Related papers: Thermal capacities and polytropic processes
In many textbooks of thermodynamics, the polytropic process is usually introduced by defining its process equation rather than analyzing its actual origin. We realize a polytropic process of an ideal gas system when it is thermally contact…
Transient processes generally constitute part of energy-system cycles. If skillfully manipulated, they actually are capable of assisting systems to behave beneficially to suit designers' needs. In the present study, behaviors related to…
A complete characterization of the set of states that can be achieved through Thermal Processes (TP) is given by describing all vertices, edges and facets of the allowed set of states in the language of thermomajorization curves. TPs are…
At first glance, the title of this work seems to be improper. And the reason is well known. Since blackbody pressure depends only on temperature, one cannot take the derivative of the thermodynamic quantities with respect to one of them,…
Calculating liquid energy and heat capacity in general form is an open problem in condensed matter physics. We develop a recent approach to liquids from the solid state by accounting for the contribution of anharmonicity and thermal…
The work function is embedded in the equation describing the relationship between the constant volume and constant pressure heat capacities. The modification of the work function results that the relationship between these quantities must…
We focus on the thermodynamic behavior of Polytropic gas as a candidate for dark energy. We use the general arguments of thermodynamics to investigate its properties and behavior. We find that a Polytropic gas may exhibit the dark energy…
Understanding thermodynamics in liquids at the atomic level is challenging because of strong atomic interactions and lack of symmetry. Recent prior theoretical works have focused on describing heat capacity of liquids in terms of…
Thermodynamics of power means applies to an ideal quantum gas which may be nonextensive. Transition to an ideal classical gas occurs when the empirical temperature exponents of the internal energy and absolute temperature coalesce. Limiting…
Comparison of the thermodynamic entropy with Boltzmann's principle shows that under conditions of constant volume the total number of arrangements in simple thermodynamic systems with temperature-independent heat capacities is TC/k. A…
Everything that is not prohibited is permissible. So, what is prohibited in the course of chemical reactions, heat transfer and other dissipative processes? Is it possible to "overshoot" the equilibrium, and if yes, then how far?…
Thermodynamics imposes restrictions on what state transformations are possible. In the macroscopic limit of asymptotically many independent copies of a state---as for instance in the case of an ideal gas---the possible transformations…
Thermodynamic transport phenomena in the system consisting of many hard-disks confined in a circular tube with a temperature difference are discussed. Here, temperatures on parts of the walls of the tube are imposed by stochastic boundary…
Thermal conductivity coefficient $\kappa$ measures the ability of a material to conduct a heat current. In particular, $\kappa$ is an important property that often dictates the usefulness of a material over a wide range of environmental…
We show how to extend the concept of heat capacity to nonequilibrium systems. The main idea is to consider the excess heat released by an already dissipative system when slowly changing the environment temperature. We take the framework of…
We propose a new simple way to evaluate the effect of anharmonicity on a system's thermodynamic functions such as heat capacity. In this approach, the contribution of all potentially complicated anharmonic effects to constant-volume heat…
We provide the theoretical basis of calorimetry for a class of active particles subject to thermal noise. Simulating AC-calorimetry, we numerically evaluate the heat capacity of run-and-tumble particles in double-well and in periodic…
Entropy might be a not well defined concept if the system can undergo transformations involving stationary nonequilibria. It might be analogous to the heat content (once called ``caloric'') in transformations that are not isochoric (i.e.…
Heat capacity of matter is considered to be its most important property because it holds information about system's degrees of freedom as well as the regime in which the system operates, classical or quantum. Heat capacity is well…
The thermodynamics framework of an interacting quantum gas trapped by an arbitrary external potential is reviewed. We show that for each confining potential, in the thermodynamic limit, there emerge "generalized" volume and pressure…