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In this paper we establish a connection between density functional theory (DFT) for lattice models and common real-space DFT. We consider the lattice DFT description of a two-level model subject to generic interactions in Mermin's DFT…

Strongly Correlated Electrons · Physics 2023-10-23 Nahual Sobrino , David Jacob , Stefan Kurth

Density functional theory (DFT) has become the most popular approach to electronic structure across disciplines, especially in material and chemical sciences. Last year, at least 30,000 papers used DFT to make useful predictions or give…

Chemical Physics · Physics 2017-01-05 Justin C. Smith , Francisca Sagredo , Kieron Burke

We introduce a method that allows the evaluation of general expressions for the spectral functions of the one-dimensional Hubbard model for all values of the on-site electronic repulsion U. The spectral weights are expressed in terms of…

Strongly Correlated Electrons · Physics 2007-05-23 J. M. P. Carmelo , K. Penc

Forty-five years after the point de d\'epart [1] of density functional theory, its applications in chemistry and the study of electronic structures keep steadily growing. However, the precise form of the energy functional in terms of the…

Chemical Physics · Physics 2019-10-29 Philippe Blanchard , José M. Gracia-Bondía , Joseph C. Várilly

We formulate a time-dependent density-matrix functional theory (TDDMFT) approach for higher-order correlation effects like biexcitons in optical processes in solids based on the reduced two-particle density-matrix formalism within the…

Materials Science · Physics 2015-05-19 Volodymyr Turkowski , Carsten A. Ullrich , Talat S. Rahman , Michael N. Leuenberger

The thermodynamics of the inhomogeneous one-dimensional repulsive fermionic Hubbard model with parabolic confinement is studied by a density-functional theory approach, based on Mermin's generalization to finite temperatures. A…

Strongly Correlated Electrons · Physics 2019-04-25 V. L. Campo

The principles of density-functional theory are studied for finite lattice systems represented by graphs. Surprisingly, the fundamental Hohenberg-Kohn theorem is found void in general, while many insights into the topological structure of…

Quantum Physics · Physics 2022-01-13 Markus Penz , Robert van Leeuwen

Classical density functional theory (DFT) provides an exact variational framework for determining the equilibrium properties of inhomogeneous fluids. We report a generalization of DFT to treat the non-equilibrium dynamics of classical…

Soft Condensed Matter · Physics 2013-09-06 Matthias Schmidt , Joseph M. Brader

Solving the fundamental and optical gap problems, which yield information about charged and neutral excitations in electronic systems, is one of the biggest challenge in density-functional theory (DFT). Despite their intrinsic difference,…

Chemical Physics · Physics 2018-08-29 Bruno Senjean , Emmanuel Fromager

We develop a systematic approach to construct energy functionals of the one-particle reduced density matrix (1RDM) for equilibrium systems at finite temperature. The starting point of our formulation is the grand potential $\Omega…

Other Condensed Matter · Physics 2018-11-20 Klaas J. H. Giesbertz , Anna-Maija Uimonen , Robert van Leeuwen

We introduce a framework for two-dimensional conformal field theory (CFT) in the language of analytic number theory. Attached to the torus partition function of every two-dimensional CFT is a self-dual, degree-4 $L$-function of root number…

High Energy Physics - Theory · Physics 2025-09-29 Eric Perlmutter

Functional data that are nonnegative and have a constrained integral can be considered as samples of one-dimensional density functions. Such data are ubiquitous. Due to the inherent constraints, densities do not live in a vector space and,…

Statistics Theory · Mathematics 2016-01-13 Alexander Petersen , Hans-Georg Müller

One route to numerically propagating quantum systems is time dependent density functional theory (TDDFT). The application of TDDFT to a particular system's time evolution is predicated on V-representability which we have analyzed in a…

Chemical Physics · Physics 2015-03-03 J. D. Whitfield

Given a vector space of microscopic quantum observables, density functional theory is formulated on its dual space. A generalized Hohenberg-Kohn theorem and the existence of the universal energy functional in the dual space are proven. In…

Nuclear Theory · Physics 2009-09-25 G. Rosensteel , Ts. Dankova

Random matrix theory (RMT) universality is the defining property of quantum mechanical chaotic systems, and can be probed by observables like the spectral form factor (SFF). In this paper, we describe systematic deviations from RMT…

Statistical Mechanics · Physics 2025-01-15 Rahel L. Baumgartner , Luca V. Delacrétaz , Pranjal Nayak , Julian Sonner

A density functional theory (DFT) framework is presented that links functional derivatives of free-energy functionals to non-linear static density response functions in quantum many-body systems. Within this framework, explicit expressions…

Density functional theory (DFT) provides a theoretical framework for efficient and fairly accurate calculations of the electronic structure of molecules and crystals. The main features of density functional theory are described and DFT…

Chemical Physics · Physics 2012-06-12 Hauke Paulsen , Alfred Xaver Trautwein

We develop a Hilbert space framework for a number of general multi-scale problems from dynamics. The aim is to identify a spectral theory for a class of systems based on iterations of a non-invertible endomorphism. We are motivated by the…

Dynamical Systems · Mathematics 2007-05-23 Dorin Ervin Dutkay , Palle E. T. Jorgensen

Using the existence of infinite numbers $k$ in the non-Archimedean ring of Robinson-Colombeau, we define the hyperfinite Fourier transform (HFT) by considering integration extended to $[-k,k]^{n}$ instead of $(-\infty,\infty)^{n}$. In order…

Functional Analysis · Mathematics 2022-10-03 Akbarali Mukhammadiev , Diksha Tiwari , Paolo Giordano

Functionals (i.e. functions of functions) are widely used in quantum field theory and solid-state physics. In this paper, functionals are given a rigorous mathematical framework and their main properties are described. The choice of the…

Mathematical Physics · Physics 2018-03-14 Christian Brouder , Nguyen Viet Dang , Camille Laurent-Gengoux , Kasia Rejzner
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