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We propose a computationally lean, two-stage approach that reliably predicts self-assembly behavior of complex charged molecules on a metallic surfaces under electrochemical conditions. Stage one uses ab initio simulations to provide…

Computational Physics · Physics 2020-07-15 Benedikt Hartl , Shubham Sharma , Oliver Brügner , Stijn F. L. Mertens , Michael Walter , Gerhard Kahl

Interstellar molecules, which play an important role in astrochemistry, are identified using observed spectral lines. Despite the advent of spectral analysis tools in the past decade, the identification of spectral lines remains a tedious…

Astrophysics of Galaxies · Physics 2025-02-07 Yisheng Qiu , Tianwei Zhang , Thomas Möller , XueJian Jiang , Zihao Song , Huaxi Chen , Donghui Quan

With the development of low order scaling methods for performing Kohn-Sham Density Functional Theory, it is now possible to perform fully quantum mechanical calculations of systems containing tens of thousands of atoms. However, with an…

Chemical Physics · Physics 2020-04-03 William Dawson , Stephan Mohr , Laura E. Ratcliff , Takahito Nakajima , Luigi Genovese

Nuclear Magnetic Resonance (NMR) spectroscopy is particularly well-suited to determine the structure of molecules and materials in powdered form. Structure determination usually proceeds by finding the best match between experimentally…

Scanning tunneling microscopy (STM) has been a fundamental tool to characterize many-body effects in condensed matter systems, from extended solids to quantum dots. STM of molecules decoupled from the supporting conductive substrate has the…

Mesoscale and Nanoscale Physics · Physics 2011-01-14 Dimitrios Toroz , Massimo Rontani , Stefano Corni

A recently proposed mutual information based algorithm for decomposing data into least dependent components (MILCA) is applied to spectral analysis, namely to blind recovery of concentrations and pure spectra from their linear mixtures. The…

Data Analysis, Statistics and Probability · Physics 2007-07-13 Sergey A. Astakhov , Harald Stögbauer , Alexander Kraskov , Peter Grassberger

One of the molecular properties most intuitive to the human perception is the geometrical shape. However, when exploring a large chemical space the determination of shape needs to be automated. We present a fast and simple approach to…

Chemical Physics · Physics 2019-04-16 Guido Falk von Rudorff

Accurate classification of molecular chemical motifs from experimental measurement is an important problem in molecular physics, chemistry and biology. In this work, we present neural network ensemble classifiers for predicting the presence…

Materials Science · Physics 2023-06-29 Matthew R. Carbone , Phillip M. Maffettone , Xiaohui Qu , Shinjae Yoo , Deyu Lu

A method for making realistic estimates of the density of levels in even-even nuclei is presented making use of the Monte Carlo shell model (MCSM). The procedure follows three basic steps: (1) computation of the thermal energy with the…

Nuclear Theory · Physics 2009-10-30 W. E. Ormand

Molecular structure elucidation from spectroscopic data is a long-standing challenge in Chemistry, traditionally requiring expert interpretation. We introduce NMIRacle, a two-stage generative framework that builds upon recent paradigms in…

Chemical Physics · Physics 2026-03-12 Federico Ottomano , Yingzhen Li , Alex M. Ganose

Motivation: Tumor classification using Imaging Mass Spectrometry (IMS) data has a high potential for future applications in pathology. Due to the complexity and size of the data, automated feature extraction and classification steps are…

Machine Learning · Statistics 2018-06-28 Jens Behrmann , Christian Etmann , Tobias Boskamp , Rita Casadonte , Jörg Kriegsmann , Peter Maass

Nuclear Magnetic Resonance (NMR) Spectroscopy is the second most used technique (after X-ray crystallography) for structural determination of proteins. A computational challenge in this technique involves solving a discrete optimization…

Artificial Intelligence · Computer Science 2021-09-09 Jose F. S. Bravo-Ferreira , David Cowburn , Yuehaw Khoo , Amit Singer

Complexity measures are essential to understand complex systems and there are numerous definitions to analyze one-dimensional data. However, extensions of these approaches to two or higher-dimensional data, such as images, are much less…

Data Analysis, Statistics and Probability · Physics 2012-12-27 H. V. Ribeiro , L. Zunino , E. K. Lenzi , P. A. Santoro , R. S. Mendes

The structure of proteins is essential for its function. The determination of protein structures is possible by experimental or predicted by computational methods, but also a combination of both approaches is possible. Here, first an…

Other Quantitative Biology · Quantitative Biology 2020-03-03 Gerhard Mayer

A new generalized Statistical Complexity Measure (SCM) was proposed by Rosso et al in 2010. It is a functional that captures the notions of order/disorder and of distance to an equilibrium distribution. The former is computed by a measure…

Information Theory · Computer Science 2012-07-04 Eliana S. de Almeida , Antonio Carlos de Medeiros , Osvaldo A. Rosso , Alejandro C. Frery

Liquid state NMR is a powerful tool for the analysis of complex mixtures of unknown molecules. This capacity has been used in many analytical approaches: metabolomics, identification of active compounds in natural extracts, characterization…

The pathway toward the tailored synthesis of materials starts with precise characterization of the conformational properties and dynamics of individual molecules. Electron spin resonance based scanning tunneling microscopy can potentially…

This paper introduces a novel approach for automated estimation of plasma temperature and density using emission spectroscopy, integrating Bayesian inference with sophisticated physical models. We provide an in-depth examination of Bayesian…

Plasma Physics · Physics 2023-12-21 Todd A. Oliver , Craig Michoski , Samuel Langendorf , Andrew LaJoie

Urea, NH2C(O)NH2, is a molecule of great importance in organic chemistry and biology. Two searches for urea in the interstellar medium were reported in the past, but neither were conclusive. We want to take advantage of the increased…

Astrophysics of Galaxies · Physics 2019-07-31 A. Belloche , R. T. Garrod , H. S. P. Müller , K. M. Menten , I. Medvedev , J. Thomas , Z. Kisiel

We show that combining vibrational spectroscopy with signal processing can result in a scheme for ultrasensitive detection of molecules. We consider the vibrational spectrum as a signal on the energy axis and apply a matched filter on that…

Computational Physics · Physics 2018-12-10 Tay Yong Boon , Ian Tay Rongde , Loy Liang Yi , Aw Ke Fun , Ong Zhi Li , Sergei Manzhos