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The adsorption energies and orientation of methanol on graphene are determined from first-principles density functional calculations. We employ the well-tested vdW-DF method that seamlessly includes dispersion interactions with all of the…

Materials Science · Physics 2013-03-18 Elsebeth Schroder

The dissolution and microfluidic mass transfer of carbon dioxide in water at high-pressure conditions are crucial for a myriad of technological applications, including microreactors, extractions, and carbon capture, utilization, and…

Fluid Dynamics · Physics 2021-07-20 Tsai-Hsing Martin Ho , Dan Sameoto , Peichun Amy Tsai

Large-scale energy storage has become an inevitable solution for integrating stochastically available renewable energy sources into the electric grid. Vanadium redox flow batteries offer a viable option among other technologies, due to…

Applied Physics · Physics 2026-02-16 B. Sziffer , V. Jozsa

The isothermal compressibility of water is essential to understand its anomalous properties. We compute it by ab initio molecular dynamics simulations of 200 molecules at five densities, using two different van der Waals density…

The formation of molecules in and on amorphous solid water (ASW) as it occurs in interstellar space releases appreciable amounts of energy that need to be dissipated to the environment. Here, energy transfer between CO$_2$ formed within and…

Chemical Physics · Physics 2021-12-02 Meenu Upadhyay , Markus Meuwly

Integrating external heat into electrolysers can reduce the electrical power demand for carbon-neutral hydrogen production. Efficient operation requires detailed models that incorporate heat availability and its effect on startup costs.…

Chemical Physics · Physics 2025-07-11 Matthias Derez , Alexander Hoogsteyn , Erik Delarue

The distribution of entangled states of light over long distances is a major challenge in the field of quantum information. Optical losses, phase diffusion and mixing with thermal states lead to decoherence and destroy the non-classical…

Achieving versatile routes to generate crystalline carbon-based nanostructures has become a fervent pursuit in photocatalysis-related fields. We demonstrate that the direct electrooxidation of ethanol, performed on Ni foam, yields…

In Part I of this paper series, a theoretical and numerical model for a a driven pendulum filled with liquid was developed. The system was analyzed in the framework of tuned liquid dampers (TLD) and hybrid mass liquid dampers (HMLD) theory.…

Water desalination by capacitive deionization (CDI) is performed via electrochemical cells consisting of two porous carbon electrodes. Upon transferring charge from one electrode to the other, ions are removed from the feedwater by…

Materials Science · Physics 2015-06-15 P. M. Biesheuvel , M. E. Suss , H. V. M. Hamelers

The separation of liquid mixture has been studied for a long time. Separation proceeds based on the difference in physical properties including pore size and electrostatic interaction. Therefore, there are many difficulties in separation of…

Materials Science · Physics 2021-01-26 Kyoung Hwan Choi , Da Young Hwang , Jeong Eon Park , Dong Hack Suh

In this paper, the self-assembly of condensed droplets on smooth and constrained surfaces under saturated vapor atmosphere of ethanol and methanol binary system is reported. Hexagonally ordered array of pores are obtained on smooth surfaces…

Soft Condensed Matter · Physics 2018-07-06 K Nilavarasi , V Madhurima

We study the energetics of acetylene (${\rm C_2H_2}$) molecules inside a carbon nanotube (CNT) using the {\it ab initio} pseudopotential method. The encapsulation energy of a single ${\rm C_2H_2}$ molecule into the nanotube and the…

Other Condensed Matter · Physics 2016-08-31 Gunn Kim , Yeonju Kim , Jisoon Ihm

The current state of the art in direct water splitting in photo-electrochemical cells (PECs) is presented together with: (i) a case study of water splitting using a simple solar cell with the most efficient water splitting electrodes and…

The electric double layer is an important structure that appears at charged liquid interfaces, and it determines the performance of various electrochemical devices such as supercapacitors and electrokinetic energy converters. Here the…

Soft Condensed Matter · Physics 2023-08-15 Haruto Iwasaki , Yasuyuki Kimura , Yuki Uematsu

Deuterium fractionation is highly efficient during the early stages of star formation, particularly in starless and prestellar cores where temperatures are low (<10 K) and molecular freeze-out onto dust grains is significant. Methanol forms…

Separation of hydrocarbon isomers with closely matched physicochemical properties remains an energetically demanding challenge in the petrochemical refineries. This study presents a comparative analysis of three methods: the fractional…

Chemical Physics · Physics 2025-09-03 Shubhadeep Nag , Yashonath Subramanian

We compute the electrical conductivity for liquid hydrogen at high pressure using quantum Monte Carlo. The method uses Coupled Electron-Ion Monte Carlo to generate configurations of liquid hydrogen. For each configuration correlated…

Strongly Correlated Electrons · Physics 2010-01-22 Fei Lin , Miguel A. Morales , Kris T. Delaney , Carlo Pierleoni , Richard M. Martin , D. M. Ceperley

A mathematical model is developed to describe column adsorption when the contaminant constitutes a significant amount of the fluid. This requires modelling the variation of pressure and velocity, in addition to the usual…

Fluid Dynamics · Physics 2025-02-10 Timothy G. Myers , Marc Calvo-Schwarzwalder , Francesc Font , Abel Valverde

We report the performance of a hydrogen-chlorine electrochemical cell with a chlorine electrode employing a low precious metal content alloy oxide electrocatalyst for the chlorine electrode: (Ru_0.09Co_0.91)_3O_4. The cell employs a…

Materials Science · Physics 2012-06-14 Brian Huskinson , Jason Rugolo , Sujit K. Mondal , Michael J. Aziz