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The fragmentation of molecular cations following inner-shell decay processes in molecules containing heavy elements underpins the x-ray damage effects observed in x-ray scattering measurements of biological and chemical materials, as well…

Chemical Physics · Physics 2024-06-17 Adam E. A. Fouda , Stephen H. Southworth , Phay J. Ho

The capability of generating two intense, femtosecond x-ray pulses with controlled time delay opens the possibility of performing time-resolved experiments for x-ray induced phenomena. We have applied this capability to study the…

Understanding inner-shell decay processes in heavy-element molecules is essential for unraveling x-ray-induced photodynamics and advancing molecular imaging techniques. In this study, we investigate the influence of atomic substitution on…

Atomic and Molecular Clusters · Physics 2025-09-30 Nivedita Bhat , Yeonsig Nam , Linda Young , Stephen H. Southworth , Phay J. Ho

Results of the most sophisticated measurements in coincidence of the angular resolved K-shell photo- and Auger-electrons, and of two atomic ions produced by dissociation of N2 molecule, are analyzed. Detection of photoelectrons at certain…

The development of intense high-energy radiation sources and the improvement of techniques for detecting charged fragments have made possible experiments on multiple ionization of a molecule with registration of the momentum and charge of…

The predominant reason for the damaging power of high-energy radiation is multiple ionization of a molecule, either direct or via the decay of highly excited intermediates, as e.g., in the case of X-ray irradiation. Consequently, the…

The decay of inner-shell vacancy in an atom through radiative and non-radiative transitions leads to final charged ions. The de-excitation decay of 3s, 3p and 3d vacancies in Kr atoms are calculated using Monte-Carlo simulation method. The…

Atomic Physics · Physics 2008-04-24 Yehia A. Lotfy , Adel M. El-Shemi

Soft X-rays (90-173 eV) from the 3rd generation Canadian Light Source have been used in conjunction with a multi coincidence time and position sensitive detection apparatus to observe the dissociative ionization of OCS. By varying the X-ray…

Metal ions play numerous important roles in biological systems being central to the function of biomolecules. In this letter we show that the absorption of X-rays by these ions leads to a complicated chain of ultrafast relaxation steps…

Chemical Physics · Physics 2016-03-23 Vasili Stumpf , Kirill Gokhberg , Lorenz S. Cederbaum

The consequences of the Auger effect on the population of heavy element ions are analyzed for the case of relatively cool gas irradiated by keV X-rays, with intended applications to the accretion disks of young stellar ob jects. Highly…

Astrophysics of Galaxies · Physics 2015-05-28 Máté Ádámkovics , Alfred E. Glassgold , Rowin Meijerink

We theoretically study orbital alignment in x-ray-ionized atoms and ions, based on improved electronic-structure calculations starting from the Hartree-Fock-Slater model. We employ first-order many-body perturbation theory to improve the…

Atomic Physics · Physics 2023-01-03 Laura Budewig , Sang-Kil Son , Robin Santra

We devise an ab initio formalism for the quantum dynamics of Auger decay by laser-dressed atoms which are inner-shell ionized by extreme ultraviolet (XUV) light. The optical dressing laser is assumed to be sufficiently weak such that…

Atomic Physics · Physics 2009-11-06 Christian Buth , Kenneth J. Schafer

The model is constructed of the propagation of gamma-ray burst radiation through a dense molecular cloud. The main processes of the interaction of the radiation with the interstellar gas are taken into account in the simulations: the…

High Energy Astrophysical Phenomena · Physics 2024-05-20 Aleksandr Nesterenok

Time-resolved x-ray scattering (TRXS) measures internuclear separations in a molecule following laser-induced photoexcitation. The molecular dynamics induced by the excitation laser may lie on one or several bound or dissociative electronic…

Atomic Physics · Physics 2019-09-25 MR Ware , JM Glownia , N Al-Sayyad , JT O'Neal , PH Bucksbaum

X-radiation from energetic electrons is the prime diagnostic of flare-accelerated electrons. The observed X-ray flux (and polarization state) is fundamentally a convolution of the cross-section for the hard X-ray emission process(es) in…

A general scenario for electronic charge migration in finite samples illuminated by an intense laser pulse is given. Microscopic calculations for neon clusters under strong short pulses as produced by X-ray free-electron laser sources…

Atomic and Molecular Clusters · Physics 2009-04-30 Christian Gnodtke , Ulf Saalmann , Jan M. Rost

A photofragmentation study of gas-phase indole (C$_8$H$_7$N) upon single-photon ionization at a photon energy of 420 eV is presented. Indole was primarily inner-shell ionized at its nitrogen and carbon $1s$ orbitals. Electrons and ions were…

We investigate molecular dynamics of multiple ionization in N2 through multiple core-level photoabsorption and subsequent Auger decay processes induced by intense, short X-ray free electron laser pulses. The timing dynamics of the…

We present a theoretical framework to describe state-resolved ionization dynamics of neon atoms driven by ultraintense x-ray free-electron-laser pulses. In general, x-ray multiphoton ionization dynamics of atoms have been described by…

Atomic Physics · Physics 2023-01-10 Laura Budewig , Sang-Kil Son , Robin Santra

Intense X-ray photo-absorption from short and intense pulses by a molecule triggers complicated electron and subsequently ion dynamics leading to photo-electron spectra which are difficult to interpret. Illuminating fullerenes offers a way…

Atomic and Molecular Clusters · Physics 2014-08-20 Abraham Camacho Garibay , Ulf Saalmann , Jan M. Rost
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