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The tetradymite compound BiSbTeSe$_2$, is one of the most bulk-insulating three-dimensional topological insulators, which makes it important in the topological insulator research. It is a member of the solid-solution system…

We use density functional theory (DFT) calculations to study the lattice vibrations and electronic properties of the correlated metal LaNiO$_3$. To characterize the rhombohedral to cubic structural phase transition of perovskite LaNiO$_3$,…

Materials Science · Physics 2011-11-09 Gaoyang Gou , Ilya Grinberg , Andrew M. Rappe , James M. Rondinelli

We report ab initio calculations of the electronic band structure and the phonon dispersion relations of the zincblende-type mercury chalcogenides (beta-HgS, HgSe, and HgTe). The latter have been used to evaluate the temperature dependence…

Materials Science · Physics 2009-08-26 M. Cardona , R. K. Kremer , R. Lauck , G. Siegle , A. Munoz , A. H. Romero

The interplay between lattice distortions, magnetism, and spin-orbit coupling in 5d transition-metal halides offers a fertile platform for exploring correlated spin-lattice dynamics. Here, we investigate the impact of structural symmetry…

Strongly Correlated Electrons · Physics 2026-01-30 S. Bhatia , A. Ahmad , M. Zeeshan , S. Kaur , J. K. Anand , A. Goswami , B. K. Mani , K. Sen

Despite the tremendous progress in spintronic studies of van der Waals (vdW) room-temperature ferromagnet Fe3GaTe2, much less effort has been spent on its lattice dynamics and possible interaction with spintronic degrees of freedom. In this…

Materials Science · Physics 2025-06-12 Xia Chen , Xi Zhang , Wenjie He , Yu Li , Jiating Lu , Dinghua Yang , Deren Li , Li Lei , Yong Peng , Gang Xiang

The availability of ab initio electronic calculations and the concomitant techniques for deriving the corresponding lattice dynamics have been profusely used for calculating thermodynamic and vibrational properties of semiconductors, as…

Materials Science · Physics 2015-05-27 A. H. Romero , M. Cardona , R. K. Kremer , R. Lauck , G. Siegle , C. Hoch , A. Munoz , A. Schindler

Topological materials provide an exclusive platform to study the dynamics of relativistic particles in table-top experiments and offer the possibility of wide-scale technological applications. ZrSiS is a newly discovered topological…

The semimetal NbIrTe4 has been proposed to be a Type-II Weyl semimetal with 8 pairs of opposite Chirality Weyl nodes which are very close to the Fermi energy. This topological electronic structure is made possible because of the broken…

Stable structures of layered SnS and SnSe and their associated electronic and vibrational spectra are predicted using first-principles DFT calculations. The calculations show that both materials undergo a phase transformation upon thinning…

Materials Science · Physics 2019-06-04 Antoine Dewandre , Matthieu J. Verstraete , Nicole Grobert , Zeila Zanolli

The theoretical studies on the electronic and lattice properties of the series of non-centrosymmetric superconductors ThTSi, where T = Co, Ni, Ir, and Pt are presented. The electronic band structure and crystal parameters were optimized…

Materials Science · Physics 2019-11-01 A. Ptok , K. Domieracki , K. J. Kapcia , J. Łażewski , P. T. Jochym , M. Sternik , P. Piekarz , D. Kaczorowski

Vibration properties of Zn(1-x)Be(x)Se, a mixed II-VI semiconductor haracterized by a high contrast in elastic properties of its pure constituents, ZnSe and BeSe, are simulated by first-principles calculations of electronic structure,…

Materials Science · Physics 2009-11-10 A. V. Postnikov , Olivier Pages , Joseph Hugel

We report a comprehensive investigation of the lattice dynamics of URu$_2$Si$_2$ as a function of temperature using Raman scattering, optical conductivity and inelastic neutron scattering measurements as well as theoretical {\it ab initio}…

The lead chalcogenides represent an important family of functional materials, in particular due to the benchmark high-temperature thermoelectric performance of PbTe. A number of recent investigations, experimental and theoretical, have…

Materials Science · Physics 2014-05-27 Jonathan Michael Skelton , Stephen C. Parker , Atsushi Togo , Isao Tanaka , Aron Walsh

Lattice vibrations are highly sensitive to crystal symmetries and their changes across phase transitions. The latter can modify irreducible (co)representations and corresponding infrared and Raman selection rules of phonons. This concept is…

To date, two types of coupling between electromagnetic radiation and a crystal lattice have been identified experimentally. One is direct, for infrared (IR)-active vibrations that carry an electric dipole. The second is indirect, it occurs…

We combine polarization-resolved low frequency Raman microscopy and dispersion-corrected density-functional calculations (DFT-D3) to study polymorph-dependent lattice vibrations in coronene, a model molecular system for nanographenes and…

Strain is prominent in fabricated samples of two-dimensional semiconductors and it also serves as an exploitable tool for engineering their properties. However, quantifying strain and characterizing its spatially inhomogeneous distribution…

Materials Science · Physics 2014-09-01 Ruixiang Fei , Li Yang

We present a systematic study of the structure and lattice dynamics at room temperature, and the phonon behavior at low temperatures in orthorhombic Gd$_{1-x}$Y$_{x}$MnO$_{3}$ manganites, with 0 $\leq$ x $\leq$ 0.4, using powder x-ray…

Strongly Correlated Electrons · Physics 2014-12-31 R. Vilarinho , E. C. Queirós , A. Almeida , P. B. Tavares , J. Agostinho Moreira

We measured the Raman and the Infrared phonon spectrum of SmFeAsO polycrystalline samples. We also performed Density Functional Theory calculations within the pseudopotential approximation to obtain the structural and dynamical lattice…

We present a combined density-functional-perturbation-theory and inelastic neutron scattering study of the lattice dynamical properties of YNi2B2C. In general, very good agreement was found between theory and experiment for both phonon…

Superconductivity · Physics 2015-06-19 F. Weber , L. Pintschovius , W. Reichardt , R. Heid , K. -P. Bohnen , A. Kreyssig , D. Reznik , K. Hradil