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State-of-the-art electrocaloric cooling prototypes rely on the conventional electrocaloric effect of ferroelectric lead scandium tantalate (PbSc0.5Ta0.5O3, PST), which peaks near room temperature. Here, we demonstrate that A-site calcium…

Barocaloric (BC) effects at liquid-vapor transitions in hydrofluorocarbons drive most commercial technologies used for heating and cooling in the heating, ventilation and air-conditioning sector. However, these fluids suffer from huge…

There is a surge of interest in developing environmentally friendly cooling technology based on the solid--state electrocaloric effect (ECE). Here, we point out that negative ECE with a fast cooling rate ($\approx$10$^{11}$ K/s) can be…

Materials Science · Physics 2018-02-07 Yubo Qi , Shi Liu , Aaron M. Lindenberg , Andrew M. Rappe

Solid-state cooling is an environmentally friendly and highly scalable technology that may solve most of the problems associated with current refrigerant methods. Solid-state cooling consists of applying external fields on caloric…

Materials Science · Physics 2019-06-07 Claudio Cazorla

In acceptor doped ferroelectrics and in ferroelectric films and nanocomposites, defect dipoles, strain gradients, and the electric boundary conditions at interfaces and surfaces often impose internal bias fields. In this work we delicately…

Materials Science · Physics 2018-09-05 Yang-Bin Ma , Bai-Xiang Xu , Karsten Albe , Anna Grünebohm

In the framework of solid-state cooling technology, four kinds of caloric effects, magnetocaloric (MC), electrocaloric (EC), barocaloric (BC) and elastocaloric (eC) effects, are compared in view of environment discussion and application…

Materials Science · Physics 2016-04-21 Zhongjian Xie , Gael Sebald , Daniel Guyomar

Direct electronic structure measurements of a variety of the colossal magnetoresistive oxides show the presence of a pseudogap at the Fermi energy E_F which drastically suppresses the electron spectral function at E_F. The pseudogap is a…

Strongly Correlated Electrons · Physics 2016-08-31 T. Saitoh , D. S. Dessau , Y. Moritomo , T. Kimura , Y. Tokura , N. Hamada

The electrocaloric (EC) effect is the reversible change in temperature and/or entropy of a material when it is subjected to an adiabatic electric field change. Our tight-binding calculations linked to Fermi statistics, show that the EC…

Mesoscale and Nanoscale Physics · Physics 2021-01-11 Natalia Cortés , Oscar Negrete , Francisco J. Peña , Patricio Vargas

Solid-state refrigeration based on caloric effects is an energetically efficient and environmentally friendly technology, which is deemed as a potential alternative to the conventional vapor-compression technology. One of the greatest…

Materials Science · Physics 2022-04-29 Qingyong Ren , Ji Qi , Dehong Yu , Wenli Song , Bao Yuan , Tianhao Wan , Weijun Ren , Zhidong Zhang , Xin Tong , Bing Li

The adiabatic elastocaloric effect relates changes in the strain that a material experiences to resulting changes in its temperature. While elastocaloric materials have been utilized for cooling in room temperature applications, the use of…

Materials Science · Physics 2025-03-06 Mark P. Zic , Linda Ye , Maya H. Martinez , Ian R. Fisher

The electrocaloric (EC) effect is calculated for Gd-substituted PMN (x = 0 to 0.1) relaxors from temperature dependent heat capacity and polarization measurements, using a thermodynamic Maxwell equation. Polarization change with temperature…

Materials Science · Physics 2018-11-01 Adityanarayan H. Pandey , A. M. Awasthi , Surya Mohan Gupta

Mechanocaloric materials experience a change in temperature when a mechanical stress is adiabatically applied on them. Thus far, only ferroelectrics and superelastic metallic alloys have been considered as potential mechanocaloric compounds…

Materials Science · Physics 2016-05-20 Claudio Cazorla , Daniel Errandonea

Perovskite-type Ba0.9Sr0.1Ti0.9Sn0.1O3(BSTSn) ceramic was synthesized by the sol gel method. The P E hysteresis loops were recorded at different temperatures to investigate the ferroelectric and energy storage properties of BSTSn ceramic.…

Materials Science · Physics 2023-06-13 S. Khardazi , H. Zaitouni , S. Belkhadir , D. Mezzane , M. Amjoud , Y. Gagou , B. Asbani , I. Lukyanchuk , S. Terenchuk

As shown in our previous studies, geometrical field grading techniques such as stacked and protruding substrate designs cannot well mitigate high electric stress issue within power electronics modules. However, it was shown that a…

Applied Physics · Physics 2020-06-29 Maryam Mesgarpour Tousi , Mona Ghassemi

We analyse the effects of applying an electric field on the critical temperature, Ts, at which superionicity appears in archetypal fast ion conductor CaF2 by means of molecular dynamics simulations. We find that the onset of superionicity…

Materials Science · Physics 2015-08-31 Claudio Cazorla

In this work, we have studied the effects from increasing the strength of the applied electric field on the charge transport of hydrogenated graphitic fibers. Resistivity measurements were carried out for direct currents in the nA - mA…

Materials Science · Physics 2020-05-19 Nadina Gheorghiu , Charles R. Ebbing , Timothy J. Haugan

During the last few years, the increasing demand of energy for refrigeration applications has relived the interest of the scientific community in the study of alternative methods to the traditional gas-based refrigeration. Within this…

Other Condensed Matter · Physics 2015-10-28 M. Quintero , P. Gaztañaga , I. Irurzun

Analytical results obtained within Landau-Ginzburg-Devonshire approach and effective media models, predict that the synergy of size effects and Vegard stresses can significantly enhance the electrocaloric cooling (up to 7 times) of the…

In this study, we report on a direct measurement method for the electrocaloric effect, the heating/cooling upon application/removal of an electric field in dielectric materials, based on a lock-in thermography technique. By use of…

Materials Science · Physics 2023-03-08 Ryo Iguchi , Daisuke Fukuda , Jun Kano , Takashi Teranishi , Ken-ichi Uchida

We report on the dielectric and electrocaloric properties of Ba$_{1-y}$Ca$_y$Ti$_{1-x}$Hf$_x$O$_3$ for compositions $0.12<x<0.18$ and $y=0.06$, as well as $x=0.15$ and $0<y<0.15$, synthesized by the conventional solid-state reaction method.…

Materials Science · Physics 2023-08-23 David Gracia , Sara Lafuerza , Javier Blasco , Marco Evangelisti