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We apply the transcorrelated method to problems of multireference character. For this, we show that the choice of reference wavefunction during the Jastrow optimisation procedure is vital, and we propose a workflow wherein we use…

Coupled-cluster theory with single, double, and perturbative triple excitations (CCSD(T)) -- often considered the "gold standard" of main-group quantum chemistry -- is inapplicable to three-dimensional metals due to an infrared divergence,…

Materials Science · Physics 2023-03-21 Verena A. Neufeld , Timothy C. Berkelbach

A relativistic version of the coupled-cluster single-double (CCSD) method is developed for atoms with a single valence electron. In earlier work, a linearized version of the CCSD method (with extensions to include a dominant class of triple…

Atomic Physics · Physics 2009-11-13 Rupsi Pal , M. S. Safronova , W. R. Johnson , Andrei Derevianko , Sergey G. Porsev

Quantum computing promises a new approach to solving difficult computational problems, and the quest of building a quantum computer has started. While the first attempts on construction were succesful, scalability has never been achieved,…

Quantum Physics · Physics 2014-08-01 Alexandru Paler , Simon J. Devitt , Kae Nemoto , Ilia Polian

\noindent Model building in $\mathsf{SO(10)}$, which is the leading grand unification framework, often involves large Higgs representations and their couplings. Explicit calculations of such couplings is a multi-step process that involves…

High Energy Physics - Phenomenology · Physics 2021-10-06 Azadan Bhagwagar , Raza M. Syed

Unsatisfiable cores (UCs) are a well established means for debugging in a declarative setting. Still, there are few tools that perform automated extraction of UCs for LTL. Existing tools compute a UC as an unsatisfiable subset of the set of…

Logic in Computer Science · Computer Science 2015-06-30 Viktor Schuppan

The bisimulation proof method can be enhanced by employing `bisimulations up-to' techniques. A comprehensive theory of such enhancements has been developed for first-order (i.e., CCS-like) labelled transition systems (LTSs) and…

Logic in Computer Science · Computer Science 2023-06-22 Jean-Marie Madiot , Damien Pous , Davide Sangiorgi

First principles methods can provide insight into materials that is otherwise impossible to acquire. Density Functional Theory (DFT) has been the first principles method of choice for numerous applications, but it falls short of predicting…

Materials Science · Physics 2019-07-24 Arpita Paul , Turan Birol

Boosted by the relentless increase of available computational resources, high-throughput calculations based on first principles methods have become a powerful tool to screen a huge range of materials. The backbone of these studies are…

Materials Science · Physics 2022-03-23 Holger-Dietrich Saßnick , Caterina Cocchi

We present a C++ software package called PhaseTracer for mapping out cosmological phases, and potential transitions between them, for Standard Model extensions with any number of scalar fields. PhaseTracer traces the minima of effective…

High Energy Physics - Phenomenology · Physics 2020-06-30 Peter Athron , Csaba Balazs , Andrew Fowlie , Yang Zhang

Unitary Coupled Cluster (UCC) theory is a promising variational method for electronic structure calculations, especially for strongly correlated systems and quantum computers. However, its practical application is limited by the steep…

Chemical Physics · Physics 2026-02-05 Prateek Vaish , Brenda Rubenstein

It has been well established that the Jastrow correlation factor can effectively capture the electron correlation effects, and thus, the efficient optimization of the many-body wave function including the Jastrow correlation factor is of…

Atomic Physics · Physics 2023-09-12 Masayuki Ochi

As an essential attribute of organic compounds, polarity has a profound influence on many molecular properties such as solubility and phase transition temperature. Thin layer chromatography (TLC) represents a commonly used technique for…

A method is presented to calculate from first principles the higher-order elastic constants of a solid material. The method relies on finite strain deformations, a density functional theory approach to calculate the Cauchy stress tensor,…

Materials Science · Physics 2025-10-08 Ruvini Attanayake , Umesh C. Roy , Abhiyan Pandit , Angelo Bongiorno

An overset grid method was used to investigate the interaction between a particle-laden flow and a circular cylinder. The overset grid method was implemented in the Pencil Code , a high-order finite-difference code for compressible flow…

Fluid Dynamics · Physics 2019-05-22 J. R. Aarnes , N. E. L. Haugen , H. I. Andersson

Lattice systems and discrete networks with dissipative interactions are successfully employed as meso-scale models of heterogeneous solids. As the application scale generally is much larger than that of the discrete links, physically…

Computational Physics · Physics 2016-11-21 Ondřej Rokoš , Lars A. A. Beex , Jan Zeman , Ron H. J. Peerlings

Quantum trajectory methods can be used for a wide range of open quantum systems to solve the master equation by unraveling the density operator evolution into individual stochastic trajectories in Hilbert space. This C++ class library…

Quantum Physics · Physics 2009-10-30 Ruediger Schack , Todd A. Brun

A block-correlated coupled cluster (BCCC) method based on the generalized valence bond (GVB) wave function (GVB-BCCC in short) is proposed and implemented at the ab initio level, which represents an attractive multireference electronic…

Chemical Physics · Physics 2023-03-16 Qingchun Wang , Mingzhou Duan , Enhua Xu , Jingxiang Zou , Shuhua Li

The rapidly growing interest in simulating condensed-phase materials using quantum chemistry methods calls for a library of high-quality Gaussian basis sets suitable for periodic calculations. Unfortunately, most standard Gaussian basis…

Chemical Physics · Physics 2022-06-07 Hong-Zhou Ye , Timothy C. Berkelbach

A major difficulty in quantum simulation is the adequate treatment of a large collection of entangled particles, synonymous with electron correlation in electronic structure theory, with coupled cluster (CC) theory being the leading…

Chemical Physics · Physics 2024-06-06 Zachary W. Windom , Daniel Claudino , Rodney J. Bartlett