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The hierarchical equations of motion (HEOM) for a generalized quantum dissipative system is rigorously constructed in the frameworks of two different stochastic dynamical descriptions, i.e., the non-Markovian quantum state diffusion…

Quantum Physics · Physics 2018-07-18 Wei Wu

We apply a recently developed quasi-diabatic (QD) scheme to the symmetric quasi-classical (SQC) approach for accurate quantum dynamics propagation. By using the adiabatic states as the quasi-diabatic states during a short-time quantum…

Chemical Physics · Physics 2018-07-11 Juan Sebastian C. Sandoval , Arkajit Mandal , Pengfei Huo

We develop from first principles Markovian master equations suited for studying the time evolution of a system evolving adiabatically while coupled weakly to a thermal bath. We derive two sets of equations in the adiabatic limit, one using…

Quantum Physics · Physics 2015-11-03 Tameem Albash , Sergio Boixo , Daniel A. Lidar , Paolo Zanardi

The mapping approach addresses the mismatch between the continuous nuclear phase space and discrete electronic states by creating an extended, fully continuous phase space using a set of harmonic oscillators to encode the populations and…

Chemical Physics · Physics 2019-09-30 Maximilian A. C. Saller , Aaron Kelly , Jeremy O. Richardson

We present a framework for dynamic quadrupedal locomotion over challenging terrain, where the choice of appropriate footholds is crucial for the success of the behaviour. We build a model of the environment on-line and on-board using an…

This paper presents a novel on-line path planning method that enables aerial robots to interact with surfaces. We present a solution to the problem of finding trajectories that drive a robot towards a surface and move along it. Triangular…

Robotics · Computer Science 2021-02-23 Michael Pantic , Lionel Ott , Cesar Cadena , Roland Siegwart , Juan Nieto

Stochastic nonlinear dynamical systems can undergo rapid transitions relative to the change in their forcing, for example due to the occurrence of multiple equilibrium solutions for a specific interval of parameters. In this paper, we…

Data Analysis, Statistics and Probability · Physics 2020-11-12 S. Baars , D. Castellana , F. W. Wubs , H. A. Dijkstra

The Davydov D1 ansatz, which assigns an individual bosonic trajectory to each spin state, is an efficient, yet extremely accurate trial state for time-dependent variation of the sub-Ohmic spin-boson model [J. Chem. Phys. 138, 084111…

Chemical Physics · Physics 2015-06-16 Yao Yao , Yang Zhao

The non-Markovian dynamics of a three-level quantum system coupled to a bosonic environment is a difficult problem due to the lack of an exact dynamic equation such as a master equation. We present for the first time an exact quantum…

Quantum Physics · Physics 2010-12-27 Jun Jing , Ting Yu

We demonstrate an approach to the numerical solution of nonlinear stochastic differential equations with Markovian switching. Such equations describe the stochastic dynamics of processes where the drift and diffusion coefficients are…

Numerical Analysis · Mathematics 2024-08-28 Cónall Kelly , Kate O'Donovan

We describe a quantum trajectories technique for the unraveling of the quantum adiabatic master equation in Lindblad form. By evolving a complex state vector of dimension $N$ instead of a complex density matrix of dimension $N^2$,…

Quantum Physics · Physics 2024-01-17 Ka Wa Yip , Tameem Albash , Daniel A. Lidar

We set up a general density-operator approach to geometric steady-state pumping through slowly driven open quantum systems. This approach applies to strongly interacting systems that are weakly coupled to multiple reservoirs at high…

Mesoscale and Nanoscale Physics · Physics 2017-05-11 T. Pluecker , M. R. Wegewijs , J. Splettstoesser

The crossover from nonadiabatic to adiabatic electron transfer has been theoretically studied under a spin-boson model (dissipative two-state system) description. We present numerically exact data for the thermal transfer rate and the…

Condensed Matter · Physics 2009-11-07 L. Muehlbacher , R. Egger

The paradigm of Floquet engineering of topological states of matter can be generalized into the time-quasiperiodic scenario, where a lower dimensional time-dependent system maps into a higher dimensional one by combining the physical…

Mesoscale and Nanoscale Physics · Physics 2021-12-07 Zihao Qi , Gil Refael , Yang Peng

The symmetrical quasi-classical dynamics method based on the Meyer-Miller mapping Hamiltonian (MM-SQC) shows the great potential in the treatment of the nonadiabatic dynamics of complex systems. We performed the comprehensive benchmark…

Chemical Physics · Physics 2019-03-12 Yu Xie , Jie Zheng , Zhenggang Lan

A generalized formalism of the so-called non-adiabatic quantum molecular dynamics is presented, which applies for atomic many-body systems in external laser fields. The theory treats the nuclear dynamics and electronic transitions…

Atomic Physics · Physics 2007-05-23 Thomas Kunert , Ruediger Schmidt

The electronic structure calculations remain a major bottleneck in ab initio nonadiabatic molecular dynamics. We develop an efficient TDDFT-based FSSH implementation in the GPU4PySCF package for medium-sized molecular systems. Our approach…

Chemical Physics · Physics 2026-05-08 Cheng Fan , Zhichen Pu , Zehao Zhou , Yuanheng Wang , Yi Qin Gao , Qiming Sun

We discuss the emergence of nonadiabatic behavior in the dynamics of the order parameter in a low-dimensional quantum many-body system subject to a linear ramp of one of its parameters. While performing a ramp within a gapped phase seems to…

Statistical Mechanics · Physics 2014-09-25 Anna Maraga , Pietro Smacchia , Michele Fabrizio , Alessandro Silva

Mean-Field Ring Polymer Molecular Dynamics (MF-RPMD) is a powerful, efficient, and accurate method for approximate quantum dynamic simulations of multi-level system dynamics. Initial efforts to compute nonadiabatic reaction rates using…

Chemical Physics · Physics 2021-04-29 Britta Ann Johnson , Nandini Ananth

We introduce a geometric framework for efficient few-parameter pulse optimization in multi-level quantum systems, enabling high-fidelity state transfer beyond the adiabatic limit. Our method interpolates smoothly between adiabatic and…

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