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Recent theoretical studies in quantum spectroscopy have emphasized the potential of non-classical correlations in entangled photon pairs for selectively targeting specific nonlinear optical processes in nonlinear optical responses. However,…

Chemical Physics · Physics 2026-04-21 Yuta Fujihashi , Ozora Iso , Ryosuke Shimizu , Akihito Ishizaki

Classical time-resolved optical spectroscopy experiments are performed using sequences of ultrashort light pulses, with photon fluxes incident on the sample which are many orders of magnitude higher than real-world conditions corresponding…

Recent advances in techniques for generating quantum light have stimulated research on novel spectroscopic measurements using quantum entangled photons. One such spectroscopy technique utilizes non-classical correlations among entangled…

Chemical Physics · Physics 2021-07-28 Yuta Fujihashi , Akihito Ishizaki

Quantum entanglement has emerged as a great resource for interactions between molecules and radiation. We propose a new paradigm of stimulated Raman scattering with entangled photons. A quantum ultrafast Raman spectroscopy is developed for…

Quantum Physics · Physics 2023-05-26 Joel Jiahao Fan , Zhe-Yu Jeff Ou , Zhedong Zhang

Quantum light is a key resource for promoting quantum technology. One such class of technology aims to improve the precision of optical measurements using engineered quantum states of light. In this study, we investigate transmission…

Quantum Physics · Physics 2020-08-10 Akihito Ishizaki

Entangled photon spectroscopy is a nascent field that has important implications for measurement and imaging across chemical, biology, and materials fields. Entangled photon spectroscopy potentially offers improved spatial and…

Optics · Physics 2021-07-07 Szilard Szoke , Manni He , Bryce P. Hickam , Scott K. Cushing

Nonlinear spectroscopic techniques using entangled photon pairs can provide an opportunity to exploit non-classical correlations encoded in two-photon wavefunctions to manipulate two-exciton wavefunctions. We propose an entangled photon…

Quantum Physics · Physics 2026-04-10 Arunangshu Debnath , Shaul Mukamel

Conventional nonlinear spectroscopy uses classical light to detect matter properties through the variation of its response with frequencies or time delays. Quantum light opens up new avenues for spectroscopy by utilizing parameters of the…

Quantum Physics · Physics 2017-02-01 Konstantin E. Dorfman , Frank Schlawin , Shaul Mukamel

Ultrafast optical spectroscopy is a powerful technique for studying the dynamic processes of molecular systems in condensed phases. However, in molecular systems containing many dye molecules, the spectra can become crowded and difficult to…

Chemical Physics · Physics 2025-02-05 Yuta Fujihashi , Akihito Ishizaki , Ryosuke Shimizu

Energy-time entangled photons are critical in many quantum optical phenomena and have emerged as important elements in quantum information protocols. Entanglement in this degree of freedom often manifests itself on ultrafast timescales…

Quantum Physics · Physics 2018-02-07 Jean-Philippe W. MacLean , John M. Donohue , Kevin J. Resch

In molecular aggregates, multiple delocalized exciton states interact with phonons, making the state-resolved spectroscopic monitoring of dynamics challenging. We propose a protocol that combines photon-entanglement-enhanced narrowband…

Quantum Physics · Physics 2026-04-24 Arunangshu Debnath , Shaul Mukamel

Entangled photons have the remarkable ability to be more sensitive to signal and less sensitive to noise than classical light. Joint photons can sample an object collectively, resulting in faster phase accumulation and higher spatial…

Optics · Physics 2015-09-04 Chien-Hung Lu , Matthew Reichert , Xiaohang Sun , Jason W. Fleischer

Entangled photons exhibit non-classical light-matter interactions that create new opportunities in materials and molecular science. For example, in entangled two-photon absorption, the intensity-dependence scales linearly as if only one…

Optics · Physics 2020-05-15 Szilard Szoke , Hanzhe Liu , Bryce P. Hickam , Manni He , Scott K. Cushing

Quantum light spectroscopy, providing novel molecular information non-accessible by classical light, necessitates new computational tools when applied for complex molecular systems. We introduce two computational protocols for the molecular…

Chemical Physics · Physics 2021-09-14 Bing Gu , Daniel Keefer , Shaul Mukamel

Entangled two-photon spectroscopy is expected to provide advantages compared with classical protocols. It is achieved by coherently controlling the spectral properties of energy-entangled photons. We present here an experimental setup that…

Quantum Physics · Physics 2021-08-25 Stefan Lerch , André Stefanov

In the same manner that free-space propagation and curved glass lenses are used to shape the spatial properties of light, a combination of chromatic dispersion and devices known as time lenses may be used to reshape its temporal properties.…

Quantum Physics · Physics 2016-12-08 John M. Donohue , Morgan Mastrovich , Kevin J. Resch

Energy-time entangled photons provide new opportunities for controlling multiphoton absorption beyond classical limits. Here, we investigate biexciton generation in nanocrystal quantum dots driven by energy-time-entangled quantum light…

Chemical Physics · Physics 2026-05-27 Kaiyue Peng , Chieh Tsao , Hendrik Utzat , Eran Rabani

We study the dynamics of quantum matter interacting with time-energy entangled photons. We consider the stimulation of a collective mode of a two-dimensional material by means of one of the two partners of a time-energy entangled pair of…

Mesoscale and Nanoscale Physics · Physics 2026-01-15 Giovanni Citeroni , Marco Polini , Michael Dapolito , D. N. Basov , Giacomo Mazza

Pairs of photons entangled in their time-frequency degree of freedom are of great interest in quantum optics research and applications, due to their relative ease of generation and their high capacity for encoding information. Here we…

Quantum Physics · Physics 2022-02-23 Sofiane Merkouche , Valérian Thiel , Brian J. Smith

We develop an ultrafast frequency-resolved Raman spectroscopy with entangled photons for polyatomic molecules in condensed phases, to probe the electronic and vibrational coherences. Using quantum correlation between the photons, the signal…

Quantum Physics · Physics 2021-06-23 Zhedong Zhang , Tao Peng , Xiaoyu Nie , Girish S. Agarwal , Marlan O. Scully
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