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The development of tandem photovoltaics and photoelectrochemical solar cells requires new absorber materials with band gaps in the range of ~1.5-2.3 eV, for use in the top cell paired with a narrower-gap bottom cell. An outstanding…

Zinc nitride films were synthesized by reactive radio frequency (rf) magnetron sputtering of a zinc target using an Ar+N2 mixture. The as-deposited films were annealed in the air and O2 at 300 {\deg}C for 1 hr. The XRD measurements…

Materials Science · Physics 2023-01-18 Ting Wen , Ahalapitiya H Jayatissa

Silicon telluride (Si2Te3) is a two-dimensional material with a unique variable structure where the silicon atoms form Si-Si dimers to fill the "metal" sites between the Te layers. The Si-Si dimers have four possible orientations: three…

Materials Science · Physics 2020-01-29 Romakanta Bhattarai , Xiao Shen

Monolayer C$_3$N is an emerging two-dimensional indirect band gap semiconductor with interesting mechanical, thermal, and electronic properties. In this work we present a description of C$_3$N electronic and dielectric properties, focusing…

Mesoscale and Nanoscale Physics · Physics 2022-04-26 Miki Bonacci , Matteo Zanfrognini , Elisa Molinari , Alice Ruini , Marilia J. Caldas , Andrea Ferretti , Daniele Varsano

Two-dimensional (2D) semiconductors provide a unique opportunity for optoelectronics due to their layered atomic structure, electronic and optical properties. To date, a majority of the application-oriented research in this field has been…

Optics · Physics 2017-10-26 Deep Jariwala , Artur R. Davoyan , Joeson Wong , Harry A. Atwater

All-optical signal processing based on nonlinear optical devices is promising for ultrafast information processing in optical communication systems. Recent advances in two-dimensional (2D) layered materials with unique structures and…

Optics · Physics 2024-03-07 David J. Moss

With the rise of AI-assisted materials screening, extraordinary properties are now frequently predicted in experimentally uncharted material systems, highlighting the need to develop new synthesis methods for unconventional materials beyond…

As the characteristic dimensions of modern top-down devices are getting smaller, such devices reach their operational limits given by quantum mechanics. Thus, two-dimensional (2D) structures appear as one of the best solutions to meet the…

Ternary nitride ZnSnN$_2$ is a promising photovoltaic absorber material. In this work, using first-principles calculations, we investigate the stability and electronic properties of "4-8"-type ZnSnN$_2$ thin films. We find that below a…

Materials Science · Physics 2024-01-30 D. Q. Fang

Two-dimensional materials with a proper band gap and high carrier mobility are urgently desired in the field of nanoelectronics. We propose a novel two-dimensional crystal monolayer $\mathrm{TlP_5}$, which is dynamically and…

ZnSnN2 is an Earth-abundant analog to the III-Nitrides with potential as a solar absorber due to its direct bandgap, steep absorption onset, and disorder-driven bandgap tunability. Despite these desirable properties, discrepancies in the…

Two-dimensional (2D) allotrope of tin with low buckled honeycomb structure, named as stanene, is proposed to be an ideal 2D topological insulator with a nontrivial gap larger than 0.1 eV. Theoretical works also pointed out the topological…

Materials Science · Physics 2017-11-01 Jian Gou , Longjuan Kong , Hui Li , Qing Zhong , Wenbin Li , Peng Cheng , Lan Chen , Kehui Wu

The application of ultrathin two-dimensional (2D) perovskites in near-infrared and visible-range optoelectronics has been limited owing to their inherent wide bandgaps, large excitonic binding energies and low optical absorption at higher…

Mesoscale and Nanoscale Physics · Physics 2022-05-06 Abin Varghese , Yuefeng Yin , Mingchao Wang , Saurabh Lodha , Nikhil V. Medhekar

In this work we use first-principles density-functional theory (DFT) calculations combined with the maximally localized Wannier function tight binding Hamiltonian (MLWF-TB) and Bethe-Salpeter equation (BSE) formalism to investigate…

We study the 2D Raman band of in-plane uniaxially strained graphene within a non-orthogonal tight-binding model. At non-zero strain, the obtained 2D band splits into two subbands at strain angles $0^{\circ}$ and $30^{\circ}$ or into three…

Mesoscale and Nanoscale Physics · Physics 2013-06-11 Valentin N. Popov , Philippe Lambin

The bulk phase of transition metal nitrides (TMNs) has long been a subject of extensive investigation due to their utility as coating materials, electrocatalysts, and diffusion barriers, attributed to their high conductivity and refractory…

Two-dimensional (2D) intrinsic superconductors with nontrivial topological band and vertical ferroelectricity exhibit fascinating characteristics to achieving electrostatic control of quantum phases. While, only a few such 2D materials have…

Superconductivity · Physics 2024-05-01 Xin-Zhu Yin , Na Jiao , Jinlian Lu , Meng-Meng Zheng , Hong-Yan Lu , Ping Zhang

The recent experimental synthesis of 2D graphitic C3N5 has attracted lot of interests in its electronic and optical properties and its comparison with other graphitic C3N4 and C3N3. To this end, we performed DFT calculations using more…

Materials Science · Physics 2022-07-19 Shakti Singh , P. Anees , Sharat Chandra , Tapan Ghanty

In recent years, two-dimensional (2D) layered semiconductors have received much attention for their potential in next-generation electronics and optoelectronics. Wide-bandgap 2D semiconductors are especially important in blue and…

Materials Science · Physics 2022-02-16 Huiyu Nong , Qinke Wu , Junyang Tan , Yujie Sun , Rongxu Zheng , Rongjie Zhang , Shilong Zhao , Bilu Liu

Searching the novel 2D semiconductor is crucial to develop the next-generation low-dimensional electronic device. Using first-principles calculations, we propose a class of unexplored binary V-V compound semiconductor (PN, AsN, SbN, AsP,…

Computational Physics · Physics 2016-06-13 Weiyang Yu , Zhili Zhu , Chun-Yao Niu , Xiaolin Cai , Wei-Bing Zhang