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A relation between equilibrium, steady-state, and waiting-time dependent dynamical two-time correlation functions in dense glass-forming liquids subject to homogeneous steady shear flow is discussed. The systems under study show pronounced…

Soft Condensed Matter · Physics 2015-05-18 Matthias Krüger , Fabian Weysser , Thomas Voigtmann

There is growing evidence that the flow of driven amorphous solids is not homogeneous, even if the macroscopic stress is constant across the system. Via event driven molecular dynamics simulations of a hard sphere glass, we provide the…

Soft Condensed Matter · Physics 2015-06-04 Suvendu Mandal , Markus Gross , Dierk Raabe , Fathollah Varnik

Using extensive non-equilibrium molecular dynamics simulations, we investigate a glassforming binary Lennard-Jones mixture under shear. Both supercooled liquids and glasses are considered. Our focus is on the characterization of…

Soft Condensed Matter · Physics 2020-08-26 Mehrdad Golkia , Gaurav P. Shrivastav , Pinaki Chaudhuri , Jürgen Horbach

Elastic models of the glass transition relate the relaxation dynamics and the elastic properties of structural glasses. They are based on the assumption that the relaxation dynamics occurs through activated events in the energy landscape…

Soft Condensed Matter · Physics 2015-08-20 M. Pica Ciamarra , Peter Sollich

The excitation-chain theory of the glass transition, proposed in an earlier publication, predicts diverging, super-Arrhenius relaxation times and, {\it via} a similarly diverging length scale, suggests a way of understanding the relations…

Statistical Mechanics · Physics 2009-11-11 J. S. Langer

A theoretical treatment of deeply supercooled liquids is difficult because their properties emerge from spatial inhomogeneities that are self-induced, transient, and nanoscopic. I use computer simulations to analyse self-induced static and…

Statistical Mechanics · Physics 2021-08-24 Ludovic Berthier

In trajectory space, dynamical heterogeneities in glass-forming liquids correspond to the emergence of a dynamical phase transition between an active phase poor in local structure and an inactive phase which is rich in local structure. We…

Soft Condensed Matter · Physics 2021-08-10 Francesco Turci , Thomas Speck , C. Patrick Royall

We review a theoretical perspective of the dynamics of glass forming liquids and the glass transition. It is a perspective we have developed with our collaborators during this decade. It is based upon the structure of trajectory space. This…

Soft Condensed Matter · Physics 2010-04-20 David Chandler , Juan P. Garrahan

We use computer simulations to study the glass transition of dense fluids made of polydisperse, repulsive spheres. For hard particles, we vary the volume fraction, phi, and use compressible particles to explore finite temperatures, T>0. In…

Statistical Mechanics · Physics 2009-08-25 Ludovic Berthier , Thomas A. Witten

We investigate the relaxation process and the dynamical heterogeneities of the kinetically constrained Kob--Anderson lattice glass model, and show that these are characterized by different timescales. The dynamics is well described within…

Soft Condensed Matter · Physics 2011-09-21 Raffaele Pastore , Massimo Pica Ciamarra , Antonio de Candia , Antonio Coniglio

As approaching the glass transition, particle motion in liquids becomes highly heterogeneous and regions with virtually no mobility coexist with liquid-like domains. This complex dynamics is believed to be responsible for different…

Soft Condensed Matter · Physics 2018-03-28 F. Puosi , N. Jakse , A. Pasturel

Many amorphous glassy materials exhibit complex spatio-temporal mechanical response and rheology, characterized by an intermittent stress-strain response and a fluctuating velocity profile. Under quasistatic and athermal deformation…

Soft Condensed Matter · Physics 2010-02-01 Michel Tsamados

Many systems, including polymers and molecular liquids, when adequately cooled and/or compressed, solidify into a disordered solid, i.e., a glass. The~transition is not abrupt, featuring progressive decrease of the microscopic mobility and…

Soft Condensed Matter · Physics 2019-11-19 Francesco Puosi , Antonio Tripodo , Dino Leporini

The interplay of slow dynamics and thermodynamic features of dense liquids is studied by examinining how the glass transition changes depending on the presence or absence of Lennard-Jones-like attractions. Quite different thermodynamic…

Materials Science · Physics 2009-11-13 Th. Voigtmann

We numerically investigate the dynamic heterogeneity and its length scale found in the coarse-grained ionic liquid model systems. In our ionic liquid model systems, cations are modeled as dimers with positive charge, while anions are…

Soft Condensed Matter · Physics 2016-03-10 Soree Kim , Sang-Won Park , YounJoon Jung

The existence of a generalized fluctuation-dissipation theorem observed in simulations and experiments performed in various glassy materials is related to the concepts of local equilibration and heterogeneity in space. Assuming the…

Statistical Mechanics · Physics 2009-11-10 Ludovic Berthier

We consider the Mode Coupling Theory (MCT) of Glass transition for a Binary fluid. The Equations of Nonlinear Fluctuating Hydrodynamics are obtained with a proper choice of the slow variables corresponding to the conservation laws. The…

Statistical Mechanics · Physics 2009-11-07 Upendra Harbola , Shankar P. Das

The presence of strong local fluctuations -- dynamical heterogeneities -- has been observed near the glass transitions of a wide variety of materials. Here we explore the possible presence of universality in those fluctuations. We compare…

Disordered Systems and Neural Networks · Physics 2008-11-20 Azita Parsaeian , Horacio E. Castillo

We analyze a simple dynamical model of glasses, based on the idea that each particle is trapped in a local potential well, which itself evolves due to hopping of neighbouring particles. The glass transition is signalled by the fact that the…

Condensed Matter · Physics 2009-10-28 Jean-Philippe Bouchaud , Alain Comtet , Cécile Monthus

We present simulation results for the dynamics of a schematic model based on the frustration-limited domain picture of glass-forming liquids. These results are compared with approximate theoretical predictions analogous to those commonly…

Statistical Mechanics · Physics 2009-11-10 Phillip L. Geissler , David R. Reichman
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