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In this work, the tetrahydrofuran (THF) hydrate-water interfacial free energy is determined at $500\,\text{bar}$, at one point of the univariant two-phase coexistence line of the THF hydrate, by molecular dynamics simulation. The Mold…

Freezing in the vicinity of water-vapor interfaces is of considerable interest to a wide range of disciplines, most notably the atmospheric sciences. In this work, we use molecular dynamics and two advanced sampling techniques, forward flux…

Statistical Mechanics · Physics 2014-11-04 Amir Haji-Akbari , Ryan S. DeFever , Sapna Sarupria , Pablo G. Debenedetti

Crystallization of supersaturated liquids usually starts by heterogeneous nucleation. Mounting evidence shows that even homogeneous nucleation in simple liquids takes place in two steps; first a dense amorphous precursor forms, and the…

Materials Science · Physics 2014-07-15 László Gránásy , Frigyes Podmaniczky , Gyula I. Tóth , György Tegze , Tamás Pusztai

Surface icing affects the safety and performance of numerous processes in technology. Previous studies mostly investigated freezing of individual droplets. The interaction among multiple droplets during freezing is investigated less,…

Soft Condensed Matter · Physics 2019-01-23 Gustav Graeber , Valentin Dolder , Thomas M. Schutzius , Dimos Poulikakos

In this work, we perform a systematic computer simulation study of ice premelting, and explore the thickness and structure of quasi-liquid layers formed at the interface of ice with substrates of different hydrophilicity. Our study shows…

Soft Condensed Matter · Physics 2024-10-30 Łukasz Baran , Pablo Llombart , Luis G. MacDowell

Freezing or solidification of impacting droplets is omnipresent in nature and technology, be it a rain droplet falling on a supercooled surface, be it in inkjet printing where often molten wax is used, be it in added manufacturing or in…

Soft Condensed Matter · Physics 2020-02-05 Pallav Kant , Robin B. J. Koldeweij , Kirsten Harth , Michiel A. J. van Limbeek , Detlef Lohse

Ice nucleation is a process of great relevance in physics, chemistry, technology and environmental sciences, much theoretical and experimental efforts have been devoted to its understanding, but still it remains a topic of intense research.…

Soft Condensed Matter · Physics 2019-06-26 Haiyang Niu , Yi Isaac Yang , Michele Parrinello

The injection of liquid fuel at supercritical pressures is a relevant but overlooked topic in combustion. Typically, the role of two-phase dynamics is neglected under the assumption that the liquid rapidly transitions to a supercritical…

Fluid Dynamics · Physics 2024-01-17 Jordi Poblador-Ibanez , William A. Sirignano

A model for the formation of cavitation nuclei in liquids has recently been presented with basis in interfacial liquid tension at non-planar solid surfaces of concave form. In the present paper investigations of water-solid interfaces by…

Fluid Dynamics · Physics 2007-05-23 Niels Asger Mortensen , Anders Kuhle , Knud A. Morch

When moist air meets a cold surface, it creates a breath figure characterized by numerous small droplets. The central question is how the vapor flux is distributed between the growth of previously condensed drops and the nucleation of new…

Fluid Dynamics · Physics 2025-08-27 Ambre Bouillant , Christopher Henkel , Uwe Thiele , Bruno Andreotti , Jacco H. Snoeijer

The process of homogeneous crystal nucleation has been considered in a model liquid, where the interparticle interaction is described by a short-range spherical oscillatory potential. Mechanisms of initiating structural ordering in the…

Materials Science · Physics 2018-12-18 Bulat N. Galimzyanov , Dinar T. Yarullin , Anatolii V. Mokshin

When an ice crystal is born from liquid water two key changes occur: (i) the molecules order; and (ii) the mobility of the molecules drops as they adopt their lattice positions. Most research on ice nucleation (and crystallization in…

Chemical Physics · Physics 2019-03-27 Martin Fitzner , Gabriele C. Sosso , Stephen J. Cox , Angelos Michaelides

The atomisation of suspension containing liquid and dispersed particles is prevalent in many applications. Previous studies of droplet breakup mainly focused on homogeneous fluids, and the heterogeneous effect of particles on the breakup…

Fluid Dynamics · Physics 2024-03-19 Zhikun Xu , Tianyou Wang , Zhizhao Che

Spherical-cap-shaped interfacial nanobubbles (NBs) forming on hydrophobic surfaces in aqueous solutions have extensively been studied both from a fundamental point of view and due to their relevance for various practical applications. In…

Fluid Dynamics · Physics 2022-08-18 Yuliang Wang , Xiaolai Li , Shuai Ren , Hadush Tedros Alem , Lijun Yang , Detlef Lohse

The impact of nucleating gas bubbles in the form of a dispersed gas phase on hydrogen isotope permeation at interfaces between liquid metals, like LLE, and structural materials, like stainless steel, has been studied. Liquid metal to…

Fluid Dynamics · Physics 2013-10-28 Jorge Fradera , Santiago Cuesta-López

The understanding of geochemical interactions between H2 and geofluids is of great importance for underground H2 storage but requires further study. We report the first investigation on the three-phase fluid mixture containing H2, H2O, and…

Chemical Physics · Physics 2023-07-31 Yafan Yang , Jingyu Wan , Jingfa Li , Guangsi Zhao , Xiangyu Shang

Using all-atomic molecular dynamics(MD) simulations, we show that various substrates could induce interfacial water (IW) to form the same ice-like oxygen lattice but different hydrogen polarity order, and regulate the heterogeneous ice…

Computational Physics · Physics 2020-02-19 Mingzhe Shao , Chuanbiao Zhang , Conghai Qi , Chunlei Wang , Jianjun Wang , Fangfu Ye , Xin Zhou

Premelting at the ice-polymer interfaces, in which a quasi-liquid layer (QLL) forms below the melting point, is strongly influenced by polymer surface chemistry; however, the molecular-scale mechanisms underlying these effects remain poorly…

Soft Condensed Matter · Physics 2025-04-29 Takumi Sato , Ikki Yasuda , Noriyoshi Arai , Kenji Yasuoka

Understanding the dynamics in the deposition of water droplets onto solid surfaces is of importance from both fundamental and practical viewpoints. While the deposition of a water droplet onto a heated surface is extensively studied, the…

Fluid Dynamics · Physics 2019-05-22 Yugang Zhao , Fangqi Zhu , Hui Zhang , Chun Yang , Tze How New , Liwen Jin

This paper deals with the condensation of liquid droplets on hydrophobic and hydrophilic surfaces. A stochastic mesoscale model based on the theory of fluctuating hydrodynamics and the thermodynamics of a diffuse interface approach shows…

Soft Condensed Matter · Physics 2025-06-30 Matteo Teodori , Dario Abbondanza , Mirko Gallo , Carlo Massimo Casciola