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As much as chiral metasurfaces are significant in stereochemistry and polarization control, tunable chiroptical response is important for their dynamic counterparts. A single metasurface device with invertible chiral states can selectively…

Optics · Physics 2023-06-07 Andrew S. Kim , Anjan Goswami , Mohammad Taghinejad , Wenshan Cai

We present an analysis of two experimental approaches to controlling the directionality of molecular rotation with ultrashort laser pulses. The two methods are based on the molecular interaction with either a pair of pulses (a "double kick"…

Optics · Physics 2015-06-11 C. Bloomquist , S. Zhdanovich , A. A. Milner , V. Milner

Enantiodetection of chiral molecules is important to pharmaceutical drug production, chemical reaction control, and biological function designs. Traditional optical methods of enantiodetection rely on the weak magnetic-dipole or…

Chemical Physics · Physics 2022-09-14 Mao-Rui Cai , Chong Ye , Hui Dong , Yong Li

We design, by invariant-based inverse engineering, resonant laser pulses to perform fast population transfers in three-level systems. The efficiency and laser intensities are examined for different protocols. The energy cost to improve the…

Quantum Physics · Physics 2012-11-16 Xi Chen , J. G. Muga

Different methods have been recently put forward and implemented experimentally to inverse engineer the time dependent Hamiltonian of a quantum system and accelerate slow adiabatic processes via non-adiabatic shortcuts. In the…

Quantum Physics · Physics 2011-08-08 Xi Chen , E. Torrontegui , J. G. Muga

Chirality is a fundamental symmetry concept describing discrete states, i.e., left-handed, right-handed, or achiral, and existing at disparate scales and in many categories of scientific fields. Even though symmetry breaking is…

Inverse iteration is known to be an effective method for computing eigenvectors corresponding to simple and well-separated eigenvalues. In the non-symmetric case, the solution of shifted Hessenberg systems is a central step. Existing…

Mathematical Software · Computer Science 2021-01-14 Angelika Schwarz

We derive here a new highly selective photoelectron-based chirality-sensing technique that utilizes 'locally-chiral' laser pulses. We show that this approach results in strong chiral discrimination, where the standard forwards/backwards…

Chemical Physics · Physics 2021-07-14 Ofer Neufeld , Hannes Hübener , Angel Rubio , Umberto De Giovannini

Achieving chemical accuracy with shallow quantum circuits is a significant challenge in quantum computational chemistry, particularly for near-term quantum devices. In this work, we present a Clifford-based Hamiltonian engineering…

Quantum Physics · Physics 2024-01-09 Jiace Sun , Lixue Cheng , Weitang Li

The performance of computational methods for many-body physics and chemistry is strongly dependent on the choice of basis used to cast the problem; hence, the search for better bases and similarity transformations is important for progress…

Chirality and chiral molecules are key elements in modern chemical and biochemical industries. Individual addressing, and the eventual separation of chiral enantiomers has been and still is an important elusive task in molecular physics and…

The Lewis and Riesenfeld method has been investigated, by Ramos et al in Ref.[1], for quantum systems governed by time-dependent PT symmetric Hamiltonians and particularly where the quantum system is a particle submitted to action of a…

Quantum Physics · Physics 2020-03-18 Walid Koussa , Mustapha Maamache

An ultimate goal of materials science is to deliver materials with desired properties at will. In the theoretical study, a standard approach consists of constructing a Hamiltonian based on phenomenology or first principles, calculating…

Strongly Correlated Electrons · Physics 2023-03-24 Koji Inui , Yukitoshi Motome

Encouraged by the success of contrastive learning on image classification tasks, we propose a new self-supervised method for the structured regression task of 3D hand pose estimation. Contrastive learning makes use of unlabeled data for the…

Computer Vision and Pattern Recognition · Computer Science 2022-08-04 Adrian Spurr , Aneesh Dahiya , Xi Wang , Xucong Zhang , Otmar Hilliges

Enantio-conversion with the help of electromagnetic fields is an essential issue due to the chirality-dependence of many chemical, biological, and pharmaceutical processes. Here, we propose a method for this issue based on a five-level…

Quantum Physics · Physics 2021-03-03 Chong Ye , Bo Liu , Yu-Yuan Chen , Yong Li

Indefinite causal orders have been shown to enable a precision of inverse square N in quantum parameter estimation, where N is the number of independent processes probed in an experiment. This surpasses the widely accepted ultimate quantum…

Quantum Physics · Physics 2025-05-07 Yu Guo , Yuehan Chen , Geng Chen , Xiao-Min Hu , Yun-Feng Huang , Chuan-Feng Li , Guang-Can Guo , Bi-Heng Liu

An interesting method of fast enantio-specific state transfer is proposed for cyclic three-level systems of chiral molecules. We show that the fast population transfer via shortcut to adiabaticity can be accomplished for the cyclic…

Quantum Physics · Physics 2023-05-10 Jian-Jian Cheng , Chong Ye , Yong Li

Chiral emission, where the handedness of a transition dipole determines the direction in which a photon is emitted, has recently been observed from atoms and quantum dots coupled to nanophotonic waveguides. Here, we consider the case of…

Optics · Physics 2018-06-06 Diego Martín-Cano , Harald R. Haakh , Nir Rotenberg

We demonstrate experimentally a method of varying the degree of directionality in laser-induced molecular rotation. To control the ratio between the number of clockwise and counter-clockwise rotating molecules (with respect to a fixed…

Chemical Physics · Physics 2021-05-05 Alexander A. Milner , Valery Milner

We propose a predictive building-up of tetrahedral molecules, based on a previously derived chirality index, which characterizes a tetrahedral molecule, with n chiral centers, as achiral, diastereoisomer, or enantiomer as a function of the…

Chemical Physics · Physics 2008-11-26 S. Capozziello , A. Lattanzi