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We show the possibility of tailoring the molecular arrangement, as well as the chemical and structural modifications, of porphyrins at the monolayer saturation coverage on TiO2(110) by Synchrotron photoemission, electron diffraction, STM…

Amorphous hydrogenated silicon (a-Si:H) is an important material for surface defect passivation of photovoltaic silicon (Si) wafers in order to reduce their recombination losses. The material is however unstable with regards to hydrogen (H)…

The electrochemical hydrogenation of graphene induces a robust and reversible conductor-insulator transition, of strong interest in logic-and-memory applications. However, its mechanism remains unknown. Here we show that it proceeds as a…

Magnesium hydride has great potential as a solid hydrogen (H) storage material because of its high H storage capacity of 7.6 wt%. However, its slow hydrogenation and dehydrogenation kinetics and the high temperature of 300 $^\circ$C…

Materials Science · Physics 2023-04-25 R. Kadono , M. Hiraishi , H. Okabe , A. Koda , T. U. Ito

We report laboratory measurements of the absorption coefficient of solid para-H2, within the wavelength range from 1 to 16.7 micron, at high spectral resolution. In addition to the narrow rovibrational lines of H2 which are familiar from…

Astrophysics of Galaxies · Physics 2022-05-03 Cassie Kettwich , David Anderson , Mark Walker , Artem Tuntsov

Graphene functionalization by hydrogen and fluorine has been proposed as a route to modulate its reactivity and electronic properties. However, until now, proposed systems present degradation and limited hydrogen adsorption capacity. In…

Since the current transportation sector is the largest consumer of oil, and subsequently responsible for major air pollutants, it is inevitable to use alternative renewable sources of energies for vehicular applications. The hydrogen energy…

Atomic and Molecular Clusters · Physics 2016-07-26 Ravindra Shinde , Meenakshi Tayade

Liquid-liquid phase transition of hydrogen is at the center of hydrogen phase diagram as a promising route towards emergent properties such as the Wigner-Huntington metallization, superconductivity, and superfluidity. Here we report a study…

Materials Science · Physics 2022-06-27 Jianqing Guo , Bingqing Cheng , Limei Xu , Enge Wang , Ji Chen

By applying density functional theory (DFT) and ab-initio molecular dynamics (AIMD) simulations, we predict the ultrahigh hydrogen storage capacity of K and Ca decorated single-layer biphenylene sheet (BPS). We have kept various alkali and…

Materials Science · Physics 2022-02-25 Vikram Mahamiya , Alok Shukla , Brahmananda Chakraborty

Two-dimensional porous carbon nanomaterials are proven to be promising hydrogen storage substrates as they possess high surface area, large number of active sites, low molecular mass, and hydrogen molecules can be adsorbed on both sides of…

Materials Science · Physics 2023-12-05 Vikram Mahamiya , Alok Shukla , Brahmananda Chakraborty

We report the detection of Deuterium absorption at redshift 2.525659 towards Q1243+3047. We describe improved methods to estimate the Deuterium to Hydrogen abundance ratio (D/H) in absorption systems, including improved modeling of the…

Astrophysics · Physics 2009-11-07 David Kirkman , David Tytler , Nao Suzuki , John M. O'Meara , Dan Lubin

Metal-ion batteries are in huge demand to cope with the increasing need for renewable energy, especially in automobiles. In this work, we apply first-principle calculations to examine two-dimensional beryllium carbide (2D-Be2C) as a…

Materials Science · Physics 2025-11-03 Hetvi Jadav , Sadhana Matth , Himanshu Pandey

The interplay between electron correlation and nuclear quantum effects makes our understanding of elemental hydrogen a formidable challenge. Here, we present the phase diagram of hydrogen and deuterium at low temperatures and high-pressure…

Materials Science · Physics 2023-06-28 Lorenzo Monacelli , Michele Casula , Kosuke Nakano , Sandro Sorella , Francesco Mauri

Developing efficient hydrogen storage and conversion technologies is essential for sustainable energy. This study investigates the catalytic potential of a dicalcium nitride (Ca2N) monolayer for hydrogen dissociation using density…

Mesoscale and Nanoscale Physics · Physics 2025-01-28 Gwan Woo Kim , Soonmin Jang , Gunn Kim

Establishing the phase diagram of hydrogen is a major challenge for experimental and theoretical physics. Experiment alone cannot establish the atomic structure of solid hydrogen at high pressure, because hydrogen scatters X-rays only…

We present a design and performance tests of an intense source of cold hydrogen atoms for loading large magnetic traps. Our source is based on a cryogenic dissociator of molecular hydrogen at 0.6 K followed by a series of thermal…

The process of hydrogen desorption from graphane (graphene sheet saturated by hydrogen adsorbed from both sides) has been studied using the method of molecular dynamics. The temperature dependences of the time of desorption onset for…

Mesoscale and Nanoscale Physics · Physics 2010-01-08 L. A. Openov , A. I. Podlivaev

Diffraction of atoms from surfaces provides detailed insights into structures, interactions, and dynamical processes. However, currently the method is limited to measurements in reflection - diffraction through materials has only been…

We report on the first ESR study of atomic hydrogen and tritium stabilized in a solid T$_{2}$ and T$_{2}$:H$_{2}$ matrices down to 70$\,$mK. The concentrations of T atoms in pure T$_{2}$ approached $2\times10^{20}$cm$^{-3}$ and record-high…

Other Condensed Matter · Physics 2017-04-05 S. Sheludiakov , J. Ahokas , J. Järvinen , O. Vainio , L. Lehtonen , D. Zvezdov , S. Vasiliev , D. M. Lee , V. V. Khmelenko

We investigate the electron transfer from a dissociatively adsorbed H2 molecule to a Au(111) surface using the first-principles methods. A fractional electron transfers from a molecule to a substrate, and potential energy increases during…

Materials Science · Physics 2009-11-13 Shigeyuki Takagi , Jun-ichi Hoshino , Hidekazu Tomono , Kazuo Tsumuraya