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Related papers: Simulation of CH$_3$OH ice UV photolysis under lab…

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We present the results of James Webb Space Telescope observations of the protostar ST6 in the Large Magellanic Cloud (LMC) with the Medium Resolution Spectrograph of the Mid-Infrared Instrument (4.9-27.9 $\mu$m). Characterized by one-third…

Methanol is a seed species of complex organic molecules that is of fundamental importance in astrochemistry. Although various isotopologues of CH$_3$OH have been detected in the interstellar medium (ISM), CH$_{3}$$^{17}$OH is only…

Astrophysics of Galaxies · Physics 2025-10-10 Yoshimasa Watanabe , Takahiro Oyama , Akemi Tamanai , Shaoshan Zeng , Nami Sakai

Methanol (CH$_{3}$OH) ice is abundant in space and is a key feedstock for seeding chemical complexity in interstellar and circumstellar environments. Despite its ubiquity, gas-phase methanol has only been detected in one disk around a…

Astrophysics of Galaxies · Physics 2025-10-07 John D. Ilee , Catherine Walsh , Jenny C. Calahan

The recent detection of gas-phase methanol (CH$_3$OH) lines in the disc of TW Hya by Walsh et al. provided the first observational constraints on the complex O-bearing organic content in protoplanetary discs. The emission has a ring-like…

Solar and Stellar Astrophysics · Physics 2017-03-14 S. Yu. Parfenov , D. A. Semenov , Th. Henning , A. S. Shapovalova , A. M. Sobolev , R. Teague

Ethanolamine (NH2CH2CH2OH) has recently been identified in the molecular cloud G+0.693-0.027, situated in the SgrB2 complex in the Galactic center. However, its presence in other regions, and in particular in star-forming sites, is still…

Deuterium fractionation is highly efficient during the early stages of star formation, particularly in starless and prestellar cores where temperatures are low (<10 K) and molecular freeze-out onto dust grains is significant. Methanol forms…

Methanol ice is embedded in interstellar ice mantles present in dense molecular clouds. We aim to measure the sputtering efficiencies starting from different ice mantles of varying compositions experimentally, in order to evaluate their…

Astrophysics of Galaxies · Physics 2020-02-19 E. Dartois , M. Chabot , A. Bacmann , P. Boduch , A. Domaracka , H. Rothard

The simultaneous detection of organic molecules of the form C$_2$H$_{\text{n}}$O, such as ketene (CH$_2$CO), acetaldehyde (CH$_3$CHO), and ethanol (CH$_3$CH$_2$OH), toward early star-forming regions offers hints of shared chemical history.…

Astrophysics of Galaxies · Physics 2021-06-16 K. -J. Chuang , G. Fedoseev , C. Scirè , G. A. Baratta , C. Jäger , Th. Henning , H. Linnartz , M. E. Palumbo

The occurrence of complex organic molecules (COMs) in the gas phase at low temperature in the dense phases of the ISM suggests that a non-thermal desorption mechanism is at work because otherwise, COMs should condense within a short…

Astrophysics of Galaxies · Physics 2019-07-17 E. Dartois , M. Chabot , T. Id Barkach , H. Rothard , B. Augé , A. N. Agnihotri , A. Domaracka , P. Boduch

We present experimental results obtained from photoionization and photodissociation processes of abundant interstellar CH$_3$-X type organic molecules like methanol (CH$_3$OH), methylamine (CH$_3$NH$_2$) and acetonitrile (CH$_3$CN) as…

Ice mantles that formed on top of dust grains are photoprocessed by the secondary ultraviolet (UV) field in cold and dense molecular clouds. UV photons induce photochemistry and desorption of ice molecules. Experimental simulations…

Solar and Stellar Astrophysics · Physics 2015-10-20 R. Martín-Doménech , J. Manzano-Santamaría , G. M. Muñoz Caro , G. A. Cruz-Díaz , Y. -J. Chen , V. J. Herrero , I. Tanarro

The development of molecular complexity during stellar and planetary formation owes much to the interaction of gas and dust. When the first astrochemical models including solid-state chemistry were developed more than forty years ago, data…

At the low temperatures found in the interior of dense clouds and circumstellar regions, along with H$_2$O and smaller amounts of species such as CO, CO$_2$, or CH$_3$OH, the infrared features of CH$_4$ have been observed on icy dust…

Instrumentation and Methods for Astrophysics · Physics 2020-04-01 H. Carrascosa , G. A. Cruz-Díaz , G. M. Muñoz Caro , E. Dartois , Y. -J. Chen

The aim of the presented work is to analyze the impact of experimentally evaluated reactions of hydrogen abstraction on surfaces of interstellar grains on the chemical evolution of methanol and its precursors on grains and in the gas phase…

Astrophysics of Galaxies · Physics 2021-03-24 V. A. Sokolova

Rate constants for the C(3P) + CH3OH reaction have been measured in a continuous supersonic flow reactor over the range 50 K to 296 K. C(3P) was created by the in-situ pulsed laser photolysis of CBr4, a multiphoton process which also…

We propose a new model for treating solid-phase photoprocesses in interstellar ice analogues. In this approach, photoionization and photoexcitation are included in more detail, and the production of electronically-excited (suprathermal)…

Ethanethiol (C$_2$H$_5$SH), a molecule detected in the interstellar medium (ISM), indicates the rich chemistry involving sulfur atoms. However, its behavior at low temperatures remains elusive, particularly the reported transition from an…

Ethanol (CH$_3$CH$_2$OH) is a relatively common molecule, often found in star forming regions. Recent studies suggest that it could be a parent molecule of several so-called interstellar complex organic molecules (iCOMs). Yet, the formation…

Context. Methane is among the main components of the ice mantles of insterstellar dust grains, where it is at the start of a rich solid-phase chemical network. Quantification of the photon-induced desorption yield of these frozen molecules…

Methanol and complex organic molecules have been found in cold starless cores, where a standard warm-up scenario would not work because of the absence of heat sources. A recent chemical model attributed the presence of methanol and large…

Astrophysics of Galaxies · Physics 2021-07-14 Miwa Goto , A. I. Vasyunin , B. M. Giuliano , I. Jiménez-Serra , P. Caselli , C. G. Román-Zúñiga , J. Alves