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Based on standard perturbation theory, we present a full quantum derivation of the formula for the orbital magnetization in periodic systems. The derivation is generally valid for insulators with or without a Chern number, for metals at…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Junren Shi , G. Vignale , Di Xiao , Qian Niu

Working in the Wannier representation, we derive an expression for the orbital magnetization of a periodic insulator. The magnetization is shown to be comprised of two contributions, an obvious one associated with the internal circulation…

Materials Science · Physics 2007-05-23 T. Thonhauser , Davide Ceresoli , David Vanderbilt , R. Resta

The theoretical treatment of homogeneous static magnetic fields in periodic systems is challenging, as the corresponding vector potential breaks the translational invariance of the Hamiltonian. Based on density operators and perturbation…

Materials Science · Physics 2015-05-30 X. Gonze , J. W. Zwanziger

We extend the recently-developed theory of bulk orbital magnetization to finite electric fields, and use it to calculate the orbital magnetoelectric response of periodic insulators. Working in the independent-particle framework, we find…

Mesoscale and Nanoscale Physics · Physics 2010-05-28 Andrei Malashevich , Ivo Souza , Sinisa Coh , David Vanderbilt

Magneto-optical response, i.e. optical response in the presence of a magnetic field, is commonly used for characterization of materials and in optical communications. However, quantum mechanical description of electric and magnetic fields…

Materials Science · Physics 2019-06-18 Irina V. Lebedeva , David A. Strubbe , Ilya V. Tokatly , Angel Rubio

We derive a multi-band formulation of the orbital magnetization in a normal periodic insulator (i.e., one in which the Chern invariant, or in 2d the Chern number, vanishes). Following the approach used recently to develop the single-band…

Materials Science · Physics 2009-11-11 Davide Ceresoli , T. Thonhauser , David Vanderbilt , R. Resta

We apply a microscopic theory of polarization and magnetization to crystalline insulators at zero temperature and consider the orbital electronic contribution of the linear response to spatially varying, time-dependent electromagnetic…

Mesoscale and Nanoscale Physics · Physics 2021-11-08 Perry T. Mahon , J. E. Sipe

In this review article, we survey the relatively new theory of orbital magnetization in solids-often referred to as the "modern theory of orbital magnetization"-and its applications. Surprisingly, while the calculation of the orbital…

Materials Science · Physics 2015-03-19 T. Thonhauser

We establish a theoretical formulation of the orbital magnetic moment in multiorbital tight-binding models, focusing on the role of the electric dipole. We demonstrate that the total magnetic moment can be decomposed into several…

Mesoscale and Nanoscale Physics · Physics 2025-11-26 Kosuke Tazuke , Takahiro Morimoto , Sota Kitamura

We derive a quantum-mechanical formula of the orbital magnetic quadrupole moment (MQM) in periodic systems by using the gauge-covariant gradient expansion. This formula is valid for insulators and metals at zero and finite temperature. We…

Materials Science · Physics 2018-07-25 Atsuo Shitade , Hikaru Watanabe , Youichi Yanase

Spin-orbit coupling introduces chirality into electronic structure. This can have profound effects on the magnetization induced by orbital motion of electrons. Here we derive a formula for the orbital magnetization of interacting electrons…

Strongly Correlated Electrons · Physics 2014-09-23 R. Nourafkan , G. Kotliar , A. -M. S. Tremblay

Phenomenological orbital-polarization (OP) terms have been repeatedly introduced in the single-particle equations of spin-density-functional theory, in order to improve the description of orbital magnetic moments in systems containing…

Materials Science · Physics 2015-05-13 J. M. Morbec , K. Capelle

In this paper we present the revised view on the optical activity of crystals based on the model of two dumped coupled oscillators. The results are compared with the results of the same problem solved before and it is presented that the…

Materials Science · Physics 2016-08-31 I. Vysin , J. Riha

We compute the orbital magnetization in real materials by evaluating a recently discovered formula for periodic systems, within density functional theory. We obtain improved values of the orbital magnetization in the ferromagnetic metals…

Materials Science · Physics 2010-02-19 Davide Ceresoli , Uwe Gerstmann , Ari P. Seitsonen , Francesco Mauri

In this paper, we propose a unified formalism, using Green's functions, to integrate out the electrons in an insulator under uniform electromagnetic fields. We derive a perturbative formula for the Green's function in the presence of…

Other Condensed Matter · Physics 2013-05-29 Kuang-Ting Chen , Patrick A. Lee

We present a simple and general method for construction of localized orbitals to describe electronic structure of extended periodic metals and insulators as well as confined systems. Spatial decay of these orbitals is found to exhibit…

Materials Science · Physics 2007-05-23 Joydeep Bhattacharjee , Umesh V Waghmare

Modern theory of the orbital magnetization is applied to the series of insulating perovskite transition metal oxides (orthorhombic YTiO$_3$, LaMnO$_3$, and YVO$_3$, as well as monoclinic YVO$_3$), carrying a net ferromagnetic (FM) moment in…

Materials Science · Physics 2014-03-04 S. A. Nikolaev , I. V. Solovyev

Within the framework of independent particle approximation, the optical activity tensor of solids is formulated as from different contributions: the magnetic dipole, electric quadrupole, and band dispersion terms. The first two terms have…

Materials Science · Physics 2026-03-12 Xiaoming Wang , Yanfa Yan

A general formula for the orbital magnetic moment of interacting electrons in solids is derived using the many-electron Green function method. The formula factorizes into two parts, a part that contains the information about the…

Materials Science · Physics 2016-04-20 F. Aryasetiawan , K. Karlsson , T. Miyake

We derive the effective heat current density operator for the strong-coupling regime of Mott insulators. Similarly to the case of the electric current density, the leading contribution to this effective operator is proportional to the local…

Strongly Correlated Electrons · Physics 2013-11-05 Shi-Zeng Lin , Cristian D. Batista
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