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We theoretically investigate the role of complex dipole phase in the attosecond probing of charge migration. The iodobromoacetylene ion (ICCBr$^+$) is considered as an example, in which one can probe charge migration by accessing both the…

Chemical Physics · Physics 2022-02-23 Yuki Kobayashi , Daniel M. Neumark , Stephen R. Leone

Molecular ions can be held in a chain of laser-cooled atomic ions by sympathetic cooling. This system is ideal for performing high-precision molecular spectroscopy with applications in astrochemistry and fundamental physics. Here we show…

Atomic Physics · Physics 2015-08-20 Ncamiso B. Khanyile , Gang Shu , Kenneth R. Brown

Coherently displaced harmonic oscillator number states of a harmonically bound ion can be coupled to two internal states of the ion by a laser-induced motional sideband interaction. The internal states can subsequently be read out in a…

We report an ultrafast and efficient way to create the maximum coherence between the two lower states in a -like atomic systems, driven by two nonlinearly chirped few-cycle pulses. The phenomenon of coherent population trapping and…

Quantum Physics · Physics 2011-11-18 Amarendra K. Sarma , Parvendra Kumar

Nonstationary molecular states which contain electronic coherences can be impulsively created and manipulated by using recently-developed ultrashort optical and X-ray pulses via photoexcitation, photoionization and Auger processes. We…

Chemical Physics · Physics 2015-09-02 Konstantin E. Dorfman , Kochise Bennett , Shaul Mukamel

Ion Mobility Spectrometry (IMS) is a well-known, sensitive and rapid technique to detect dangerous organic compounds. We propose a system in which a crown type discharge generates a ionic flow that is swept towards an array of collectors by…

We apply dynamical mean field theory to study a prototypical model that describes charge ordering in the presence of both electron-lattice interactions and intersite electrostatic repulsion between electrons. We calculate the optical and…

Strongly Correlated Electrons · Physics 2009-11-13 S. Ciuchi , S. Fratini

We present systematic comparison of three quantum mechanical approaches describing excitation dynamics in molecular complexes using the Time-Dependent variational principle (TDVP) with three increasing sophistication trial wavefunctions…

Chemical Physics · Physics 2023-06-02 Mantas Jakučionis , Agnius Žukas , Darius Abramavičius

With a classical ensemble model that including electron correlations during the whole ionization process, we investigated strong-field sequential double ionization of Ar by elliptically polarized pulses at the quantitative level. The…

Atomic Physics · Physics 2015-06-04 Yueming Zhou , Cheng Huang , Qing Liao , Peixiang Lu

We investigate a double-layer of penetrable ions near a charged wall. We find a new mechanism for charge reversal that occurs in the weak-coupling regime and, accordingly, the system is suitable for the mean-field analysis. The…

Soft Condensed Matter · Physics 2013-05-06 Derek Frydel , Yan Levin

Revealing possible long-living coherence in ultrafast processes allows detecting genuine quantum mechanical effects in molecules. To investigate such effects from a quantum chemistry perspective, we have developed a method for simulating…

Chemical Physics · Physics 2018-07-04 Emanuele Coccia , Filippo Troiani , Stefano Corni

The quasi-neutral hybrid model with kinetic ions and fluid electrons is a promising approach for bridging the inherent multi-scale nature of many problems in space and laboratory plasmas. Here, a novel, implicit, particle-in-cell based…

Plasma Physics · Physics 2018-11-14 A. Stanier , L. Chacón , G. Chen

Time-dependent electron transport through a quantum dot and double quantum dot systems in the presence of polychromatic external periodic quantum dot energy-level modulations is studied within the time evolution operator method for a…

Mesoscale and Nanoscale Physics · Physics 2010-03-12 T. Kwapinski , S. Kohler , P. Hanggi

Here we study a pumping device capable of maintaining a density gradient and a flux of particles across a membrane. Its driving mechanism is based on the flashing ratchet effect powered by the random telegraph process in the presence of…

Statistical Mechanics · Physics 2015-05-13 A. Gomez-Marin , J. M. Sancho

As a step toward the full \emph{ab-initio} description of two-photon double ionization processes, we present a finite-pulse version of the virtual-sequential model for polyelectronic atoms. The model relies on the \emph{ab initio}…

Atomic Physics · Physics 2023-08-02 Siddhartha Chattopadhyay , Carlos Marante , Barry Schneider , Luca Argenti

An approximate approach to quantum vibrational dynamics, "Brownian Chain Molecular Dynamics (BCMD)", is proposed to alleviate the chain resonance and curvature problems in the imaginary time-based path integral (PI) simulation. Here the…

Chemical Physics · Physics 2024-01-26 Motoyuki Shiga

A Thouless pump transports an integer amount of charge when pumping adiabatically around a singularity. We study the splitting of such a critical point into two separate critical points by adding a Hubbard interaction. Furthermore, we…

Quantum Gases · Physics 2022-08-02 E. Bertok , F. Heidrich-Meisner , A. A. Aligia

We introduce a system-independent method to derive effective atomic C$_6$ coefficients and polarizabilities in molecules and materials purely from charge population analysis. This enables the use of dispersion-correction schemes in…

Materials Science · Physics 2016-09-05 Martin Stöhr , Georg S. Michelitsch , John C. Tully , Karsten Reuter , Reinhard J. Maurer

Motivated by our observation of fast echo decay and a surprising coherence freeze, we have developed a pump-probe spectroscopy technique for vibrational states of ultracold $^{85}$Rb atoms in an optical lattice to gain information about the…

We study the strong coupling between the molecular excited state and the plasmonic modes of silver hole arrays with a resonant frequency very close to the asymptotic line of the plasmonic dispersion relation, at the nonlinear regime. We…

Mesoscale and Nanoscale Physics · Physics 2017-01-26 Lihi Efremushkin , Maxim Sukharev , Adi Salomon
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