Related papers: An Ice Age JWST inventory of dense molecular cloud…
Ice mantles play a crucial role in shaping the astrochemical inventory of molecules during star and planet formation. Small-scale molecular processes have a profound impact on large-scale astronomical evolution. The areas of solid-state…
An important tracer of the origin and evolution of cometary ices is the comparison with ices found in dense clouds and towards Young Stellar Objects (YSOs). We present a survey of ices in the 2-5 micron spectra of 23 massive YSOs, taken…
Context. Interstellar ice is the main form of metal species in dark molecular clouds. Experiments and observations have shown that the ice is significantly processed after the freeze-out of molecules onto grains. The processing is caused by…
Complex organic molecules (COMs) detected in the gas phase are thought to be mostly formed on icy grains, but no unambiguous detection of icy COMs larger than CH3OH has been reported so far. Exploring this matter in more detail has become…
Major components of ices on interstellar grains in molecular clouds - water and carbon oxides - occur at various optical depths. This implies that selective desorption mechanisms are at work. An astrochemical model of a contracting low-mass…
Ices imprint strong absorption features in the near- and mid-infrared, but until recently they have been studied almost exclusively with spectroscopy toward small samples of bright sources. We show that JWST photometry alone can reveal and…
Context. The gas and ice-grain chemistry of the pre-stellar core L1544 has been the subject of several observations and modelling studies conducted in the past years. The chemical composition of the ice mantles reflects the environmental…
The properties of the ices that form in dense molecular clouds represent an important set of initial conditions in the evolution of interstellar and preplanetary matter in regions of active star formation. Of the various spectral features…
Context. The formation and destruction of molecules in the interstellar medium is a complex interplay between gas-phase reactions as well as processes on grain surfaces and within icy mantles. For many decades, the gas-phase composition of…
(Abridged) Aims & Methods. A two-dimensional, semi-analytical model is presented that follows, for the first time, the chemical evolution from a collapsing molecular cloud (a pre-stellar core) to a protostar and circumstellar disk. The…
The physical evolution of Young Stellar Objects (YSOs) is accompanied by an enrichment of the molecular complexity, mainly triggered by the heating and energetic processing of the astrophysical ices. In this paper, a study of how the ice…
Using NIRSpec on JWST, we studied a sample of 15 intermediate-mass (1.8-4.1 Msun) young stellar objects (YSOs) previously identified with MIRI photometry in the low-metallicity NGC 346 star-forming cluster in the Small Magellanic Cloud…
Ices regulate much of the chemistry during star formation and account for up to 80% of the available oxygen and carbon. In this paper, we use the Spitzer c2d ice survey, complimented with data sets on ices in cloud cores and high-mass…
Ices are an important constituent of protoplanetary disks. New observational facilities, notably the James Webb Space Telescope (JWST), will greatly enhance our view of disk ices by measuring their infrared spectral features. We present a…
Although still poorly understood, the chemistry that occurs on the surfaces of interstellar dust particles profoundly affects the growth of molecules in the interstellar medium. An important set of surface reactions produces icy mantles of…
Ice is a major component of astrophysical environment - from interstellar molecular clouds through protoplanetary disks to evolved solar systems. Ice and complex organic matter coexist in these environments as well, and it is thought…
Ice chemistry in the dense, cold interstellar medium (ISM) is probably responsible for the formation of interstellar complex organic molecules (COMs). Recent laboratory experiments performed at T=4 K have shown that irradiation of CO:N2 ice…
Observations of star forming environments revealed that the abundances of some deuterated interstellar molecules are markedly larger than the cosmic D/H ratio of 10-5. Possible reasons for this pointed to grain surface chemistry. How- ever,…
This work focuses on the ice features toward the binary protostellar system Ced 110 IRS 4A and 4B, and observed with JWST as part of the Early Release Science Ice Age collaboration. We aim to explore the JWST observations of the binary…
Carbon dioxide is one of the three most abundant species within the ice mantles around dust grains inside molecular clouds. Since a substantial amount of interstellar grains is made of siliceous materials, we have studied the infrared…