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We consider and compare four Hamiltonian formulations of thermostated mechanics, three of them kinetic, and the other one configurational. Though all four approaches ``work'' at equilibrium, their application to many-body nonequilibrium…

Chaotic Dynamics · Physics 2009-11-13 Wm G Hoover , Carol G Hoover

We introduce an algorithm for sampling many-body quantum states in Fock space. The algorithm efficiently samples states with probability approximately proportional to an arbitrary function of the second-quantized Hamiltonian matrix element…

Strongly Correlated Electrons · Physics 2016-04-28 Adam Holmes , Hitesh J. Changlani , C. J. Umrigar

Addressing both dynamic and static correlation accurately is a primary goal in electronic structure theory. Non-orthogonal configuration interaction (NOCI) is a versatile tool for treating static correlation, offering chemical insights by…

Chemical Physics · Physics 2025-06-27 Chong Sun , Fei Gao , Gustavo E. Scuseria

A new technique for constructing the relativistic wave equation for the two-body system composed of the spin-1/2 and spin-0 particles is proposed. The method is based on the extension of the SL(2,C) group to the Sp(4,C) one. The obtained…

High Energy Physics - Theory · Physics 2008-11-26 D. A. Kulikov , R. S. Tutik

In the present letter, it is demonstrated how full configuration interaction (FCI) results in extended basis sets may be obtained to within sub-kJ/mol accuracy by decomposing the energy in terms of many-body expansions in the virtual…

Chemical Physics · Physics 2017-09-15 Janus J. Eriksen , Filippo Lipparini , Jürgen Gauss

By properly generalizing Nozie`res' Fermi liquid theory, we construct an Hamiltonian approach to the scattering of conduction electrons off a spin-1/2 impurity in the ovescreneed Kondo regime, as T -> 0. We derive the S-matrix at the…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Domenico Giuliano , Arturo Tagliacozzo

Heat conduction phenomena are studied theoretically using computer simulation. The systems are crystal with nonlinear interaction, and fluid of hard-core particles. Quasi-one-dimensional system of the size of $L_x\times L_y\times L_z(L_z\gg…

Statistical Mechanics · Physics 2009-10-31 Takashi Shimada , Teruyoshi Murakami , Satoshi Yukawa , Keiji Saito , Nobuyasu Ito

The configuration interaction (CI) is a versatile wavefunction theory for interacting fermions but it involves an extremely long CI series. Using a symmetric tensor decomposition (STD) method, we convert the CI series into a compact and…

Chemical Physics · Physics 2013-05-30 Wataru Uemura , Osamu Sugino

We propose a novel partitioning of the Hilbert space, hierarchy configuration interaction (hCI), where the excitation degree (with respect to a given reference determinant) and the seniority number (i.e., the number of unpaired electrons)…

Chemical Physics · Physics 2022-05-12 Fábris Kossoski , Yann Damour , Pierre-François Loos

An approximate quantum-mechanical two-body equation for spinless particles incorporating relativistic kinematics is derived. The derivation is based on the relativistic energy-momentum relation $mc^{2}+\epsilon =…

Quantum Physics · Physics 2015-08-11 K. -E. Thylwe , S. Belov

The conventional Langevin equation offers a mathematically convenient framework for investigating open stochastic systems interacting with their environment or a bath. However, it is not suitable for a wide variety of systems whose dynamics…

Statistical Mechanics · Physics 2024-09-06 Jong-Min Park , Hyunggyu Park , Jae Sung Lee

The mapping between the fermion and spinon compositions of eigenstates in the one-dimensional spin-1/2 XX model on a lattice with N sites is used to describe the spinon interaction from two different perspectives: (i) For finite N the…

Strongly Correlated Electrons · Physics 2009-11-13 Michael Karbach , Gerhard Muller , Klaus Wiele

The ground state energy and pairing gap of the interacting Fermi gases calculated by the {\it ab initio} stochastic method are compared with those estimated from the Bardeen-Cooper-Schrieffer pairing Hamiltonian. We discuss the ingredients…

Atomic Physics · Physics 2016-09-08 S. Y. Chang , V. R. Pandharipande

Based on self-consistent field (SCF) atomic mean-field (amf) quantities, we present two simple, yet computationally efficient and numerically accurate matrix-algebraic approaches to correct both scalar-relativistic \textit{and} spin-orbit…

Chemical Physics · Physics 2023-02-03 Stefan Knecht , Michal Repisky , Hans Jørgen Aagaard Jensen , Trond Saue

In this paper, we continue our investigation of a one-dimensional, two-component, quantum many-body system in which like particles interact with a pair potential $s(s+1)/{\rm sinh}^{2}(r)$, while unlike particles interact with a pair…

Condensed Matter · Physics 2016-08-14 Rudolf A. Römer , Bill Sutherland

We consider the AdS/dS CFT correspondence and study the nature of the thermal bath of the de Sitter field theory using holography. Unlike the temperature of a thermal field theory in flat spacetime, the temperature of a superconformal field…

High Energy Physics - Theory · Physics 2017-08-09 Chong-Sun Chu , Dimitrios Giataganas

We investigate spin and heat currents in the non-equilibrium steady state of inhomogeneous $XX$-spin chains, which act as interfaces between two bosonic heat baths. Using special functions that diagonalize the single-particle Hamiltonian,…

Quantum Physics · Physics 2024-08-13 Pierre-Antoine Bernard , Ismaël Bussière , Roberto Floreanini , Luc Vinet

Doubly occupied configuration interaction (DOCI), the exact diagonalization of the Hamiltonian in the paired (seniority zero) sector of the Hilbert space, is a combinatorial cost wave function that can be very efficiently approximated by…

Chemical Physics · Physics 2020-05-14 Jacob M. Wahlen-Strothman , Thomas M. Henderson , Gustavo E. Scuseria

The ground state of the $S=1/2$ kagome Heisenberg antiferromagnet is now recognized as a spin liquid, but its precise nature remains unsettled, even if more and more clues point towards a gapless spin liquid. We use high temperature series…

Strongly Correlated Electrons · Physics 2020-04-22 Bernard Bernu , Laurent Pierre , Karim Essafi , Laura Messio

The interaction of two excited hydrogen atoms in metastable states constitutes a theoretically interesting problem because of the quasi-degenerate 2P_{1/2} levels which are removed from the 2S states only by the Lamb shift. The total…

Atomic Physics · Physics 2017-02-15 U. D. Jentschura , V. Debierre , C. M. Adhikari , A. Matveev , N. Kolachevsky