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It is shown that four-component (4C), quasi-four-component (Q4C), and exact two-component (X2C) relativistic Hartree-Fock (HF) equations can be implemented in an unified manner, by making use of the atomic nature of the small components of…

Chemical Physics · Physics 2023-11-28 Wenjian Liu

In this paper the old problem of determining the discrete spectrum of a multi-particle Hamiltonian is reconsidered. The aim is to bring a fermionic Hamiltonian for large numbers N of particles by analytical means into a shape such that…

Mathematical Physics · Physics 2013-06-13 Joachim Schröter

We present an efficient method for estimating the eigenvalues of a Hamiltonian $H$ from the expectation values of the evolution operator for various times. For a given quantum state $\rho$, our method outputs a list of eigenvalue estimates…

Quantum Physics · Physics 2020-09-08 Rolando D. Somma

We apply the quantum Hamilton-Jacobi formalism, naturally defined in the complex domain, to a number of complex Hamiltonians, characterized by discrete parity and time reversal (PT) symmetries and obtain their eigenvalues and…

Quantum Physics · Physics 2009-11-10 S. Sree Ranjani , A. K. Kapoor , Prasanta K. Panigrahi

We present a systematic hierarchy of approximations for {\it local} exact-decoupling of four-component quantum chemical Hamiltonians based on the Dirac equation. Our ansatz reaches beyond the trivial local approximation that is based on a…

Chemical Physics · Physics 2012-06-28 Daoling Peng , Markus Reiher

In this work we construct Gaussian beam approximations to solutions of the high frequency Helmholtz equation with a localized source. Under the assumption of non-trapping rays we show error estimates between the exact outgoing solution and…

Numerical Analysis · Mathematics 2013-04-05 Hailiang Liu , James Ralston , Olof Runborg , Nicolay M. Tanushev

The spectrum of a local random Hamiltonian can be represented generically by the so-called $\epsilon$-free convolution of its local terms' probability distributions. We establish an isomorphism between the set of $\epsilon$-noncrossing…

Mathematical Physics · Physics 2023-10-25 Benoit Collins , Zhi Yin , Liang Zhao , Ping Zhong

We study a parameterized version of the local Hamiltonian problem, called the weighted local Hamiltonian problem, where the relevant quantum states are superpositions of computational basis states of Hamming weight $k$. The Hamming weight…

Computational Complexity · Computer Science 2022-11-11 Michael J. Bremner , Zhengfeng Ji , Xingjian Li , Luke Mathieson , Mauro E. S. Morales

A semiclassical second-order differential equation for the inhomogeneous local gap $\Delta(r)$ is derived from a strict second-order $\hbar$ expansion of the anomalous pairing tensor and compared with a similar equation given by Simonucci…

Quantum Gases · Physics 2023-07-21 Peter Schuck , Michael Urban , Xavier Viñas

Here, we study quantitative homogenization of first-order convex Hamilton-Jacobi equations with $(u/\varepsilon)$-periodic Hamiltonians which typically appear in dislocation dynamics. Firstly, we establish the optimal convergence rate by…

Analysis of PDEs · Mathematics 2025-07-02 Hiroyoshi Mitake , Panrui Ni , Hung V. Tran

We study the optimal convergence rate for homogenization problem of convex Hamilton-Jacobi equations when the Hamitonian is periodic with respect to spatial and time variables, and notably time-dependent. We prove a result similar to that…

Analysis of PDEs · Mathematics 2023-01-02 Hoang Nguyen-Tien

Measuring the expectation value of the molecular electronic Hamiltonian is one of the challenging parts of the variational quantum eigensolver. A widely used strategy is to express the Hamiltonian as a sum of measurable fragments using…

Quantum Physics · Physics 2023-01-04 Seonghoon Choi , Ignacio Loaiza , Artur F. Izmaylov

We study local optima of the Hamiltonian of the Sherrington-Kirkpatrick model. We compute the exponent of the expected number of local optima and determine the "typical" value of the Hamiltonian.

Probability · Mathematics 2017-12-22 Louigi Addario-Berry , Luc Devroye , Gabor Lugosi , Roberto Imbuzeiro Oliveira

We provide for first order discretizations of the integral fractional Laplacian sharp local error estimates on proper subdomains in both the local $H^1$-norm and the localized energy norm. Our estimates have the form of a local best…

Numerical Analysis · Mathematics 2024-07-25 Markus Faustmann , Michael Karkulik , Jens Markus Melenk

A method based on the envelope theory is presented to compute approximate solutions for $N$-body Hamiltonians with identical particles in $D$ dimensions ($D\ge 2$). In some favorable cases, the approximate eigenvalues can be analytically…

Quantum Physics · Physics 2013-11-14 C. Semay , C. Roland

We consider the problems of testing and learning an unknown $n$-qubit Hamiltonian $H$ from queries to its evolution operator $e^{-iHt}$ under the normalized Frobenius norm. We prove: 1. Local Hamiltonians: We give a tolerant testing…

Quantum Physics · Physics 2025-06-09 Srinivasan Arunachalam , Arkopal Dutt , Francisco Escudero Gutiérrez

Quantum entanglement is considered, by and large, to be a very delicate and non-robust phenomenon that is very hard to maintain in the presence of noise, or non-zero temperatures. In recent years however, and motivated, in part, by a quest…

Quantum Physics · Physics 2017-02-27 Lior Eldar

The $k$-means problem is a classic objective for modeling clustering in a metric space. Given a set of points in a metric space, the goal is to find $k$ representative points so as to minimize the sum of the squared distances from each…

Computational Geometry · Computer Science 2026-03-31 Vincent Cohen-Addad , Karthik C. S. , David Saulpic , Chris Schwiegelshohn

We determine the sharp threshold for Hamilton cycles in randomly perturbed sparse graphs. For any $\alpha=\alpha(n)=o(1)$, let $G_{\alpha}$ be an $n$-vertex graph with minimum degree $\delta(G_{\alpha})\ge\alpha n$. We prove that if…

Combinatorics · Mathematics 2026-05-29 Guorui Ma , Zhifei Yan

A harmonic oscillator Hamiltonian augmented by a non-Hermitian \pt-symmetric part and its su(1,1) generalizations, for which a family of positive-definite metric operators was recently constructed, are re-examined in a supersymmetric…

Mathematical Physics · Physics 2008-11-26 C. Quesne