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Related papers: Quantum Simulation of non-Born-Oppenheimer dynamic…

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The introduction of nonlinearities in the Schr\"odinger equation has been considered in the literature as an effective manner to describe the action of external environments or mean fields. Here, in particular, we explore the nonlinear…

Quantum Physics · Physics 2024-03-08 David Navia , Ángel S. Sanz

The exact path integration for a family of maximally super-integrable systems generalizing the hydrogen atom in the $n$-dimensional Euclidean space is presented. The Green's function is calculated in parabolic rotational and spherical…

Quantum Physics · Physics 2007-05-23 M. T. Chefrour , F. Benamira , L. Guechi , S. Mameri

In this paper, we have constructed the Feynman path integral method for non-paraxial optics. This is done by using the mathematical analogy between a non-paraxial optical system and the generalized Schr\"odinger equation deformed by the…

A basis set of generalized nonspherical Gaussian functions (GGTOs) is presented and discussed. As a first example we report on Born-Oppenheimer energies of the hydrogen molecule. Although accurate results have been obtained, we conclude…

Chemical Physics · Physics 2009-10-31 T. Detmer , P. Schmelcher , L. S. Cederbaum

Quantum computers can be used to simulate nonlinear non-Hamiltonian classical dynamics on phase space by using the generalized Koopman-von Neumann formulation of classical mechanics. The Koopman-von Neumann formulation implies that the…

Quantum Physics · Physics 2020-10-27 Ilon Joseph

In this paper we study the semiclassical limit of the Schr\"odinger equation. Under mild regularity assumptions on the potential $U$ which include Born-Oppenheimer potential energy surfaces in molecular dynamics, we establish asymptotic…

Analysis of PDEs · Mathematics 2010-06-29 Luigi Ambrosio , Alessio Figalli , Gero Friesecke , Johannes Giannoulis , Thierry Paul

We introduce a novel approach for a fully quantum description of coupled electron-ion systems from first principles. It combines the variational quantum Monte Carlo (QMC) solution of the electronic part with the path integral (PI) formalism…

Chemical Physics · Physics 2018-03-06 Félix Mouhat , Sandro Sorella , Rodolphe Vuilleumier , Antonino M. Saitta , Michele Casula

Input-output theory is a well-known tool in quantum optics and ubiquitous in the description of quantum systems probed by light. Owing to the generality of the setup it describes, the theory finds application in a wide variety of…

Quantum Physics · Physics 2026-04-30 Aaron Daniel , Matteo Brunelli , Aashish A. Clerk , Patrick P. Potts

Mean-field molecular dynamics based on path integrals is used to approximate canonical quantum observables for particle systems consisting of nuclei and electrons. A computational bottleneck is the sampling from the Gibbs density of the…

Numerical Analysis · Mathematics 2023-11-30 Xin Huang , Petr Plechac , Mattias Sandberg , Anders Szepessy

We leverage the power of neural quantum states to describe the ground state wave function of solid and liquid atomic hydrogen, including both electronic and protonic degrees of freedom. For static protons, the resulting Born-Oppenheimer…

Strongly Correlated Electrons · Physics 2026-04-27 David Linteau , Saverio Moroni , Giuseppe Carleo , Markus Holzmann

In this work, we used a tool of conventional Nikiforov-Uvarov method to determine bound state solution of Schrodinger equation with quantum interaction potential called Hulthen-Yukawa inversely quadratic potential (HYIQP). We obtained the…

Quantum Physics · Physics 2017-02-15 Ituen B. Okon , Oyebola Popoola , Cecilia N. Isonguyo

Recent advances in the spectroscopy of biomolecules have highlighted the possibility of quantum coherence playing an active role in biological energy transport. The revelation that quantum coherence can survive in the hot and wet…

Quantum Physics · Physics 2012-06-12 Ross Dorner , John Goold , Vlatko Vedral

Two path integral representations for the $T$-matrix in nonrelativistic potential scattering are derived and proved to produce the complete Born series when expanded to all orders. They are obtained with the help of "phantom" degrees of…

Nuclear Theory · Physics 2009-07-28 R. Rosenfelder

Simulations of chemical dynamics are a powerful means for understanding chemistry. However, classical computers struggle to simulate many chemical processes, especially non-adiabatic ones, where the Born-Oppenheimer approximation breaks…

We present a new Monte Carlo method which couples Path Integral for finite temperature protons with Quantum Monte Carlo for ground state electrons, and we apply it to metallic hydrogen for pressures beyond molecular dissociation. This…

Statistical Mechanics · Physics 2009-11-10 Markus Holzmann , Carlo Pierleoni , David M. Ceperley

To simulate plasma phenomena, large-scale computational resources have been employed in developing high-precision and high-resolution plasma simulations. One of the main obstacles in plasma simulations is the requirement of computational…

Quantum Physics · Physics 2025-11-17 Hayato Higuchi , Yuki Ito , Kazuki Sakamoto , Keisuke Fujii , Akimasa Yoshikawa

State-of-the-art {\em ab initio} techniques have been applied to compute the potential energy curves of the (BaRb)$^+$ molecular ion in the Born-Oppenheimer approximation. The long-range coefficients describing the electrostatic, induction,…

In this paper the path integral technique is applied to the quantum motion on the Hermitian hyperbolic space HH(2). The Schr\"odinger equation on this space separates in 12 coordinate systems which are closely related to the coordinate…

Exactly Solvable and Integrable Systems · Physics 2009-11-10 Christian Grosche

We develop a Born-Oppenheimer type formalism for the description of quantum thermal transport along hybrid nanoscale objects. Our formalism is suitable for treating heat transfer in the off-resonant regime, where e.g., the relevant…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Lian-Ao Wu , Dvira Segal

Starting with the exact factorization of the molecular wavefunction, this paper presents the results from the numerical implementation in nonadiabatic molecular dynamics of the recently proposed bohmion method. Within the context of quantum…

Chemical Physics · Physics 2021-10-06 Darryl D. Holm , Jonathan I. Rawlinson , Cesare Tronci
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