, encompassing classical force fields and different quantum chemical (QC) methods, as well as density-functional based tight-binding (DFTB) in…

Chemical Physics · Physics 2020-12-15 J. Douady , A. Simon , M. Rapacioli , F. Calvo , E. Yurtsever , A. Tekin

We study the formation of clusters consisting of several chains in dilute solutions of amphiphilic heteropolymers. By means of the Gaussian variational theory we show that in a region of the phase diagram within the conventional two-phase…

Soft Condensed Matter · Physics 2009-10-31 E. G. Timoshenko , Yu. A. Kuznetsov

We created a computational workflow to analyze the potential energy surface (PES) of materials using machine-learned interatomic potentials in conjunction with the minima hopping algorithm. We demonstrate this method by producing a…

Materials Science · Physics 2025-02-14 Hossein Tahmasbi , Kushal Ramakrishna , Mani Lokamani , Attila Cangi

Treating realistically the ambient water is one of the main difficulties in applying Monte Carlo methods to protein folding. The solvent-accessible area method, a popular method for treating water implicitly, is investigated by means of…

Soft Condensed Matter · Physics 2007-05-23 Hsiao-Ping Hsu , Bernd A. Berg , Peter Grassberger

We present a first principles-quality potential energy surface (PES) describing the inter-atomic forces for hydrogen atoms interacting with free-standing graphene. The PES is a high-dimensional neural network potential that has been…

We enumerate all minimal energy packings (MEPs) for small single linear and ring polymers composed of spherical monomers with contact attractions and hard-core repulsions, and compare them to corresponding results for monomer packings. We…

Soft Condensed Matter · Physics 2015-05-18 Robert S. Hoy , Corey S. O'Hern

Several commonly observed physical and biological systems are arranged in shapes that closely resemble an honeycomb cluster, that is, a tessellation of the plane by regular hexagons. Although these shapes are not always the direct product…

Optimization and Control · Mathematics 2025-01-10 Marco Caroccia , Kenneth DeMason , Francesco Maggi

We perform a comprehensive survey of the potential energy landscapes of 13-atom Morse clusters, and describe how they can be characterized and visualized. Our aim is to detail how the global features of the funnel-like surface change with…

Statistical Mechanics · Physics 2009-10-31 Mark A. Miller , Jonathan P. K. Doye , David J. Wales

We present an efficient algorithm for calculating the minimum energy path (MEP) and energy barriers between local minima on a multidimensional potential energy surface (PES). Such paths play a central role in the understanding of transition…

Computational Physics · Physics 2012-04-19 Amit Samanta , Weinan E

In order to investigate the phase stability of equiatomic FeN compounds and the structure-dependent magnetic properties, the electronic structure and total energy of FeN with NaCl, ZnS and CsCl structures and various magnetic configurations…

Materials Science · Physics 2009-10-31 Yong Kong

Spectroscopic properties of low-lying states and cluster structures in $^{12}$C are analyzed in a "beyond mean-field framework" based on global energy density functionals (EDFs). To build symmetry-conserving collective states,…

Nuclear Theory · Physics 2019-03-20 Petar Marević , Jean-Paul Ebran , Elias Khan , Tamara Nikšić , Dario Vretenar

The low-energy structures of mixed Ar--Xe and Kr--Xe Lennard-Jones clusters are investigated using a newly developed parallel Monte Carlo minimization algorithm with specific exchange moves between particles or trajectories. Tests on the…

Atomic and Molecular Clusters · Physics 2009-11-10 F. Calvo , E. Yurtsever

We present an efficient method to find minimum energy structures using energy estimates from accurate quantum Monte Carlo calculations. This method involves a stochastic process formed from the stochastic energy estimates from Monte Carlo…

Computational Physics · Physics 2015-05-18 Lucas K. Wagner , Jeffrey C. Grossman

Likely candidates for the global potential energy minima of (H$_{2}$O)$_{n}$ clusters with $n\leq21$ on the (0001)-surface of graphite are found using basin-hopping global optimization. The potential energy surfaces are constructed using…

Atomic and Molecular Clusters · Physics 2007-10-10 B. S. Gonzalez , J. Hernandez-Rojas , J. Breton , J. M. Gomez Llorente

We describe a global optimization technique using `basin-hopping' in which the potential energy surface is transformed into a collection of interpenetrating staircases. This method has been designed to exploit the features which recent work…

Condensed Matter · Physics 2007-05-23 David Wales , Jonathan Doye

The lowest energy configurations of Cn(n =< 55) clusters are obtained using the energy mini- mization technique with the conjugate gradient (CG) method where a modified Brenner potential is invoked to describe the carbon and hydrocarbon…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 D. P. Kosimov , A. A. Dzhurakhalov , F. M. Peeters

Pentacene has been used widely in organic devices, and the interface structure between pentacene and a substrate is known to significantly influence device performances. Here we demonstrate that molecular ordering of pentacene on graphene…

Mesoscale and Nanoscale Physics · Physics 2015-06-19 W. Jung , D. -H. Oh , I. Song , H. -C. Shin , S. J. Ahn , Y. Moon , C. -Y. Park , J. R. Ahn

We have studied the structure and properties of potassium clusters containing even number of atoms ranging from 2 to 20 at the ab initio level. The geometry optimization calculations are performed using all-electron density functional…

Atomic and Molecular Clusters · Physics 2016-09-28 Arup Banerjee , Tapan K. Ghanty , Aparna Chakrabarti

Evolutionary algorithm is combined with full-potential ab-initio calculations to investigate conformational space of (MoS$_2$)$_n$ and (MoSe$_2$)$_n$ (n=1-10) nanoclusters and to identify the lowest energy structural isomers of these…

Materials Science · Physics 2018-04-04 Zohre Hashemi , Shohreh Rafiezadeh , Roohollah Hafizi , S. Javad Hashemifar , Hadi Akbarzadeh

Photovoltaic (PV) devices made from blends of a polyarylamine biscarbonate ester (PABC) and [6,6]-phenyl $C_{61}$ butyric acid methyl ester (PCBM) have been fabricated and characterized. PABC is a hole transporting co-polymer prepared from…