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Related papers: Field-free molecular alignment by the optimized tw…

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The mixed-field orientation of an asymmetric-rotor molecule with its permanent dipole moment non-parallel to the principal axes of polarizability is investigated experimentally and theoretically. We find that for the typical case of a…

We report the observation of macroscopic field-free orientation, i.e. more than 73 % of CO molecules pointing in the same direction. This is achieved through an all-optical scheme operating at high particle densities ($>10^{17}$cm$^{-3}$)…

Chemical Physics · Physics 2014-07-09 P. M. Kraus , D. Baykusheva , H. J. Wörner

The time-dependent quantum system of two laser-driven electrons in a harmonic oscillator potential is analysed, taking into account the repulsive Coulomb interaction between both particles. The Schrodinger equation of the two-particle…

Quantum Physics · Physics 2009-11-07 Uwe Schwengelbeck

We consider solid surface scattering of molecules that were subject to strong non-resonant ultrashort laser pulses just before hitting the surface. The pulses modify the rotational states of the molecules, causing their field free…

Chemical Physics · Physics 2015-06-12 Yuri Khodorkovsky , J. R. Manson , Ilya Sh. Averbukh

The propensity of molecules to spatially align along the polarization vector of intense, pulsed light fields is related to readily-accessible parameters (molecular polarizabilities, moment of inertia, peak intensity of the light and its…

Atomic Physics · Physics 2009-11-06 S. Banerjee , D. Mathur , G. Ravindra Kumar

Impulsive orientation of symmetric-top molecules excited by two-color femtosecond pulses is considered. In addition to the well-known transient orientation appearing immediately after the pulse and then reemerging periodically due to…

Optics · Physics 2021-07-22 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

Modern laser systems are able to generate short and intense laser pulses ionizing matter in the poorly explored barrier-suppression regime. Field ionization in this regime is studied analytically and numerically. For analytical studies,…

Atomic Physics · Physics 2018-11-15 I. Yu. Kostyukov , A. A. Golovanov

We study the control by electromagnetic fields of molecular alignment and orientation, in a linear, rigid rotor model. With the help of a monotonically convergent algorithm, we find that the optimal field is in the microwave part of the…

Chemical Physics · Physics 2007-05-23 Julien Salomon , Claude M. Dion , Gabriel Turinici

We present a theoretical study of the mixed-field orientation of molecules without rotational symmetry. The time-dependent one-dimensional and three-dimensional orientation of a thermal ensemble of 6-chloropyridazine-3-carbonitrile…

Chemical Physics · Physics 2017-06-26 Linda V. Thesing , Jochen Küpper , Rosario González-Férez

We present quantum mechanical explanations for unresolved phenomena observed in field-free molecular alignment by a femtosecond laser pulse. Quantum phase analysis of molecular rotational states reveals the physical origin of the following…

Optics · Physics 2015-04-09 Sang Jae Yun , Chul Min Kim , Jongmin Lee , Chang Hee Nam

We study interaction of generic asymmetric molecules with a pair of strong time-delayed short laser pulses with crossed linear polarizations. We show that such an excitation not only provides unidirectional rotation of the most polarizable…

Chemical Physics · Physics 2018-02-28 E. Gershnabel , I. Sh. Averbukh

We investigate experimentally and numerically the field-free orientation of the symmetric top molecule of methyl-iodide at high temperature using a terahertz radiation generated by a plasma induced by a two-color laser beam. The degree of…

Quantum Physics · Physics 2016-11-03 P. Babilotte , K. Hamraoui , F. Billard , E. Hertz , B. Lavorel , O. Faucher , D. Sugny

We explore the possibility of forming a oriented polar molecule directly from a pair of colliding atoms. The process comprises the photoassociation and vibrational stabilization along with the molecular orientation. These processes are…

Quantum Physics · Physics 2026-01-14 Murilo D. Forlevesi , Edson Denis Leonel , Emanuel F. de Lima

We introduce a new optical tool - a "two-dimensional optical centrifuge", capable of aligning molecules in extreme rotational states. Unlike the conventional centrifuge, which confines the molecules in the plane of their rotation, its…

Chemical Physics · Physics 2016-05-18 A. A. Milner , A. Korobenko , V. Milner

We present a very efficient technique for solving the three-dimensional time-dependent Schrodinger equation. Our method is applicable to a wide range of problems where a fullly three-dimensional solution is required, i.e., to cases where no…

Atomic Physics · Physics 2009-11-13 T. K. Kjeldsen , L. A. A. Nikolopoulos , L. B. Madsen

The interaction of strong laser fields with matter intrinsically provides powerful tools to image transient dynamics with an extremely high spatiotemporal resolution. Here, we study strong-field ionisation of laser-aligned molecules and…

Schrodinger equation for a charged particle interacting with the plane wave electromagnetic field is solved exactly. The exact analytic solution and the perturbative solution up to second order are compared.

Quantum Physics · Physics 2009-11-13 C. Yuce

We demonstrate strong laser-field-free orientation of absolute-ground-state carbonyl sulfide molecules. The molecules are oriented by the combination of a 485-ps-long non-resonant laser pulse and a weak static electric field. The edges of…

The capability to control molecular rotation for field-free orientation, which arranges molecules in specific spatial directions without external fields, is crucial in physics, chemistry, and quantum information science. However,…

Quantum Physics · Physics 2025-12-25 Qian-Qian Hong , Zhe-Jun Zhang , Chuan-Cun Shu , Jun He , Daoyi Dong , Dajun Ding

We report a theoretical study of the optical centrifuge acceleration of an asymmetric top molecule interacting with an electric static field by solving the time-dependent Schr\"odinger equation in the rigid rotor approximation. A detailed…

Chemical Physics · Physics 2018-02-14 Juan J. Omiste