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A theoretical scheme for the treatment of an open molecular system with electrons and nuclei is proposed. The idea is based on the Grand Canonical description of a quantum region embedded in a classical reservoir of molecules. Electronic…

Statistical Mechanics · Physics 2018-01-17 Luigi Delle Site

This paper develops a gravitational-thermodynamic interpretation of two ensemble structures with singular behavior, denoted as canonical ensemble A and grand canonical ensemble B. Ensemble A is modeled as a stellar-type system in which…

General Relativity and Quantum Cosmology · Physics 2026-03-24 Wen-Xiang Chen

We present the development and implementation of the relativistic coupled cluster linear response theory (CC-LR) which allows the determination of molecular properties arising from time-dependent or time-independent electric, magnetic, or…

This work builds on an existing model of discrete canonical evolution and applies it to the general case of a linear dynamical system, i.e., a finite-dimensional system with configuration space isomorphic to $ \mathbb{R}^{q} $ and linear…

Mathematical Physics · Physics 2021-06-30 Jakub Káninský

Our theoretical examination of second and third harmonic generation from metal-based nanostructures predicts that nonlocal and quantum tunneling phenomena can significantly exceed expectations based solely on local, classical…

Expectation value of dynamical variables in thermodynamically equilibrium state can be typically provided through well-known canonical average. The average includes tremendous number of possible states considered far beyond practically…

General Physics · Physics 2018-04-11 Koretaka Yuge , Shono Ohta

We elucidate the origin of large differences (two-fold or more) in the fixed-node errors between the first- vs second-row systems for single-configuration trial wave functions in quantum Monte Carlo calculations. This significant difference…

Computational Physics · Physics 2015-06-17 Kevin M. Rasch , Shuming Hu , Lubos Mitas

Quantum loop and dimer models are archetypal examples of correlated systems with local constraints. Obtaining generic solutions for these models is difficult due to the lack of controlled methods to solve them in the thermodynamic limit.…

Strongly Correlated Electrons · Physics 2024-06-12 Xiaoxue Ran , Zheng Yan , Yan-Cheng Wang , Junchen Rong , Yang Qi , Zi Yang Meng

The properties of the canonical symmetry of the nonlinear Schr\"odinger equation are investigated. The densities of the local conservation laws for this system are shown to change under the action of the canonical symmetry by total space…

High Energy Physics - Theory · Physics 2007-05-23 A. N. Leznov , A. V. Razumov

The complex arrangements of atoms near grain boundaries are difficult to understand theoretically. We propose a phenomenological (Ginzburg-Landau-like) description of crystalline phases based on symmetries and fairly general stability…

Materials Science · Physics 2015-06-25 Denis Boyer , David Romeu

Many set theorists point to the linearity phenomenon in the hierarchy of consistency strength, by which natural theories tend to be linearly ordered and indeed well ordered by consistency strength. Why should it be linear? In this paper I…

Logic · Mathematics 2022-08-29 Joel David Hamkins

The canonical NLT partition function of a quasi-one dimensional (q1D) one-file system of equal hard disks [J. Chem Phys. 153, 144111 (2020)] provides an analytical description of the thermodynamics and ordering in this system (a pore) as a…

Disordered Systems and Neural Networks · Physics 2026-02-11 V. M. Pergamenshchik , T. Bryk , A. Trokhymchuk

Oscillons are long-lived, localized, oscillatory scalar field configurations. In this work we derive a condition for the existence of small-amplitude oscillons (and provide solutions) in scalar field theories with non-canonical kinetic…

Cosmology and Nongalactic Astrophysics · Physics 2013-07-09 Mustafa A. Amin

We give several different geometric characterizations of the situation in which the parallel set $F_\epsilon$ of a self-similar set $F$ can be described by the inner $\epsilon$-parallel set $T_{-\epsilon}$ of the associated canonical tiling…

Metric Geometry · Mathematics 2011-02-01 Erin P. J. Pearse , Steffen Winter

Differences in core level binding energies between atoms belonging to the same chemical species can be related to differences in their intra- and extra-atomic charge distributions, and differences in how their core holes are screened. With…

Materials Science · Physics 2014-02-14 T. L. Underwood , R. J. Cole

In this paper we study to what extent the canonical equivalence and the identity of the geometric phases of dissipative and conservative linear oscillators, established in a preceeding paper, can be generalized to nonlinear ones.…

chao-dyn · Physics 2009-10-31 O. V. Usatenko , J. -P. Provost , G. Vallee , A. Boudine

Conflict sets are loci of intersecting wavefronts emanating from $l$ different surfaces. We show that generically conflict sets are Legendrian: locally they admit the structure of wavefronts. Simple stable singularities for this problem in…

Differential Geometry · Mathematics 2007-05-23 Martijn van Manen

The carbon monolayer band structure calculated in the approximation of weakly interacting {\pi} electrons corresponds to massless electron excitations known as Dirac fermions not previously observed in any other material. However, if strong…

Strongly Correlated Electrons · Physics 2015-08-13 Marina V. Krasinkova

Nonlinear optical cavities are crucial both in classical and quantum optics; in particular, nowadays optical parametric oscillators are one of the most versatile and tunable sources of coherent light, as well as the sources of the highest…

Quantum Physics · Physics 2016-03-22 Carlos Navarrete-Benlloch , Eugenio Roldán , Yue Chang , Tao Shi

We study existence and multiplicity of positive radial solutions for a coupled elliptic system in exterior domains where the nonlinearities depend on the gradients and the boundary conditions are nonlocal. We use a non-standard cone to…

Functional Analysis · Mathematics 2020-01-01 F. Cianciaruso , L. Muglia , P. Pietramala
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